ORGANIC CHEMISTRY-ACCESS
ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
Question
Book Icon
Chapter 22, Problem 41P
Interpretation Introduction

(a)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(b)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(c)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Interpretation Introduction

(d)

Interpretation: The starting materials that are needed to synthesize the given compound by a crossed Claisen reaction are to be shown.

Concept introduction: In crossed claisen condensation reaction, the base abstracts the acidic proton from α carbon atom of an ester to form enolate. This enolate reacts with carbonyl compound of other ester that leads to the formation of a β-ketoester. The crossed Claisen condensation always takes place between the two different carbonyl compounds.

Blurred answer
Students have asked these similar questions
Problem 3. Provide a mechanism for the following transformation: H₂SO A Me. Me Me Me Me
You are trying to decide if there is a single reagent you can add that will make the following synthesis possible without any other major side products: xi 1. ☑ 2. H₂O хе i Draw the missing reagent X you think will make this synthesis work in the drawing area below. If there is no reagent that will make your desired product in good yield or without complications, just check the box under the drawing area and leave it blank. Click and drag to start drawing a structure. There is no reagent that will make this synthesis work without complications. : ☐ S ☐
Predict the major products of this organic reaction: H OH 1. LiAlH4 2. H₂O ? Note: be sure you use dash and wedge bonds when necessary, for example to distinguish between major products with different stereochemistry. Click and drag to start drawing a structure. G C टे

Chapter 22 Solutions

ORGANIC CHEMISTRY-ACCESS

Knowledge Booster
Background pattern image
Similar questions
SEE MORE QUESTIONS
Recommended textbooks for you
Text book image
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Text book image
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Text book image
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Text book image
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Text book image
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Text book image
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY