Principles of Instrumental Analysis, 6th Edition
Principles of Instrumental Analysis, 6th Edition
6th Edition
ISBN: 9788131525579
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cenage Learning
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Chapter 22, Problem 22.7QAP

Calculate the theoretical potential of each of the following cells. Is the cell reaction spontaneous as written or spontaneous in the opposite direction?
(a) Pt|Cr3+(2.00 × 10-4M),Cr2+(1.50 × 10-3 M)||Pb2+ (5.60 0215 × 10-2M)|Pb
(b) Hg|Hg22+(2.00 × 10-2 M)||H+(1.50 × 10-2 M),V3+ (2.00 × 10-2M),VO2+(3.00 × 10-3M)|Pt
(e) Pt|Fe3+(3.00 × 10-2 M), Fe2+ (4.00 × 10-5M)||Sn2+ (3.50 × 10-2M), Sn4+ (5.50 × 10-4 M)|Pt

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