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(a) Define carbocation.
(b) Which of the following are carbocations?
(i)
Interpretation:
Explanation of carbocation, Carbocation should be identified for the given molecule.
Concept introduction:
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.
Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.
Answer to Problem 23.53QP
Answer
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation. (a).
Explanation of Solution
To explain:carbocation
Structure of the carbocation is given below,
Carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
(ii)
Interpretation:
Explanation of carbocation, Carbocation should be identified for the given molecule.
Concept introduction:
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.
Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.
Answer to Problem 23.53QP
Answer
The given molecule is not a carbocation, the structure of the molecule is shown below
Explanation of Solution
To find: The carbocation.
The given molecule is not a carbocation, the structure of the molecule is shown below
Oxygen is bearing positive charge, so the given molecule is not a carbocation.
(iii)
Interpretation:
Explanation of carbocation, Carbocation should be identified for the given molecule.
Concept introduction:
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.
Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.
Answer to Problem 23.53QP
Answer
The given molecule is carbocation, the structure of the molecule is shown below
Explanation of Solution
To find: The carbocation.
The given molecule is carbocation, the structure of the molecule is shown below
Carbon atom bears positive charged species with three bonds so the given molecule is called Carbocation
(vi)
Interpretation:
Explanation of carbocation, Carbocation should be identified for the given molecule.
Concept introduction:
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.
Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.
Answer to Problem 23.53QP
Answer
The given molecule is carbocation, the structure of the molecule is shown below (d)
Explanation of Solution
To find:The carbocation.
The given molecule is carbocation, the structure of the molecule is shown below
Carbon atom bears positive charged species with three bonds so the given molecule is called Carbocation
(v)
Interpretation:
Explanation of carbocation, Carbocation should be identified for the given molecule.
Concept introduction:
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.
Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.
Answer to Problem 23.53QP
Answer
The given molecule is carbocation, the structure of the molecule is shown below (e)
Explanation of Solution
To find:The carbocation.
The given molecule is carbocation, the structure of the molecule is shown below
Carbon atom bears positive charged species with three bonds so the given molecule is called Carbocation.
(vi)
Interpretation:
Explanation of carbocation, Carbocation should be identified for the given molecule.
Concept introduction:
Carbocation: carbon atom bears positive charged species with three bonds is called Carbocation and it plays vital intermediate in organic synthesis. Carbocation migratory aptitude is mainly depends on the stability of the carbocation.
Carbocation’s are classified in to three types as primary, secondary and tertiary depending on the number of carbon atoms which is attached to the ionized carbon.
Tertiary carbocation is more stable than secondary carbocation, secondary carbocation is more stable than the primary carbocation.
Answer to Problem 23.53QP
Answer
The given molecule is not a carbocation, the structure of the molecule is shown below (f)
Explanation of Solution
To find: The carbocation.
The given molecule is not a carbocation, the structure of the molecule is shown below (f)
Nitrogen is bearing positive charge with four bonds, so the given molecule is not a carbocation.
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Chapter 23 Solutions
Chemistry: Atoms First
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Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning