Michael donor and Michael acceptor need to be identified for the given set of compounds. Concept introduction: When a active methylene is deprotonated to form a carbanion ( Michael donor ) which acts as a nucleophile for 1,4-conjugate addition to α , β -unsaturated compound ( Michael acceptor ) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below, Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction. To Find : To find the Michael donor and Michael acceptor for the given compound.

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Answer 1

Question

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

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Answer 2

Question

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Expert Solution & Answer

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Answer 3

Question

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Expert Solution & Answer

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Answer 4

Question

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Expert Solution & Answer

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Check out a sample textbook solution

See solution

Answer 5

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 6

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 7

Chapter 22, Problem 94PP

(a)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Michael donor and Michael acceptor need to be identified for the given set of compounds.

Concept introduction:

When a active methylene is deprotonated to form a carbanion (Michael donor) which acts as a nucleophile for 1,4-conjugate addition to α,β -unsaturated compound (Michael acceptor) is known as Michael addition reaction. Michael reaction is thermodynamically controlled. A general scheme is shown below,

Please remember that 1,5-difunctionalization is the hallmark of Michael addition reaction.

To Find : To find the Michael donor and Michael acceptor for the given compound.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 22.1 - Prob. 1CC Ch. 22.1 - Prob. 2CC Ch. 22.1 - Prob. 3CC Ch. 22.1 - Prob. 1LTS Ch. 22.1 - Prob. 4PTS Ch. 22.1 - Prob. 5ATS Ch. 22.1 - Prob. 6CC Ch. 22.1 - Prob. 7CC Ch. 22.1 - Prob. 8CC Ch. 22.2 - Prob. 9CC

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Chapter 22 Solutions