Chemistry, Loose-leaf Edition (8th Edition)
8th Edition
ISBN: 9780135210123
Author: Jill Kirsten Robinson, John E. McMurry, Robert C. Fay
Publisher: PEARSON
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Chapter 23, Problem 23.43SP
Interpretation Introduction
Interpretation:
The condensed structure and line drawing structure of straight-chain alkane with 7 carbon atoms are to be drawn.
Concept introduction:
Line drawing structure involves drawing of structure with the help of lines only, lone pairs are not shown in this structure.
The condensed structure is a structure in which the vertical bonds and horizontal bonds between C-C and C-H atoms are not drawn.
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Using the bond energy values, calculate the energy that must be supplied or is released upon the polymerization of 755 monomers. If energy must be supplied, provide a positive number; if energy is released, provide a negative number. Hint: Avogadro’s number is 6.02 × 1023.
-AG|F=2E|V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
Acidic solution
-0.93
+0.38
-0.51 -0.06
H3PO4 →H4P206 H3PO3 H3PO2 → P→ PH3
-0.28
-0.50
→
-0.50
Basic solution
3-1.12
-1.57
-2.05 -0.89
PO HPO →→H2PO2 P PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P2O6 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5 PH,
0.0
-0.5-
2 3 9 3
-1.5
-2.0
Pa
H,PO
H,PO
H,PO
-3
-1 0
2
4
Oxidation state, N
2
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
c) Elemental phosphorus tends to disproportionate under basic conditions. Use data in…
These two reactions appear to start with the same starting materials but result in different products. How do the chemicals know which product to form? Are both products formed, or is there some information missing that will direct them a particular way?
Chapter 23 Solutions
Chemistry, Loose-leaf Edition (8th Edition)
Ch. 23 - Prob. 23.1PCh. 23 - Prob. 23.2ACh. 23 - Prob. 23.3PCh. 23 - Prob. 23.4ACh. 23 - Prob. 23.5PCh. 23 - Prob. 23.6ACh. 23 - Draw a complete electron-dot structure for...Ch. 23 - Limonene is the major component in the oil of...Ch. 23 - Draw an orbital overlap picture for methyl a mine...Ch. 23 - Prob. 23.10A
Ch. 23 - Draw an orbital overlap picture for formaldehyde,...Ch. 23 - Prob. 23.12ACh. 23 - Prob. 23.13PCh. 23 - Prob. 23.14ACh. 23 - Prob. 23.15PCh. 23 - Draw complete electron-dot structures from the...Ch. 23 - Prob. 23.17PCh. 23 - Prob. 23.18ACh. 23 - Draw a simplified orbital overlap picture of...Ch. 23 - Prob. 23.20ACh. 23 - Prob. 23.21PCh. 23 - Prob. 23.22ACh. 23 - Prob. 23.23PCh. 23 - Prob. 23.24ACh. 23 - Prob. 23.25PCh. 23 - Prob. 23.26ACh. 23 - Asparagine is a naturally occurring aminoacid that...Ch. 23 - Prob. 23.28PCh. 23 - Prob. 23.29PCh. 23 - Prob. 23.30CPCh. 23 - Prob. 23.31CPCh. 23 - Prob. 23.32CPCh. 23 - Prob. 23.33CPCh. 23 - Prob. 23.34CPCh. 23 - Prob. 23.35CPCh. 23 - The following structure is a representation of...Ch. 23 - Prob. 23.37CPCh. 23 - Prob. 23.38CPCh. 23 - Prob. 23.39CPCh. 23 - Prob. 23.40SPCh. 23 - Prob. 23.41SPCh. 23 - Draw a straight-chain alkane with 6 carbon atoms...Ch. 23 - Prob. 23.43SPCh. 23 - Prob. 23.44SPCh. 23 - Prob. 23.45SPCh. 23 - The following line drawings represent two amino...Ch. 23 - Prob. 23.47SPCh. 23 - Prob. 23.48SPCh. 23 - Prob. 23.49SPCh. 23 - Prob. 23.50SPCh. 23 - Prob. 23.51SPCh. 23 - Prob. 23.52SPCh. 23 - Prob. 23.53SPCh. 23 - Prob. 23.54SPCh. 23 - Prob. 23.55SPCh. 23 - Prob. 23.56SPCh. 23 - Prob. 23.57SPCh. 23 - Prob. 23.58SPCh. 23 - Give a line drawing and molecular formula for the...Ch. 23 - Prob. 23.60SPCh. 23 - Prob. 23.61SPCh. 23 - Prob. 23.62SPCh. 23 - Prob. 23.63SPCh. 23 - Prob. 23.64SPCh. 23 - Prob. 23.65SPCh. 23 - Draw the complete electron-dot structure and...Ch. 23 - Prob. 23.67SPCh. 23 - Prob. 23.68SPCh. 23 - Prob. 23.69SPCh. 23 - Prob. 23.70SPCh. 23 - Prob. 23.71SPCh. 23 - Prob. 23.72SPCh. 23 - Prob. 23.73SPCh. 23 - Prob. 23.74SPCh. 23 - Prob. 23.75SPCh. 23 - Prob. 23.76SPCh. 23 - Prob. 23.77SPCh. 23 - Prob. 23.78SPCh. 23 - Prob. 23.79SPCh. 23 - Prob. 23.80SPCh. 23 - Prob. 23.81SPCh. 23 - Prob. 23.82SPCh. 23 - Prob. 23.83SPCh. 23 - Prob. 23.84SPCh. 23 - Prob. 23.85SPCh. 23 - Prob. 23.86SPCh. 23 - What does it mean to say that fats and oils are...Ch. 23 - Prob. 23.88SPCh. 23 - Prob. 23.89SPCh. 23 - Prob. 23.90SPCh. 23 - Prob. 23.91SPCh. 23 - Prob. 23.92SPCh. 23 - Prob. 23.93SPCh. 23 - Prob. 23.94SPCh. 23 - Prob. 23.95SPCh. 23 - Prob. 23.96SPCh. 23 - Prob. 23.97SPCh. 23 - Prob. 23.98SPCh. 23 - Prob. 23.99SPCh. 23 - Prob. 23.100SPCh. 23 - Prob. 23.101SPCh. 23 - Prob. 23.102SPCh. 23 - Prob. 23.103SPCh. 23 - Prob. 23.104SPCh. 23 - Prob. 23.105SPCh. 23 - Prob. 23.106SPCh. 23 - Prob. 23.107SPCh. 23 - Prob. 23.108SPCh. 23 - Prob. 23.109SPCh. 23 - Prob. 23.110SPCh. 23 - Prob. 23.111SPCh. 23 - Prob. 23.112SPCh. 23 - Prob. 23.113SPCh. 23 - What amino acids do the following abbreviations...Ch. 23 - Name and draw the structures of amino acids that...Ch. 23 - Identify the amino acids present in the following...Ch. 23 - Prob. 23.117SPCh. 23 - Prob. 23.118SPCh. 23 - Prob. 23.119SPCh. 23 - Prob. 23.120SPCh. 23 - Prob. 23.121SPCh. 23 - Prob. 23.122SPCh. 23 - Prob. 23.123SPCh. 23 - Prob. 23.124SPCh. 23 - Prob. 23.125SPCh. 23 - Prob. 23.126SPCh. 23 - Prob. 23.127SPCh. 23 - Prob. 23.128SPCh. 23 - Prob. 23.129SPCh. 23 - Prob. 23.130SPCh. 23 - Prob. 23.131SPCh. 23 - Prob. 23.132SPCh. 23 - Prob. 23.133SPCh. 23 - Prob. 23.134MPCh. 23 - Prob. 23.135MPCh. 23 - Cytochrome c is an important enzyme found in the...Ch. 23 - Prob. 23.137MPCh. 23 - Prob. 23.138MP
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