GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
10th Edition
ISBN: 9781260699227
Author: Denniston
Publisher: MCGRAW-HILL HIGHER EDUCATION
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Question
Chapter 22, Problem 8MCP
Interpretation Introduction
Interpretation:
The effect of pyruvate dehydrogenase phosphatase deficiency on the rate of aerobic respiration, glycolysis, and, lactate fermentation has to be determined.
Concept Introduction:
Pyruvate dehydrogenase phosphatase also known as protein phosphatase is an enzyme in humans encoded by the PDP1 gene. It is an enzyme that serves to reverse the effects of pyruvate dehydrogenase kinase upon pyruvate dehydrogenase.
The pyruvate dehydrogenase complex catalyzes an irreversible reaction that converts pyruvate into acetyl CoA. Acetyl-CoA enters into the citric acid cycle produces NADH and carbon dioxide that provides energy in the form of ATP to the cell.
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3.
a.
Use the MS to propose at least two possible molecular formulas.
For an unknown compound:
101.
27.0
29.0
41.0
50.0
52.0
55.0
57.0
100
57.5
58.0
58.5
62.0
63.0
64.0
65.0
74.0
40
75.0
76.0
20
20
40
60
80
100
120
140
160
180
200 220
m/z
99.5
68564810898409581251883040
115.0
116.0
77404799
17417M
117.0
12.9
118.0
33.5
119.0
36
133 0
1.2
157.0
2.1
159.0
16
169.0
219
170.0
17
171.0
21.6
172.0
17
181.0
1.3
183.0
197.0
100.0
198.0
200.
784
Relative Intensity
2
2
8
ō (ppm)
6
2
Solve the structure and assign each of the following spectra (IR and C-NMR)
1.
For an unknown compound with a molecular formula of C8H100:
a.
What is the DU? (show your work)
b.
Solve the structure and assign each of the following spectra.
8
6
2
ō (ppm)
4
2
0
200
150
100
50
ō (ppm)
LOD
D
4000
3000
2000
1500
1000
500
HAVENUMBERI -11
Chapter 22 Solutions
GENERAL,ORGANIC,+BIOCHEMISTRY(LL)-PKG
Ch. 22.1 - Prob. 22.1QCh. 22.1 - How do the mitochondria differ from the other...Ch. 22.1 - Prob. 22.3QCh. 22.1 - Describe the evidence that suggests that...Ch. 22.2 - Prob. 22.5QCh. 22.2 - Prob. 22.6QCh. 22.3 - Prob. 22.7QCh. 22.3 - Prob. 22.8QCh. 22.6 - Prob. 22.9QCh. 22.6 - Write a balanced chemical equation for the...
Ch. 22.6 - Prob. 22.1PPCh. 22.7 - Prob. 22.11QCh. 22.7 - Prob. 22.12QCh. 22.8 - Prob. 22.13QCh. 22.8 - Prob. 22.14QCh. 22.9 - Prob. 22.15QCh. 22.9 - Prob. 22.16QCh. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Prob. 22.26QPCh. 22 - Prob. 22.27QPCh. 22 - Prob. 22.28QPCh. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - Prob. 22.33QPCh. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.41QPCh. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - To what class of enzymes does dinucleotide...Ch. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Explain why deficiencies of citric acid cycle...Ch. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Prob. 22.62QPCh. 22 - Prob. 22.63QPCh. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Prob. 22.71QPCh. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QPCh. 22 - Prob. 22.81QPCh. 22 - Prob. 22.82QPCh. 22 - Why is the glutamate family of transaminases so...Ch. 22 - Prob. 22.84QPCh. 22 - Prob. 22.85QPCh. 22 - Prob. 22.87QPCh. 22 - Prob. 22.88QPCh. 22 - Prob. 22.89QPCh. 22 - Prob. 22.90QPCh. 22 - Prob. 22.91QPCh. 22 - Prob. 22.92QPCh. 22 - Prob. 22.93QPCh. 22 - Prob. 22.94QPCh. 22 - Prob. 22.95QPCh. 22 - Prob. 22.96QPCh. 22 - Prob. 22.97QPCh. 22 - Prob. 22.98QPCh. 22 - Prob. 22.99QPCh. 22 - Prob. 22.100QPCh. 22 - Prob. 22.101QPCh. 22 - Prob. 22.102QPCh. 22 - Prob. 1MCPCh. 22 - Prob. 2MCPCh. 22 - Prob. 3MCPCh. 22 - Prob. 4MCPCh. 22 - Prob. 5MCPCh. 22 - Prob. 7MCPCh. 22 - Prob. 8MCPCh. 22 - Prob. 10MCPCh. 22 - Prob. 11MCP
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