
Concept explainers
(a)
Interpretation:
The work done needed to increase the surface area of a pool of chloroform by
Concept introduction:
The atoms or molecules at the surface of the liquid are considered as a film. The atoms or molecules in bulk imply a force on the atoms or molecules at the surface of the liquid and tends to minimize the surface area of the liquid. This phenomenon is known as the surface tension of the liquid.

Answer to Problem 22.5E
The work done required to increase the surface area of a pool of chloroform by
Explanation of Solution
The work done to increase the surface area is calculated by the formula shown below.
Where,
•
•
The conversion of
Therefore, conversion of
The value of
Substitute the values of
The conversion of
Therefore,
The work done to increase the surface area of pool of chloroform by
(b)
Interpretation:
The work done to make the film of chloroform having area of
Concept introduction:
The atoms or molecules at the surface of the liquid are considered as a film. The atoms or molecules in bulk imply a force on the atoms or molecules at the surface of the liquid and tends to minimize the surface area of the liquid. This phenomenon is known as the surface tension of the liquid.

Answer to Problem 22.5E
The work done to make the film of chloroform having area of
Explanation of Solution
The making of film is same as increasing the surface area of a liquid. Therefore, the work done to make the film of chloroform is calculated by the formula given below.
Where,
•
•
The conversion of
Therefore, the conversion of
The conversion of
Therefore, the conversion of
The value of
Substitute the values of
The conversion of
Therefore,
The work done to make the film of chloroform having area of
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Chapter 22 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
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- What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.arrow_forwardWhat are the major products of the following organic reaction? Please include a detailed explanation as well as a drawing as to how the reaction proceeds.arrow_forwardPredict the organic product that forms in the reaction below: H + гон OH H+ H+ ☑ O Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the product. In the drawing area below, draw the skeletal ("line") structure of the missing organic product X. Explanation Check Click and drag to start drawing a structure. S 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forward
- In the analysis of Mg content in a 25 mL sample, a titration volume of 5 mL was obtained using 0.01 M EDTA. Calculate the Mg content in the sample if the Ca content is 20 ppmarrow_forwardPredict the organic products that form in the reaction below: H. H+ + OH H+ Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Explanation Check Click and drag to start drawing a structure. G X C © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center | Access +arrow_forward111 Carbonyl Chem Choosing reagants for a Wittig reaction What would be the best choices for the missing reagents 1 and 3 in this synthesis? 1. PPh3 3 1 2 2. n-BuLi • Draw the missing reagents in the drawing area below. You can draw them in any arrangement you like. Do not draw the missing reagent 2. If you draw 1 correctly, we'll know what it is. • Note: if one of your reagents needs to contain a halogen, use bromine. Explanation Check Click and drag to start drawing a structure. × ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Usearrow_forward
- A student proposes the transformation below in one step of an organic synthesis. There may be one or more reactants missing from the left-hand side, but there are no products missing from the right-hand side. There may also be catalysts, small inorganic reagents, and other important reaction conditions missing from the arrow. • Is the student's transformation possible? If not, check the box under the drawing area. . If the student's transformation is possible, then complete the reaction by adding any missing reactants to the left-hand side, and adding required catalysts, inorganic reagents, or other important reaction conditions above and below the arrow. • You do not need to balance the reaction, but be sure every important organic reactant or product is shown. + T X O O лет-ле HO OH HO OH This transformation can't be done in one step.arrow_forwardDetermine the structures of the missing organic molecules in the following reaction: X+H₂O H* H+ Y OH OH Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. X Sarrow_forwardPredict the major products of this organic reaction. If there aren't any products, because nothing will happen, check the box under the drawing area instead. No reaction. HO. O :☐ + G Na O.H Click and drag to start drawing a structure. XS xs H₂Oarrow_forward
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