(a) Interpretation: The product that is formed from a Michael reaction of the given starting materials by using − OEt , EtOH is to be drawn. Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β − carbon of the other α , β − unsaturated carbonyl compound is known as Michael reaction. The α , β − unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 1

Question

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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d) Determine the formal charge on the nitrogen atom in each of the structures. NH3 NH2 N C бобкат : N N H H Н H2N-OH A B C D E F G

Lewis Structure, Hybridization & Molecular Geometry a) Draw the Lewis Structure of the molecules; Label the hybridization of each carbon atom; Predict the approximate molecular geometry around each carbon atom. CH3CHO CH3CN b) Draw the Lewis Structure of Nitromethane; Predict the approximate molecular geometry around the nitrogen atom. CH3NO2 c) Draw the Lewis Structure; Label the hybridization of the boron atom; Predict the approximate molecular geometry. BF3 BF4

a. The structure of the bicarbonate (hydrogen carbonate) ion, HCO3-, HCO3 " is best described as a hybrid of several contributing resonance forms, two of which are shown here. HO :0: HO + :Ö: Bicarbonate is crucial for the control of body pH (for example, blood pH 7.4). A more self-indulgent use is in baking soda, where it serves as a source of CO2 CO2 gas, which gives bread and pastry their fluffy constituency. (i) Draw at least one additional resonance form. = (ii) Using curved "electron-pushing" arrows, show how these Lewis structures may be interconverted by movement of electron pairs. (iii) Determine which form or forms will be the major contributor(s) to the real structure of bicarbonate, explaining your answer on the basis of the criteria in Section 1-5.

Answer 2

Question

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 3

Question

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 4

Question

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

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Answer 5

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 6

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 7

Chapter 22, Problem 43P

Interpretation Introduction

(a)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 8

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 9

Interpretation Introduction

(b)

Interpretation: The product that is formed from a Michael reaction of the given starting materials by using −OEt, EtOH is to be drawn.

Concept introduction: The reaction in which an enolate ion of one carbonyl compound undergoes conjugate addition reaction with the β−carbon of the other α,β−unsaturated carbonyl compound is known as Michael reaction. The α,β−unsaturated carbonyl compounds are also called as Michael acceptors.

Answer 10

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Answer 13

Ch. 22.1 - Prob. 1P Ch. 22.1 - Prob. 2P Ch. 22.1 - Problem 24.3 What unsaturated carbonyl compound is...Ch. 22.1 - Prob. 4P Ch. 22.1 - Prob. 5P Ch. 22.2 - Prob. 6P Ch. 22.2 - Problem 24.7 Draw the products formed in each...Ch. 22.4 - Prob. 15P Ch. 22.4 - Prob. 16P Ch. 22.5 - Problem 24.16 What ester is formed when each...

Solution Summary: The author explains that the product that is formed from a Michael reaction of the given starting materials by using -OEt is shown.

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Chapter 22 Solutions