The structures for the products of the given oxidation reactions are to be drawn. Concept introduction: When aldehyde reacts with atmospheric oxygen under acidic condition. They have a tendency to form carboxylic acids. The reaction is known as autoxidation reaction. It is a nucleophilic addition reaction to ( CO ) and aldehyde is oxidized to carboxylic acids. To determine: The structure for the product of the given oxidation reaction.
The structures for the products of the given oxidation reactions are to be drawn. Concept introduction: When aldehyde reacts with atmospheric oxygen under acidic condition. They have a tendency to form carboxylic acids. The reaction is known as autoxidation reaction. It is a nucleophilic addition reaction to ( CO ) and aldehyde is oxidized to carboxylic acids. To determine: The structure for the product of the given oxidation reaction.
Solution Summary: The author explains the structures for the products of the given oxidation reactions.
Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.
Chapter 22, Problem 72E
(a)
Interpretation Introduction
Interpretation: The structures for the products of the given oxidation reactions are to be drawn.
Concept introduction: When aldehyde reacts with atmospheric oxygen under acidic condition. They have a tendency to form carboxylic acids. The reaction is known as autoxidation reaction. It is a nucleophilic addition reaction to
(CO) and aldehyde is oxidized to carboxylic acids.
To determine: The structure for the product of the given oxidation reaction.
(b)
Interpretation Introduction
Interpretation: The structures for the products of the given oxidation reactions are to be drawn.
Concept introduction: When aldehyde reacts with atmospheric oxygen under acidic condition. They have a tendency to form carboxylic acids. The reaction is known as autoxidation reaction. It is a nucleophilic addition reaction to
(CO) and aldehyde is oxidized to carboxylic acids.
To determine: The structure for the product of the given oxidation reaction.
(c)
Interpretation Introduction
Interpretation: The structures for the products of the given oxidation reactions are to be drawn.
Concept introduction: When aldehyde reacts with atmospheric oxygen under acidic condition. They have a tendency to form carboxylic acids. The reaction is known as autoxidation reaction. It is a nucleophilic addition reaction to
(CO) and aldehyde is oxidized to carboxylic acids.
To determine: The structure for the product of the given oxidation reaction.
Q2: Ranking Acidity
a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly
explain the ranking. Use Table 2.2 as reference.
Ha
Нь
HC
H-N
Ha
OHe
b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is
more acidic? Explain. (Hint: use resonance structures to help)
Name the functional groups on atenolol.
H
H-N
atenolol
Ν
H-N
OH Н
Answer d, e, and f
If the rotational constant of a molecule is B = 120 cm-1, it can be stated that the transition from 2←1:a) gives rise to a line at 120 cm-1b) is a forbidden transitionc) gives rise to a line at 240 cm-1d) gives rise to a line at 480 cm-1
Chapter 22 Solutions
WebAssign for Zumdahl/Zumdahl/DeCoste's Chemistry, 10th Edition [Instant Access], Single-Term
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