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(a)
Interpretation:
A mechanism involved in the conversion of cytosine to uracil in the presence of nitrous acid is to be stated.
Concept introduction:
The base pairing in DNA involves the pairing of cytosine with guanine and adenine with thymine. The base pairing in RNA involves the pairing of cytosine with guanine and adenine with uracil.
(b)
Interpretation:
An explanation corresponding to this conversion being mutagenic upon replication is to be stated.
Concept introduction:
The base pairing in DNA involves the pairing of cytosine with guanine and adenine with thymine. The base pairing in RNA involves the pairing of cytosine with guanine and adenine with uracil.
(c)
Interpretation:
The information regarding the presence of thymine in DNA rather than uracil is given. An explanation corresponding to the easy repairing of mutation of cytosine to uracil that is induced by nitrous acid in DNA than in RNA is to be stated.
Concept introduction:
The base pairing in DNA involves the pairing of cytosine with guanine and adenine with thymine. The base pairing in RNA involves the pairing of cytosine with guanine and adenine with uracil.
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Chapter 23 Solutions
Organic Chemistry (9th Edition)
- Problem 3-42 Consider 2-methylbutane (isopentane). Sighting along the C2-C3 bond: (a) Draw a Newman projection of the most stable conformation. (b) Draw a Newman projection of the least stable conformation. Problem 3-44 Construct a qualitative potential-energy diagram for rotation about the C-C bond of 1,2-dibromoethane. Which conformation would you expect to be most stable? Label the anti and gauche conformations of 1,2- dibromoethane. Problem 3-45 Which conformation of 1,2-dibromoethane (Problem 3-44) would you expect to have the largest dipole moment? The observed dipole moment of 1,2-dibromoethane is µ = 1.0 D. What does this tell you about the actual conformation of the molecule?arrow_forwardGas Law Studies 1. Mass of zinc Determination of 0.899 2) Moles of zinc 0.01361 mol 3.) Moles of hydrogen 00? ← I was told to calculate this number from mole of zinc. 350m So does that mean it will be 0.01361 mol too? 4 Volume of water collected (mL) 5) VL of water collected (Liters) 0.350 L 6) Temp of water collected (°C) 7) Temp of water collected (°K) 8) Atmospheric pressure (mm) 9) Vapor pressure of water (mm) 10) Corrected pressure of hydrogen 20% 29°C 764.0mm Hg (mm) 17.5mm 11) Corrected pressure of hydrogen (atm) 12) Experimentally calculated value of 19 13. Literature value of R 14) % Error 15) Suggest reasons for the % error (#14)arrow_forwardNo wedge or dashes. Do proper structure. Provide steps and explanation.arrow_forward
- 10 Question (1 point) Draw curved arrow notation to indicate the proton transfer between NaOH and CH3CO₂H. 2nd attempt :0- H See Periodic Table See Hint Draw the products of the proton transfer reaction. Don't add a + sign between the products.arrow_forwardProvide steps and explanation please.arrow_forwardProvide steps to name and label for understanding.arrow_forward
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