The structures of the final products formed in the following reactions are to be stated. Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants. To determine: The structure of C 5 H 12 .

Question

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Answer 1

Question

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 8

Figure 8

The isomer for the given reactant $C5H12O$ is $2,2-dimethylpropanol$ that is oxidized to give carboxylic acid.

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Answer 2

Question

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 8

Figure 8

The isomer for the given reactant $C5H12O$ is $2,2-dimethylpropanol$ that is oxidized to give carboxylic acid.

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Answer 3

Question

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 8

Figure 8

The isomer for the given reactant $C5H12O$ is $2,2-dimethylpropanol$ that is oxidized to give carboxylic acid.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 4

Question

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 8

Figure 8

The isomer for the given reactant $C5H12O$ is $2,2-dimethylpropanol$ that is oxidized to give carboxylic acid.

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Subscribe now to access step-by-step solutions to millions of textbook problems written by subject matter experts!

Answer 5

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 8

Figure 8

The isomer for the given reactant $C5H12O$ is $2,2-dimethylpropanol$ that is oxidized to give carboxylic acid.

Answer 6

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

Answer 7

Chapter 22, Problem 151CP

(a)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C5H12$ .

Answer 8

(a)

Expert Solution

Explanation of Solution

Explanation

The structure of $C5H12$ is shown in Figure 1.

The structure of $C5H12$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 1

Figure 1

The given reactant is $C5H12$ . As the monochlorination of the given reactant give two pairs of enantiomers. Therefore, the given reactant is $2-methyl-butane$ which consist of a parent chain of four carbon atoms having methyl group on second carbon whose structure is shown in Figure 1.

Answer 9

(a)

Expert Solution

Answer 10

(a)

Expert Solution

Answer 11

Expert Solution

Answer 12

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

Answer 13

(b)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of $C4H8$ .

Answer 14

(b)

Expert Solution

Explanation of Solution

Explanation

The structure of $C4H8$ is shown in Figure 2.

The structure of $C4H8$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 2

Figure 2

The given reactant reacts with water to form tertiary alcohol as the major product. As tertiary alcohols are formed by the dehydration of alkenes in which water add across the double bond. Therefore, the reactant should contain double bond. Hence, the reactant with $C4H8$ is $2-methyl-1-propene$ whose structure is shown in Figure 2.

Answer 15

(b)

Expert Solution

Answer 16

(b)

Expert Solution

Answer 17

Expert Solution

Answer 18

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

Answer 19

(c)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The two possible structures of $C7H12$ .

Answer 20

(c)

Expert Solution

Explanation of Solution

Explanation

The two possible structures of $C7H12$ are shown in Figure 3.

The two possible structures of $C7H12$ are,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 3

Figure 3

The given chemical formula is $C7H12$ and the major product formed in the reaction between $C7H12$ and hydrochloric acid is $1-chloro-1-methylcyclohexane$ . As the product contains cyclohexane it shows the presence of cyclohexane in the reactant molecule. The reaction between $C7H12$ and hydrochloric acid is an electrophilic addition reaction which indicate the reactant should possess double bond. Hence, the possible structures of $C7H12$ for this reaction are shown in Figure 3.

Answer 21

(c)

Expert Solution

Answer 22

(c)

Expert Solution

Answer 23

Expert Solution

Answer 24

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

Answer 25

(d)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The structure of hydrocarbon reacted with $H2O$ .

Answer 26

(d)

Expert Solution

Explanation of Solution

Explanation

The structure of hydrocarbon is shown in Figure 4.

The structure of hydrocarbon is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 4

Figure 4

The given hydrocarbon reacts with water which is further oxidized to give acetone. Therefore, the given hydrocarbon should be alkene which is propene as the major product is $2-propanone$ . Propene first reacts with water to form isopropyl alcohol which is further oxidized to give acetone as the major product.

Answer 27

(d)

Expert Solution

Answer 28

(d)

Expert Solution

Answer 29

Expert Solution

Answer 30

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 8

Figure 8

The isomer for the given reactant $C5H12O$ is $2,2-dimethylpropanol$ that is oxidized to give carboxylic acid.

Answer 31

(e)

Interpretation Introduction

Interpretation: The structures of the final products formed in the following reactions are to be stated.

Concept introduction: Organic compounds are synthesized through organic reactions. The different types of reactions in organic chemistry are elimination reaction, substitution reaction, addition reactions and many more. Addition reactions are takes place when two or more reactants combine to form a single product. Elimination reactions occur when a reactant broke down into two or more products and the substitution reactions takes place by an exchange in the reactants.

To determine: The possible structures for $C5H12O$ .

Answer 32

(e)

Expert Solution

Explanation of Solution

Explanation

The first possible structure for $C5H12O$ is shown in Figure 5.

The first possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 5

Figure 5

The major product for this reaction is carboxylic acid. Carboxylic acids are formed from the oxidation of alcohols. Therefore, the reactant should contain an alcoholic group. The chemical formula for the given reactant is $C5H12O$ . Hence, the reactant should be pentanol whose structure is shown in Figure 5.

The second possible structure for $C5H12O$ is shown in Figure 6.

The second possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 6

Figure 6

The isomer for the given reactant $C5H12O$ is $3-methylbutanol$ that is oxidized to give carboxylic acid.

The third possible structure for $C5H12O$ is shown in Figure 7.

The third possible structure for $C5H12O$ is,

Chemistry-Stud. Solution Guide, Chapter 22, Problem 151CP , additional homework tip 7

Figure 7

The isomer for the given reactant $C5H12O$ is $2-methylbutanol$ that is oxidized to give carboxylic acid.

The fourth possible structure for $C5H12O$ is shown in Figure 8.

The fourth possible structure for $C5H12O$ is,