EBK ORGANIC CHEMISTRY
9th Edition
ISBN: 8220100591310
Author: McMurry
Publisher: CENGAGE L
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Chapter 22.SE, Problem 50AP
One way to determine the number of acidic hydrogens in a molecule is to treat the compound with NaOD in D2O, isolate the product, and determine its molecular weight by mass spectrometry. For example, if cyclohexanone is treated with NaOD in D2O, the product has MW = 102. Explain how this method works.
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5. Calculate the total amount of heat transferred as 50 g of wat Specific heat H₂O (g) 2.00 J/g°C
-10 °C.
Specific heat H₂O (1)
Specific heat H₂O (s)
4.18 J/g°C
2.11 J/g°C
Heat of vaporization
2260 J/g
Heat of fusion
334 J/g
Melting point
0°C
6. Calculate the total amount of heat transferred as 25 g of
water is heated from 50 °C to 100 °C as a gas.
Boiling point
100 °C
Calculate the total amount of heat
transferred as 50 g of Water -10°C.
Calculate the total amount of heat
transferred as 25 g of water is heated
from 50°C to 100°C as a gas.
\table[[Specific heat H₂O(g), 2.00°C
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2
g
5. Calculate the total amount of heat transferred as 50 g of wat Specific heat H₂O (g) 2.00 J/g°C
-10 °C.
4.18 J/g°C
2.11 J/g°C
2260 J/g
334 J/g
Specific heat H₂O (1)
Specific heat H₂O (s)
Heat of vaporization
Heat of fusion
Melting point
6. Calculate the total amount of heat transferred as 25 g of
water is heated from 50 °C to 100 °C as a gas.
Boiling point
100 °C
0°C
Write formulas for ionic compounds composed of the following ions.
Use units as a guide to your solutions.
24. sodium and nitrate
25. calcium and chlorate
26. aluminum and carbonate
27.
CHALLENGE Write the formula for an ionic compound formed by ions from a group 2 element and polyatomic ions composed of only carbon and oxygen.show work step by step
Chapter 22 Solutions
EBK ORGANIC CHEMISTRY
Ch. 22.1 - Prob. 1PCh. 22.1 - How many acidic hydrogens does each of the...Ch. 22.1 - Prob. 3PCh. 22.3 - Write the complete mechanism for the deuteration...Ch. 22.3 - Prob. 5PCh. 22.4 - If methanol rather than water is added at the end...Ch. 22.5 - Prob. 7PCh. 22.5 - Draw a resonance structure of the acetonitrile...Ch. 22.6 - If methanol rather than water is added at the end...Ch. 22.7 - Prob. 10P
Ch. 22.7 - Draw a resonance structure of the acetonitrile...Ch. 22.7 - Why do you suppose ketone halogenations in acidic...Ch. 22.7 - Prob. 13PCh. 22.7 - Prob. 14PCh. 22.7 - Prob. 15PCh. 22.7 - Prob. 16PCh. 22.SE - Prob. 17VCCh. 22.SE - Prob. 18VCCh. 22.SE - Prob. 19VCCh. 22.SE - Prob. 20MPCh. 22.SE - Predict the product(s) and provide the mechanism...Ch. 22.SE - Predict the product(s) and provide the mechanism...Ch. 22.SE - Prob. 23MPCh. 22.SE - In the Hell–Volhard–Zelinskii reaction, only a...Ch. 22.SE - Prob. 25MPCh. 22.SE - Nonconjugated , -unsaturated ketones, such as...Ch. 22.SE - Prob. 27MPCh. 22.SE - Using curved arrows, propose a mechanism for the...Ch. 22.SE - Prob. 29MPCh. 22.SE - One of the later steps in glucose biosynthesis is...Ch. 22.SE - The Favorskii reaction involves treatment of an...Ch. 22.SE - Treatment of a cyclic ketone with diazomethane is...Ch. 22.SE - Prob. 33MPCh. 22.SE - Amino acids can be prepared by reaction of alkyl...Ch. 22.SE - Amino acids can also be prepared by a two-step...Ch. 22.SE - Heating carvone with aqueous sulfuric acid...Ch. 22.SE - Identify all the acidic hydrogens (pKa 25) in the...Ch. 22.SE - Rank the following compounds in order of...Ch. 22.SE - Prob. 39APCh. 22.SE - Base treatment of the following , -unsaturated...Ch. 22.SE - Prob. 41APCh. 22.SE - Prob. 42APCh. 22.SE - Prob. 43APCh. 22.SE - Which, if any, of the following compounds can be...Ch. 22.SE - Prob. 45APCh. 22.SE - Prob. 46APCh. 22.SE - Prob. 47APCh. 22.SE - How might you convert geraniol into either ethyl...Ch. 22.SE - Prob. 49APCh. 22.SE - One way to determine the number of acidic...Ch. 22.SE - Prob. 51APCh. 22.SE - Prob. 52APCh. 22.SE - Prob. 53APCh. 22.SE - Prob. 54APCh. 22.SE - Prob. 55APCh. 22.SE - Prob. 56APCh. 22.SE - All attempts to isolate primary and secondary...Ch. 22.SE - How would you synthesize the following compounds...Ch. 22.SE - Prob. 59APCh. 22.SE - Prob. 60APCh. 22.SE - Prob. 61APCh. 22.SE - Prob. 62APCh. 22.SE - As far back as the 16th century, South American...Ch. 22.SE - The key step in a reported laboratory synthesis of...Ch. 22.SE - Prob. 65AP
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- ADDITIONAL PRACTICE PRACTICE Problems Write formulas for ionic compounds composed of the following ions. Use units as a guide to your solutions. 24. sodium and nitrate 25. calcium and chlorate 26. aluminum and carbonate 27. CHALLENGE Write the formula for an ionic compound formed by ions from a group 2 element and polyatomic ions composed of only carbon and oxygen. ounds 1998arrow_forward7:35 < Dji Question 19 of 22 5G 50% Submit What is the pH of a buffer made from 0.350 mol of HBrO (Ka = 2.5 × 10-9) and 0.120 mol of KBRO in 2.0 L of solution? | 1 2 3 ☑ 4 5 6 C 7 8 ☐ 9 +/- Tap here for additional resources ||| 0 ×10 Гarrow_forwardaw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. B C Br HO O Substitution will not occur at a significant rate. Explanation Check + Х Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Accessibarrow_forward
- Complete the following reactions with the necessary reagents to complete the shown transformation. Example: 1. 2. ? 3. 018 Br OH Answer: H₂O, H2SO4, HgSO4arrow_forward7:34 • < Question 18 of 22 5G 50% Submit What is the pH of a buffer made from 0.220 mol of HCNO (Ka = 3.5 × 10-4) and 0.410 mol of NaCNO in 2.0 L of solution? 1 2 3 ☑ 4 5 6 C 7 8 | 9 +/- 0 ×10 Tap here for additional resources ||| Гarrow_forward6:46 ✔ 5G 58% < Question 7 of 22 Submit What is the primary species in solution at the halfway point in a titration of NH3 with HBr? A NH3 and H+ B NH₁+ and H+ C NH4+ D NH3 and NH4+ Tap here for additional resources |||arrow_forward
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