(a) Interpretation: The structures for the major products of the given reactions are to be drawn. Concept introduction: When reagents such as HCl,HBr,and H 2 O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule. To determine: The structure for the major product of the given reaction.

Question

On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 min

Answer 1

Question

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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On the next page is an LC separation of the parabens found in baby wash. Parabens are suspected in a link to breast cancer therefore an accurate way to quantitate them is desired. a. In the chromatogram, estimate k' for ethyl paraben. Clearly indicate what values you used for all the terms in your calculation. b. Is this a "good" value for a capacity factor? Explain. c. What is the resolution between n-Propyl paraben and n-Butyl paraben? Again, indicate clearly what values you used in your calculation. MAU | Methyl paraben 40 20 0 -2 Ethyl paraben n-Propyl paraben n-Butyl paraben App ID 22925 6 8 min

d. In Figure 4, each stationary phase shows some negative correlation between plate count and retention factor. In other words, as k' increases, N decreases. Explain this relationship between k' and N. Plate Count (N) 4000 3500 2500 2000 1500 1000 Figure 4. Column efficiency (N) vs retention factor (k') for 22 nonionizable solutes on FMS (red), PGC (black), and COZ (green). 3000 Eluent compositions (acetonitrile/water, A/W) were adjusted to obtain k' less than 15, which was achieved for most solutes as follows: FMS (30/70 A/W), PGC (60/40), COZ (80/20). Slightly different compositions were used for the most highly retained solutes. All columns were 50 mm × 4.6 mm id and packed with 5 um particles, except for COZ, which was packed with 3 um particles. All other chromatographic conditions were constant: column length 5 cm, column j.§. 4.6 mm, flow rate 2 mL/min, column temperature 40 °C, and injection volume 0.5 μL Log(k'x/K'ethylbenzene) FMS 1.5 1.0 0.5 0.0 ཐྭ ཋ ཤྩ བྷྲ ; 500 0 5 10…

f. Predict how the van Deemter curve in Figure 7 would change if the temperature were raised from 40 °C to 55 °C. Figure 7. van Desmter curves in reduced coordinates for four nitroalkane homologues (nitropropane, black; nitrobutane, red; nitropentane, blue; and nitrohexane, green) separated on the FMS phase. Chromatographic conditions: column dimensions 50 mm × 4.6 mm id, eluent 30/70 ACN/water, flow rates 0.2-5.0 mL/min, injection volume 0.5 and column temperature 40 °C. No corrections to the plate heights have been made to account for extracolumn dispersion. Reduced Plate Height (h) ° 20 40 60 Reduced Velocity (v) 8. (2) A water sample is analyzed for traces of benzene using headspace analysis. The sample and standard are spiked with a fixed amount of toluene as an internal standard. The following data are obtained: Ppb benzene Peak area benzene Peak area toluene 10.0 252 376 Sample 533 368 What is the concentration of benzene in the sample?

Answer 2

Question

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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Answer 3

Question

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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Answer 4

Question

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

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Answer 5

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 6

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 7

Chapter 22, Problem 62E

Interpretation Introduction

(a)

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 8

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 9

(b)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 10

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 11

(c)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 12

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 13

(d)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 14

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 15

(e)

Interpretation Introduction

Interpretation: The structures for the major products of the given reactions are to be drawn.

Concept introduction: When reagents such as HCl,HBr,and H2O add across a carbon –carbon double or triple bond, with hydrogen forming a bond to one of the carbon atom in the multiple bond and Cl,Br or OH forming a bond to the other carbon atom in the multiple bond. These reactions occur through Markovnikov’s or Anti-Markovnikov’s addition. For, the addition occurs so that the hydrogen atom bonded to the carbon atom already has greater number of hydrogen atoms, it occurs through Markovnikov’s rule.

To determine: The structure for the major product of the given reaction.

Answer 16

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Answer 27

Ch. 22 - What is a hydrocarbon? What is the difference...Ch. 22 - Prob. 2RQ Ch. 22 - What are aromatic hydrocarbons? Benzene exhibits...Ch. 22 - Summarize the nomenclature rules for alkanes,...Ch. 22 - What functional group distinguishes each of the...Ch. 22 - Distinguish between isomerism and resonance....Ch. 22 - Prob. 7RQ Ch. 22 - Prob. 8RQ Ch. 22 - Prob. 9RQ Ch. 22 - Prob. 10RQ

Solution Summary: The author explains that the structures for the major products of the given reactions are to be drawn.

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