Chemistry & Chemical Reactivity
10th Edition
ISBN: 9781337670418
Author: Kotz
Publisher: Cengage
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Chapter 22, Problem 16PS
Interpretation Introduction
Interpretation: The element which has oxidized and reduced in the given reaction has to be determined.
Concept introduction:
Oxidation: If electrons are moved from a species during a chemical reaction. The species whose electrons are removed is said to be oxidized.
Reduction: If electrons are gained to a species during a chemical reaction. The species which gets electrons are said to be reduced.
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a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
a. The first three lines of this procedure describe the reaction used to make compound 5b. In the fourth line, hexane and sodium bicarbonate are added. What organic lab technique is being used here?
b. What is the purpose of the Na2SO4?
c. What equipment would you use to “concentrate [a solution] under reduced pressure”?
Chapter 22 Solutions
Chemistry & Chemical Reactivity
Ch. 22.4 - (a) What is the formula of a complex ion composed...Ch. 22.4 - (a) Determine the metals oxidation number and...Ch. 22.4 - Name the following coordination compounds. (a)...Ch. 22.5 - What types of isomers are possible for the...Ch. 22.6 - Prob. 22.5CYUCh. 22.7 - Prob. 22.6CYUCh. 22.7 - Prob. 1.1ACPCh. 22.7 - Copper has a face-centered cubic unit cell. If...Ch. 22.7 - Prob. 1.3ACPCh. 22.7 - If a patient is given 10.0 mg of cisplatin, what...
Ch. 22.7 - Prob. 2.2ACPCh. 22.7 - How are the d electrons of Pt distributed in a...Ch. 22.7 - What are the electron configurations for Nd and...Ch. 22.7 - Prob. 3.2ACPCh. 22.7 - Prob. 3.3ACPCh. 22.7 - Prob. 3.4ACPCh. 22 - Identify, based on the position in the periodic...Ch. 22 - Prob. 2PSCh. 22 - Prob. 3PSCh. 22 - Prob. 4PSCh. 22 - Prob. 5PSCh. 22 - Iron is the most abundant transition element in...Ch. 22 - Prob. 7PSCh. 22 - Prob. 8PSCh. 22 - Prob. 9PSCh. 22 - Prob. 10PSCh. 22 - Identify a cation of a first series transition...Ch. 22 - Match up the isoelectronic ions on the following...Ch. 22 - The lanthanide contraction is given as an...Ch. 22 - Prob. 14PSCh. 22 - Prob. 15PSCh. 22 - Prob. 16PSCh. 22 - Prob. 17PSCh. 22 - Prob. 18PSCh. 22 - Which of the following ligands is expected to be...Ch. 22 - One of the following nitrogen compounds or ions is...Ch. 22 - Prob. 21PSCh. 22 - Prob. 22PSCh. 22 - Prob. 23PSCh. 22 - Prob. 24PSCh. 22 - Prob. 25PSCh. 22 - Prob. 26PSCh. 22 - Prob. 27PSCh. 22 - Prob. 28PSCh. 22 - Prob. 29PSCh. 22 - Prob. 30PSCh. 22 - Give the name or formula for each ion or compound,...Ch. 22 - Prob. 32PSCh. 22 - Prob. 33PSCh. 22 - Prob. 34PSCh. 22 - Prob. 35PSCh. 22 - Prob. 36PSCh. 22 - Prob. 37PSCh. 22 - Prob. 38PSCh. 22 - Prob. 39PSCh. 22 - Prob. 40PSCh. 22 - Prob. 41PSCh. 22 - Prob. 42PSCh. 22 - Prob. 43PSCh. 22 - Prob. 44PSCh. 22 - Prob. 45PSCh. 22 - Prob. 46PSCh. 22 - Prob. 47PSCh. 22 - Prob. 48PSCh. 22 - Prob. 49PSCh. 22 - Prob. 50PSCh. 22 - In water, the titanium(III) ion, [Ti(H2O)6]3+, has...Ch. 22 - Prob. 52PSCh. 22 - Prob. 53GQCh. 22 - Prob. 54GQCh. 22 - How many unpaired electrons are expected for...Ch. 22 - Prob. 56GQCh. 22 - Which of the following complex ions is (are)...Ch. 22 - Prob. 58GQCh. 22 - How many geometric isomers are possible for the...Ch. 22 - For a tetrahedral complex of a metal in the first...Ch. 22 - Prob. 61GQCh. 22 - Prob. 62GQCh. 22 - Prob. 63GQCh. 22 - A platinum-containing compound, known as Magnuss...Ch. 22 - Prob. 65GQCh. 22 - Prob. 66GQCh. 22 - Prob. 67GQCh. 22 - How many geometric isomers of the complex ion...Ch. 22 - Prob. 69GQCh. 22 - Prob. 70GQCh. 22 - Prob. 71GQCh. 22 - The square-planar complex Pt(en)Cl2 has chloride...Ch. 22 - The complex [Mn(H2O)6]2+ has five unpaired...Ch. 22 - Experiments show that K4[Cr(CN)6] is paramagnetic...Ch. 22 - Give a systematic name or the formula for the...Ch. 22 - When CrCI3 dissolves in water, three different...Ch. 22 - Prob. 77GQCh. 22 - The glycinate ion, H2NCH2CO2, formed by...Ch. 22 - Prob. 79GQCh. 22 - Nickel and palladium both form complexes of the...Ch. 22 - The transition metals form a class of compounds...Ch. 22 - Cerium, as noted in Applying Chemical Principles:...Ch. 22 - Prob. 84GQCh. 22 - Two different coordination compounds containing...Ch. 22 - Prob. 89SCQCh. 22 - Prob. 90SCQ
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- When N,N-dimethylaniline is treated with bromine both the ortho and para products are observed. However when treated with a mixture of nitric acid and sulfuric acid only the meta product is observed. Explain these results and support your answer with the appropriate drawings *Hint amines are bases* N HNO3 H2SO4 N NO2 N Br2 N Br + N 8-8-8 FeBr3 Brarrow_forwardDraw a mechanism that explains the formation of compound OMe SO3H 1. Fuming H2SO4arrow_forwardConsider the following two acid-base reactions: OH OHI Based on what you know about the compounds and their acidity, which direction would you expect both of these reactions to proceed? Show your reasoning. A pKa table has been provided in case you need it. Functional group Example pka CHA -50 Alkane -35 Amine : NH3 Alkyne RH 25 Water HO-H 169 16 10 Protonated amines NH 10 5 Carboxylic acids OH Hydrochloric acid HCI A chemist intends to run the following reaction on the three substrates shown below: H₂O R-CI product room temp. Cl Cl (1) (2) (3) They find one will react quickly, one slowly, and one will not react at all. Which is which, and why? HINT: What is the reaction they're trying to do? Does that mechanism tell you anything about why something would be favored?arrow_forward
- NH3 decomposes through an equilibrium reaction between NH3, H2, and N2. Only one of the options is correct:(A). The mechanism of the NH3 decomposition reaction must necessarily involve the collision of two NH3 molecules to induce a rearrangement of the atoms in this molecule.(B). The molecular weight of the NH3 decomposition reaction is 2 since two NH3 molecules must collide.(C). The rate of the NH3 decomposition reaction must be greater than that of NH3 synthesis, since the former requires two molecules to collide and the latter, four.(D). The NH3 decomposition reaction cannot occur in a single step.arrow_forwardGiven the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 lowarrow_forwardA 2-step reaction has the following mechanism: | 1. (fast) R2 R+R 2. (slow) R+Q K₂ P k_1 What series does it have? (A). v= - = (k + k1 − k-1)[R2][Q] (B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q] (C). v=k₂[R]²[Q]² (D). v = k[R₂]1/2[Q]arrow_forward
- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
- Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forwardSteps and explanations. Also provide, if possible, ways to adress this kind of problems in general.arrow_forward
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