GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 23, Problem 12E
By means of e chemical equation, give an example to represent the reaction of (a) a
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(c)
Suggest how the following boron species could be prepared, showing any
intermediates.
-B(OH)2
B(OH)2
(a) Why do transition elements show variable oxidation states?
(i) Name the element showing maximum number of oxidation states among the first series of transition metals from Sc (Z = 21) to Zn (Z = 30).
(ii) Name the element which shows only +3 oxidation state.
(b) What is lanthanoid contraction? Name an important alloy which contains some of the lanthanoid metals.
Write a balanced chemical equation for the reaction that occurs when (a) Mg(s) reacts with Cl21g2; (b) barium carbonate decomposes into barium oxide and carbon dioxide gas when heated; (c) the hydrocarbon styrene, C8H81l2, is combusted in air; (d) dimethylether, CH3OCH31g2, is combustedin air.
Chapter 23 Solutions
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 23 - By means of orbital diagrams, write electron...Ch. 23 - Arrange the following species according to the...Ch. 23 - Describe how the transition elements compare with...Ch. 23 - With only minor irregularities, the melting points...Ch. 23 - Why do the atomic radii vary so much for two...Ch. 23 - Prob. 6ECh. 23 - Which of me first transition series elements...Ch. 23 - Why is the number of common oxidation states for...Ch. 23 - As a group, the lanthanides are more reactive...Ch. 23 - The maximum difference in standard reduction...
Ch. 23 - Complete and balance the following equations. If...Ch. 23 - By means of e chemical equation, give an example...Ch. 23 - Prob. 13ECh. 23 - Prob. 14ECh. 23 - Prob. 15ECh. 23 - Prob. 16ECh. 23 - Prob. 17ECh. 23 - According to Figure 23-8, G decreases with...Ch. 23 - Prob. 19ECh. 23 - Prob. 20ECh. 23 - Write plausible half-equations to represent each...Ch. 23 - Prob. 22ECh. 23 - Use electrode potential data from this chapter or...Ch. 23 - You are given these three reducing agents: Zn(s);...Ch. 23 - Prob. 25ECh. 23 - Prob. 26ECh. 23 - Prob. 27ECh. 23 - Use data from the text to construct a standard...Ch. 23 - When a soluble lead compound is added to a...Ch. 23 - Prob. 30ECh. 23 - Prob. 31ECh. 23 - If CO2(g) under pressure is passed into...Ch. 23 - Use equation (23.19) to determine [Cr2O72] in a...Ch. 23 - If a solution is prepared by dissolving 1.505 g...Ch. 23 - Prob. 35ECh. 23 - Prob. 36ECh. 23 - Prob. 37ECh. 23 - Prob. 38ECh. 23 - Will reaction (23.25) still be spontaneous in the...Ch. 23 - Prob. 40ECh. 23 - Prob. 41ECh. 23 - Prob. 42ECh. 23 - Prob. 43ECh. 23 - Prob. 44ECh. 23 - Prob. 45ECh. 23 - Prob. 46ECh. 23 - Prob. 47ECh. 23 - At 400C , 2Hg(I)+O2(g)2HgO(s) for the reaction...Ch. 23 - Prob. 49ECh. 23 - Prob. 50ECh. 23 - Prob. 51ECh. 23 - Prob. 52ECh. 23 - Prob. 53ECh. 23 - Prob. 54ECh. 23 - The text notes that in small quantities, zinc is...Ch. 23 - Prob. 56ECh. 23 - What formulas would you expect for the metal...Ch. 23 - For the straight-line graphs in Figure 23-8...Ch. 23 - Prob. 59ECh. 23 - Prob. 60ECh. 23 - Prob. 61ECh. 23 - Prob. 62ECh. 23 - Prob. 63ECh. 23 - Prob. 64ECh. 23 - Prob. 65ECh. 23 - Prob. 66ECh. 23 - Prob. 67ECh. 23 - Prob. 68ECh. 23 - Prob. 69ECh. 23 - Prob. 70ECh. 23 - Prob. 71ECh. 23 - For a coordination number of four, the radius of...Ch. 23 - Prob. 73ECh. 23 - Prob. 74FPCh. 23 - Several transition metal ions are found in cation...Ch. 23 - Prob. 76SAECh. 23 - Briefly describe each of the following ideas. phe...Ch. 23 - Prob. 78SAECh. 23 - Prob. 79SAECh. 23 - Prob. 80SAECh. 23 - Prob. 81SAECh. 23 - Prob. 82SAECh. 23 - Prob. 83SAECh. 23 - Prob. 84SAECh. 23 - Prob. 85SAECh. 23 - Provide the missing name or formula for the...Ch. 23 - Prob. 87SAECh. 23 - Prob. 88SAECh. 23 - Prob. 89SAECh. 23 - Prob. 90SAE
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- Basic solutions of Na4XeO6, are powerful oxidants. What mass of Mn(NO3)26H2O reacts with 125.0 mL of a 0.1717 M basic solution of Na4XeO6 that contains an excess of sodium hydroxide if the products include Xe and solution of sodium permanganate?arrow_forwardWhy are the lanthanoid elements not found in nature in their elemental forms?arrow_forwardHow many cubic feet of air at a pressure of 760 torr and 0 C is required per ton of Fe2O3 to convert that Fe2O3 into iron in a blast furnace? For this exercise, assume air is 19% oxygen by volume.arrow_forward
- Using data in Appendix 1, estimate the temperature at which Fe2O3 can be reduced to iron, using hydrogen gas as a reducing agent (assume H2O(g) is the other product).arrow_forwardWhich is the stronger acid, HClO4 or HBrO4? Why?arrow_forwardThe following reactions are all similar to those of the industrial chemicals. Complete and balance the equations for these reactions: (a) reaction of a weak base and a strong acid. NH3+HClO4 (b) preparation of a soluble silver salt for silver plating. Ag2CO3+HNO3 (c) preparation of strontium hydroxide by electrolysis of a solution of strontium chloride SrCl2(aq)+H2O(l)electrolysisarrow_forward
- Balance the following equations by oxidation-reduction methods; note that three elements change oxidation state.. Co(NO3)2(s)Co2O3(s)+NO2(g)+O2(g)arrow_forwardThe ferrate ion, FeO42, is such a powerful oxidizing agent that in acidic solution, aqueous ammonia is reduced to elemental nitrogen along with the formation of the iron(III) ion. a. What is the oxidation state of iron in FeO42, and what is the electron configuration of iron in this polyatornic ion? b. lf 25.0 mL of a 0.243 M FeO42 solution is allowed to react with 55.0 mL of 1.45 M aqueous ammonia, what volume of nitrogen gas can form at 25C and 1.50 atm?arrow_forwardThe amount of sodium hypochlorite in a bleach solution can be determined by using a given volume of bleach to oxidize excess iodide ion to iodine; ClO- is reduced to Cl-. The amount of iodine produced by the redox reaction is determined by titration with sodium thiosulfate, Na2S2O3; I2 is reduced to I-. The sodium thiosulfate is oxidized to sodium tetrathionate, Na2S4O6. In this analysis, potassium iodide was added in excess to 5.00 mL of bleach (d=1.00g/cm3) . If 25.00 mL of 0.0700 M Na2S2O3 was required to reduce all the iodine produced by the bleach back to iodide, what is the mass percent of NaClO in the bleach?arrow_forward
- Write balanced chemical equations for the following reactions: (a) cadmium burned in air. (b) elemental cadmium added to a solution of hydrochloric acid. (c) cadmium hydroxide added to a solution of acetic acid, CH3CO2Harrow_forwardSodium perchlorate, NaClO4, is produced by electrolysis of sodium chlorate, NaClO3. If a current of 2.50 103 A passes through an electrolytic cell, how many kilograms of sodium perchlorate are produced per hour?arrow_forwardXenon trioxide, XeO3, is reduced to xenon in acidic solution by iodide ion. Iodide ion is oxidized to iodine, I2. Write a balanced chemical equation for the reaction.arrow_forward
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