ORGANIC CHEMISTRY (LOOSELEAF)
ORGANIC CHEMISTRY (LOOSELEAF)
6th Edition
ISBN: 9781260475630
Author: SMITH
Publisher: MCG
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Chapter 22, Problem 53P
Interpretation Introduction

Interpretation: The stepwise mechanism for the given Robinson annulation is to be drawn.

Concept introduction: Robinson annulation is a combination of Michael addition and intramolecular aldol condensation reactions. It takes place between an α,β-unsaturated carbonyl compound and a carbonyl compound. The enolate formation takes place from carbonyl compound which attacks the α,β-unsaturated carbonyl compound to form 1,5-dicarbonyl compound. This compound undergoes intramolecular aldol condensation which leads to the formation of a ring.

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