The type of isomers and its structure of given complex [ P t C l 2 B r 2 ] 2 − has to be drawn. Concept introduction: Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound. Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds. Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds. Optical isomers: Optical isomers are non-superimposable mirror images. Plane-polarized light: Light that oscillates in a single plane.

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Answer 1

Question

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

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Answer 3

Question

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

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Answer 4

Question

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

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Answer 5

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 6

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 7

Chapter 23, Problem 23.65P

(a)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [PtCl2Br2]2− has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Cr(NH3)5(NO2)]2+ has to be drawn.

Concept introduction:

Linkage isomers occur when the composition of the complex ion is the same but the ligand donor atom is different. Some ligands can bind to the metal ion through either of two donor atoms.

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The type of isomers and its structure of given complex [Pt(NH3)4I2]2+ has to be drawn.

Concept introduction:

Geometry of coordination compounds: The study of geometry of the coordination compound helps in understanding the physical and chemical property of the compound.

Stereoisomer: The same molecular formula but different with the arrangements of atoms around the metal ion. The Ligands are arranged differently in coordination compounds.

Geometric isomers: stereoisomers that cannot be interconverted without breaking the chemical bonds.

Optical isomers: Optical isomers are non-superimposable mirror images.

Plane-polarized light: Light that oscillates in a single plane.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 23.1 - Write partial electron configurations (no noble...Ch. 23.1 - Find the charge of each of the following ions,...Ch. 23.2 - Prob. 23.2AFP Ch. 23.2 - Prob. 23.2BFP Ch. 23.3 - Give the coordination number and the charge of the...Ch. 23.3 - Write the formula of the coordination compound...Ch. 23.3 - Prob. 23.4AFP Ch. 23.3 - Prob. 23.4BFP Ch. 23.3 - Prob. 23.5AFP Ch. 23.3 - Prob. 23.5BFP

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