Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337670418
Author: Kotz
Publisher: Cengage
bartleby

Concept explainers

Question
Book Icon
Chapter 22, Problem 48PS

(a)

Interpretation Introduction

Interpretation: For the given complex the coordination number of cobalt has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

Oxidation number: It is the number that defines the number of electrons that are gained or lost by the chemical substance.

(b)

Interpretation Introduction

Interpretation: For the given complex the geometry of cobalt has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

Oxidation number: It is the number that defines the number of electrons that are gained or lost by the chemical substance.

(c)

Interpretation Introduction

Interpretation: For the given complex the oxidation number has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

Oxidation number: It is the number that defines the number of electrons that are gained or lost by the chemical substance.

(d)

Interpretation Introduction

Interpretation: For the given complex, the unpaired electrons has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

Oxidation number: It is the number that defines the number of electrons that are gained or lost by the chemical substance.

(e)

Interpretation Introduction

Interpretation: For the given complex the magnetic behavior of the central metal atom has to be determined.

Concept introduction: The transition metal atoms have tendency to form complex compounds that are linked to the certain neutral or ionic species which leads to the formation of coordination compounds. There exists a large number of coordination compounds that have a large number of applications in the chemical industry as well as in daily life.

The properties of the coordination compounds depend upon the primary and secondary valancy of the metal ion in the coordination sphere. The electrical conductivity depends upon the number of ions that are produced by complex.

The strong-field ligands results in pairing of electrons present in the complex and leads to diamagnetic species , while the low-field ligand do not have tendency to pair up the electrons therefore forms paramagnetic species.

The strong field ligands lead to splitting to a higher extent than the weak field ligands and the wavelength of light absorbed depends on the energy gap that is produced by a particular ligand.

The five d orbitals get divided into two sets that is dxy, dyz and dxz orbitals forms one set and dx2-y2and dz2 forms another set. The first set are oriented between the x, y and z axes whereas the second set gets oriented along the axis.

Electronic configuration: It is defined as the distribution of electrons present in the atom over orbitals following certain rules like electrons starts filling the lower energy orbital to higher energy, pairing of electrons does not occur until all the orbitals are singly filled and finally no electrons present in orbital can have same set of quantum numbers.

Oxidation number: It is the number that defines the number of electrons that are gained or lost by the chemical substance.

Blurred answer
Students have asked these similar questions
4. a) Give a suitable rationale for the following cyclization, stating the type of process involved (e.g. 9-endo-dig), clearly showing the mechanistic details at each step. H CO₂Me 1) NaOMe 2) H3O® CO₂Me
2. Platinum and other group 10 metals often act as solid phase hydrogenation catalysts for unsaturated hydrocarbons such as propylene, CH3CHCH2. In order for the reaction to be catalyzed the propylene molecules must first adsorb onto the surface. In order to completely cover the surface of a piece of platinum that has an area of 1.50 cm² with propylene, a total of 3.45 x 10¹7 molecules are needed. Determine the mass of the propylene molecules that have been absorbed onto the platinum surface.
Chem 141, Dr. Haefner 2. (a) Many main group oxides form acidic solutions when added to water. For example solid tetraphosphorous decaoxide reacts with water to produce phosphoric acid. Write a balanced chemical equation for this reaction. (b) Calcium phosphate reacts with silicon dioxide and carbon graphite at elevated temperatures to produce white phosphorous (P4) as a gas along with calcium silicate (Silcate ion is SiO3²-) and carbon monoxide. Write a balanced chemical equation for this reaction.

Chapter 22 Solutions

Chemistry & Chemical Reactivity

Ch. 22.7 - Prob. 2.2ACPCh. 22.7 - How are the d electrons of Pt distributed in a...Ch. 22.7 - What are the electron configurations for Nd and...Ch. 22.7 - Prob. 3.2ACPCh. 22.7 - Prob. 3.3ACPCh. 22.7 - Prob. 3.4ACPCh. 22 - Identify, based on the position in the periodic...Ch. 22 - Prob. 2PSCh. 22 - Prob. 3PSCh. 22 - Prob. 4PSCh. 22 - Prob. 5PSCh. 22 - Iron is the most abundant transition element in...Ch. 22 - Prob. 7PSCh. 22 - Prob. 8PSCh. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - The lanthanide contraction is given as an...Ch. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Prob. 17PSCh. 22 - Prob. 18PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33PSCh. 22 - Prob. 34PSCh. 22 - Prob. 35PSCh. 22 - Prob. 36PSCh. 22 - Prob. 37PSCh. 22 - Prob. 38PSCh. 22 - Prob. 39PSCh. 22 - Prob. 40PSCh. 22 - Prob. 41PSCh. 22 - Prob. 42PSCh. 22 - Prob. 43PSCh. 22 - Prob. 44PSCh. 22 - Prob. 45PSCh. 22 - Prob. 46PSCh. 22 - Prob. 47PSCh. 22 - Prob. 48PSCh. 22 - Prob. 49PSCh. 22 - Prob. 50PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 52PSCh. 22 - Prob. 53GQCh. 22 - Prob. 54GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 56GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 58GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 61GQCh. 22 - Prob. 62GQCh. 22 - Prob. 63GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 65GQCh. 22 - Prob. 66GQCh. 22 - Prob. 67GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 69GQCh. 22 - Prob. 70GQCh. 22 - Prob. 71GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 77GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 79GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 84GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 89SCQCh. 22 - Prob. 90SCQ
Knowledge Booster
Background pattern image
Chemistry
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
  • Text book image
    Chemistry
    Chemistry
    ISBN:9781305957404
    Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
    Publisher:Cengage Learning
    Text book image
    Chemistry: An Atoms First Approach
    Chemistry
    ISBN:9781305079243
    Author:Steven S. Zumdahl, Susan A. Zumdahl
    Publisher:Cengage Learning
    Text book image
    Chemistry
    Chemistry
    ISBN:9781133611097
    Author:Steven S. Zumdahl
    Publisher:Cengage Learning
  • Text book image
    Chemistry & Chemical Reactivity
    Chemistry
    ISBN:9781337399074
    Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
    Publisher:Cengage Learning
    Text book image
    Chemistry & Chemical Reactivity
    Chemistry
    ISBN:9781133949640
    Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
    Publisher:Cengage Learning
    Text book image
    Chemistry: Principles and Reactions
    Chemistry
    ISBN:9781305079373
    Author:William L. Masterton, Cecile N. Hurley
    Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781133611097
Author:Steven S. Zumdahl
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning