ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX
4th Edition
ISBN: 9781119760702
Author: Klein
Publisher: WILEY
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Chapter 22, Problem 71PP
Interpretation Introduction

Interpretation: The mechanism of the given reaction has to be found

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules.  The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule.  A molecule that has several resonance structures is more stable than one with fewer.

To find: Explain the mechanism of the given reaction

Attack of acetyl chloride on pyrrole

ORGANIC CHEMISTRY,SOLNS...-ETEXT+BOX, Chapter 22, Problem 71PP

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CH3O OH OH O hemiacetal O acetal O neither O 0 O hemiacetal acetal neither OH hemiacetal O acetal O neither CH2 O-CH2-CH3 CH3-C-OH O hemiacetal O acetal CH3-CH2-CH2-0-c-O-CH2-CH2-CH3 O neither HO-CH2 ? 000 Ar B
What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 2 2. n-BuLi 3 Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. • Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure.
Predict the products of this organic reaction: NaBH3CN + NH2 ? H+ Click and drag to start drawing a structure. ×

Chapter 22 Solutions

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