Organic Chemistry: Principles And Mechanisms (second Edition)
2nd Edition
ISBN: 9780393630749
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Question
Chapter 22, Problem 22.54P
Interpretation Introduction
Interpretation:
Compounds A-G in the given synthesis scheme are to be identified.
Concept introduction:
Friedel craft acylation is the electrophilic substitution reaction in the presence of Lewis acid. In the haloform reaction, acetyl group is converted into haloform or carboxyl group through exhaustive halogenation. To convert the carboxylic group into acid chloride, thionyl chloride is used.
Nitration is the
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8. (16 pts) Provide the stepwise mechanism for the synthesis of the following compound via an enamine
Draw the titration curve of (i) weak acid vs. strong base; (ii) weak acid vs. weakbase; (iii) diprotic acid with strong base (iii) triprotic acid with strong base.
Complete the reaction in the drawing area below by adding the major products to the right-hand side.
If there won't be any products, because nothing will happen under these reaction conditions, check the box under the drawing area instead.
Note: if the products contain one or more pairs of enantiomers, don't worry about drawing each enantiomer with dash and wedge bonds. Just draw one molecule
to represent each pair of enantiomers, using line bonds at the chiral center.
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No reaction.
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1. Na O Me
Click and drag to start
drawing a structure.
2. H
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Chapter 22 Solutions
Organic Chemistry: Principles And Mechanisms (second Edition)
Ch. 22 - Prob. 22.1PCh. 22 - Prob. 22.2PCh. 22 - Prob. 22.3PCh. 22 - Prob. 22.4PCh. 22 - Prob. 22.5PCh. 22 - Prob. 22.6PCh. 22 - Prob. 22.7PCh. 22 - Prob. 22.8PCh. 22 - Prob. 22.9PCh. 22 - Prob. 22.10P
Ch. 22 - Prob. 22.11PCh. 22 - Prob. 22.12PCh. 22 - Prob. 22.13PCh. 22 - Prob. 22.14PCh. 22 - Prob. 22.15PCh. 22 - Prob. 22.16PCh. 22 - Prob. 22.17PCh. 22 - Prob. 22.18PCh. 22 - Prob. 22.19PCh. 22 - Prob. 22.20PCh. 22 - Prob. 22.21PCh. 22 - Prob. 22.22PCh. 22 - Prob. 22.23PCh. 22 - Prob. 22.24PCh. 22 - Prob. 22.25PCh. 22 - Prob. 22.26PCh. 22 - Prob. 22.27PCh. 22 - Prob. 22.28PCh. 22 - Prob. 22.29PCh. 22 - Prob. 22.30PCh. 22 - Prob. 22.31PCh. 22 - Prob. 22.32PCh. 22 - Prob. 22.33PCh. 22 - Prob. 22.34PCh. 22 - Prob. 22.35PCh. 22 - Prob. 22.36PCh. 22 - Prob. 22.37PCh. 22 - Prob. 22.38PCh. 22 - Prob. 22.39PCh. 22 - Prob. 22.40PCh. 22 - Prob. 22.41PCh. 22 - Prob. 22.42PCh. 22 - Prob. 22.43PCh. 22 - Prob. 22.44PCh. 22 - Prob. 22.45PCh. 22 - Prob. 22.46PCh. 22 - Prob. 22.47PCh. 22 - Prob. 22.48PCh. 22 - Prob. 22.49PCh. 22 - Prob. 22.50PCh. 22 - Prob. 22.51PCh. 22 - Prob. 22.52PCh. 22 - Prob. 22.53PCh. 22 - Prob. 22.54PCh. 22 - Prob. 22.55PCh. 22 - Prob. 22.56PCh. 22 - Prob. 22.57PCh. 22 - Prob. 22.58PCh. 22 - Prob. 22.59PCh. 22 - Prob. 22.60PCh. 22 - Prob. 22.61PCh. 22 - Prob. 22.62PCh. 22 - Prob. 22.63PCh. 22 - Prob. 22.64PCh. 22 - Prob. 22.65PCh. 22 - Prob. 22.66PCh. 22 - Prob. 22.67PCh. 22 - Prob. 22.1YTCh. 22 - Prob. 22.2YTCh. 22 - Prob. 22.3YTCh. 22 - Prob. 22.4YTCh. 22 - Prob. 22.5YTCh. 22 - Prob. 22.6YTCh. 22 - Prob. 22.7YTCh. 22 - Prob. 22.8YTCh. 22 - Prob. 22.9YTCh. 22 - Prob. 22.10YTCh. 22 - Prob. 22.11YTCh. 22 - Prob. 22.12YT
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- Predict the intermediate 1 and final product 2 of this organic reaction: NaOMe H+ + 1 2 H H work up You can draw 1 and 2 in any arrangement you like. Note: if either 1 or 2 consists of a pair of enantiomers, just draw one structure using line bonds instead of 3D (dash and wedge) bonds at the chiral center. Click and drag to start drawing a structure. X $ dmarrow_forwardPredict the major products of this organic reaction: 1. NaH (20°C) 2. CH3Br ? Some notes: • Draw only the major product, or products. You can draw them in any arrangement you like. • Be sure to use wedge and dash bonds where necessary, for example to distinguish between major products that are enantiomers. • If there are no products, just check the box under the drawing area. No reaction. Click and drag to start drawing a structure. G Crarrow_forwardPredict the major products of this organic reaction: 1. LDA (-78°C) ? 2. Br Some notes: • Draw only the major product, or products. You can draw them in any arrangement you like. . • Be sure to use wedge and dash bonds where necessary, for example to distinguish between major products that are enantiomers. • If there are no products, just check the box under the drawing area. No reaction. Click and drag to start drawing a structure. Xarrow_forward
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