Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
8th Edition
ISBN: 9780134581064
Author: Bruice, Paula Yurkanis
Publisher: Prentice Hall
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Question
Chapter 22, Problem 31P
Interpretation Introduction
Interpretation:
The compound having greatest rate of hydrolysis at
Concept introduction:
Catalyst: Substance which helps in increasing the rate of a particular reaction without getting consumed in the reaction.
Acid Catalyst: A catalyst which helps in increasing the rate of a particular reaction by the donation of a proton. There are two types of catalysis:
- Specific-acid catalysis: Proton is completely transferred before the slow step to the reactant in a reaction
- General-acid catalysis: Proton is completely transferred during the slow step to the reactant in a reaction
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Experiment 1
Data Table 1: Conservation of Mass - Initial Mass
Data Table 1
Data Table 2
Data Table 3
Data Table 4
Panel 1
Photo 1
Data Table 5
Reaction Mass of test tube and 5.0% HC₂H₂O2 (g)
#
(A)
(B)
Mass of NaHCO, (g) Mass of balloon and NaHCO, (g)
(C)
0.10
1
0829
14.38g
0.20
2
0.929
14.29g
0.35
1.00g
3
14.25g
0.50
1.14g
14.29
Experiment 1
Data Table 2: Moles of HC2H3O2
Reaction Volume of Mass of
Moles of HC₂H₂O₂
5.0%
Vinegar
(g)
(ML)
5.0
0.25
0042 mol
2
5.0
0.25
0042 mol
3
5.0
0.25
0042 mol
5.0
0.25
0042 mol
Experiment 1
Data Table 3: Moles of NaHCO3
Reaction Mass of NaHCO (g)
10g
20g
35g
50g
Experiment 1
Data Table 4: Theoretical Yield of CO₂
Reaction #
1
2
3
Experiment 1
Total mass before reaction (g)
(D=A+C)
15.29
15.21g
15.25g
15.349
Exercise 1
Data Table 1
Data Table 2
Data Table 3
Data Table 4
Panel 1
Photo 1
Data Table 5
Exercise 1-
Data Table 1
Data Table 2
DataTable 3
Data Table 4
Panel 1
Photo 1
Data Table 5
Exercise 1-
Moles of NaHCO
0012 mol
0025 mol
0044 mol
0062 mol…
The chemical reaction you investigated is a two-step reaction. What type of reaction occurs in each step? How did you determine your answer?
Chapter 22 Solutions
Organic Chemistry; Organic Chemistry Study Guide A Format: Kit/package/shrinkwrap
Ch. 22.2 - Compare each of the mechanisms listed here with...Ch. 22.2 - Prob. 3PCh. 22.2 - Prob. 4PCh. 22.3 - a. Draw the mechanism for the following reaction...Ch. 22.5 - Prob. 7PCh. 22.5 - Propose a mechanism for the Co2+ catalyzed...Ch. 22.6 - Prob. 9PCh. 22.7 - Prob. 10PCh. 22.7 - Prob. 12PCh. 22.7 - Prob. 13P
Ch. 22.9 - Which of the following amino acid side chains can...Ch. 22.9 - Which of the following C-terminal peptide bonds is...Ch. 22.9 - Carboxypeptidase A has esterase activity as well...Ch. 22.10 - Arginine and lysine side chains fit into trypsins...Ch. 22.10 - Explain why serine proteases do not catalyze...Ch. 22.11 - If H2 18O is used in the hydrolysis reaction...Ch. 22.11 - Draw the pH-activity profile for an enzyme that...Ch. 22.12 - The pHactivity profile for glucose-6-phosphate...Ch. 22.12 - Prob. 23PCh. 22.13 - Draw the mechanism for the hydroxide ion-catalyzed...Ch. 22.13 - What advantage does the enzyme gain by forming an...Ch. 22.13 - Prob. 26PCh. 22.13 - Prob. 27PCh. 22.13 - Aldolase shows no activity if it is incubated with...Ch. 22 - Which of the following parameters would be...Ch. 22 - Prob. 29PCh. 22 - Prob. 30PCh. 22 - Prob. 31PCh. 22 - Indicate the type of catalysis that is occurring...Ch. 22 - The deuterium kinetic isotope effect (KH2O/KD2O)...Ch. 22 - Prob. 34PCh. 22 - Co2+ catalyzes the hydrolysis of the lactam shown...Ch. 22 - there are two kinds of aldolases. Class I...Ch. 22 - Prob. 37PCh. 22 - The hydrolysis of the ester shown here is...Ch. 22 - Prob. 39PCh. 22 - At pH = 12, the rate of hydrolysis of ester A is...Ch. 22 - 2-Acetoxycyclohexyl tosylate reacts with acetate...Ch. 22 - Proof that an imine was formed between aldolase...Ch. 22 - Prob. 43PCh. 22 - a. Explain why the alkyl halide shown here reacts...Ch. 22 - Triosephosphate isomerase (TIM) catalyzes the...
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