CHEMISTRY:CENTRAL SCI.-W/ACCESS>CUSTOM<
15th Edition
ISBN: 9781323233252
Author: Brown
Publisher: PEARSON C
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Chapter 23, Problem 22E
(a)
Interpretation Introduction
To determine:
The definition of the term coordination number.
(b)
Interpretation Introduction
To determine:
An example of a ligand that is neutral and one that is negatively charged.
(c)
Interpretation Introduction
To determine:
If the ligands that are positively charged are common.
(d)
Interpretation Introduction
To determine:
The type of
(e)
Interpretation Introduction
To determine:
The most common coordination numbers for metal complexes.
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 23 Solutions
CHEMISTRY:CENTRAL SCI.-W/ACCESS>CUSTOM<
Ch. 23.2 - Prob. 23.1.1PECh. 23.2 - Prob. 23.1.2PECh. 23.2 - Prob. 23.2.1PECh. 23.2 - Prob. 23.2.2PECh. 23.4 - The following mechanism has been proposed for the...Ch. 23.4 - Prob. 23.3.2PECh. 23.4 - Prob. 23.4.1PECh. 23.4 - Platinum nanoparticles of diameter ~2 nm are...Ch. 23.4 - 14.114 One of the many remarkable enzymes in the...Ch. 23.4 - 14.115N Suppose that, in the absence of catalyst,...
Ch. 23.5 - Prob. 23.6.1PECh. 23.5 - Dinitrogen pentoxide (N2O5) decomposes in...Ch. 23.6 - The reaction between ethyl iodide and hydroxide...Ch. 23.6 - Prob. 23.7.2PECh. 23.6 - Prob. 23.8.1PECh. 23.6 - Prob. 23.8.2PECh. 23 - Prob. 1DECh. 23 - Practice Exercise 1
If 8.0 g of NH4HS(s)...Ch. 23 - Practice Exercise 1 For the reaction 4 NH3(g) + 5...Ch. 23 - Prob. 3ECh. 23 - Prob. 4ECh. 23 - Phosphorus trichloride gas and chlorine gas react...Ch. 23 - Prob. 6ECh. 23 - Prob. 7ECh. 23 - 15.70 True or false: When the temperature of an...Ch. 23 - Prob. 9ECh. 23 - Prob. 10ECh. 23 - Prob. 11ECh. 23 - Prob. 12ECh. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Practice Exercise 2 For the reaction H2 (g) + I2...Ch. 23 - Prob. 17ECh. 23 - Prob. 18ECh. 23 - Prob. 19ECh. 23 - Practice Exercise 1
A mixture of gaseous sulfur...Ch. 23 - Prob. 21ECh. 23 - Prob. 22ECh. 23 - Practice Exercise 2
The gaseous compound BrCl...Ch. 23 - Prob. 24ECh. 23 - Practice Exercise 2 At 1000 k, the value of Kp for...Ch. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Practice Exercise 1 For the equilibrium Br2(g) +...Ch. 23 - Prob. 29ECh. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - Prob. 32ECh. 23 - Prob. 33ECh. 23 - Prob. 34ECh. 23 - Prob. 35ECh. 23 - 15.6 Ethene (C2H4) reacts with healogens (X2) by...Ch. 23 - When lead(IV) oxide is heated above 300 O C, it...Ch. 23 - Prob. 38ECh. 23 - The reactin A2(g) + B(g) + A(g) + AB(g) has an...Ch. 23 - The following graph represents the yield of the...Ch. 23 - Suppose that the gas-phase reactions A B and B A...Ch. 23 - Prob. 42ECh. 23 - Prob. 43ECh. 23 - Prob. 44ECh. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - Prob. 48ECh. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - Prob. 55ECh. 23 - Prob. 56ECh. 23 - Prob. 57ECh. 23 - Prob. 58ECh. 23 - For each of the following metals, write the...Ch. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65AECh. 23 - Prob. 66AECh. 23 - Prob. 67AECh. 23 - Prob. 68AECh. 23 - Prob. 69AECh. 23 - Prob. 70AECh. 23 - Prob. 71AECh. 23 - Prob. 72AECh. 23 - Prob. 73AECh. 23 - Prob. 74AECh. 23 - Prob. 75AECh. 23 - Prob. 76AECh. 23 - Prob. 77AECh. 23 - Prob. 78AECh. 23 - Prob. 79AECh. 23 - Prob. 80AECh. 23 - Prob. 81AECh. 23 - Prob. 82AECh. 23 - Prob. 83AECh. 23 - Prob. 84AECh. 23 - Prob. 85AECh. 23 - Prob. 86AECh. 23 - Prob. 87AECh. 23 - Prob. 88AECh. 23 - Prob. 89AECh. 23 - Prob. 90IECh. 23 - Prob. 91IECh. 23 - Prob. 92IECh. 23 - Prob. 93IECh. 23 - Prob. 94IECh. 23 - Prob. 95IECh. 23 - Prob. 96IECh. 23 - Prob. 97IECh. 23 - Prob. 98IECh. 23 - Prob. 99IECh. 23 - Prob. 100IECh. 23 - Prob. 101IE
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