Mechanism for the conversion of compound (A) to compound (B) has to be given. Concept Introduction: Acid catalyzed reactions: In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Question

Assign this HSQC Spectrum ( please editing clearly on the image)

Answer 1

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Assign this HSQC Spectrum ( please editing clearly on the image)

(a 4 shows scanning electron microscope (SEM) images of extruded actions of packing bed for two capillary columns of different diameters, al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the same stationary phase, spherical particles with 1-um diameter. A) When the columns were prepared, the figure shows that the column with the larger diameter has more packing irregularities. Explain this observation. B) Predict what affect this should have on band broadening and discuss your prediction using the van Deemter terms. C) Does this figure support your explanations in application question 33? Explain why or why not and make any changes in your answers in light of this figure. Figure 4 SEM images of sections of packed columns for a) 750 and b) 30-um-i.d. capillary columns.³

fcrip = ↓ bandwidth Il temp 32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual components of the van Deemter equation and consequently, band broadening? Increase temperature Longer column Using a gas mobile phase instead of liquid Smaller particle stationary phase Multiple Paths Diffusion Mass Transfer

Answer 2

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Answer 3

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Answer 4

Question

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

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Answer 5

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

Answer 6

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 7

Chapter 22, Problem 22.53P

(a)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (A) to compound (B) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Mechanism for the conversion of compound (C) to compound (D) has to be given.

Concept Introduction:

Acid catalyzed reactions:

In an organic synthesis reactions, most of the reactions are initiated by the abstraction of proton from acids by the reactant. Sulphuric acid is one of the reagent used for this purposes.

Answer 12

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Answer 13

(d)

Interpretation Introduction

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The chirality of amitriptyline and the number of possible stereoisomers has to be checked.

Concept Introduction:

Stereoisomers and chiral:

Isomers differing only in their spatial arrangement of atoms are called as stereoisomers.

The geometric property of a molecule that cannot be superimposed on its mirror image is known as chirality. Chiral carbon is the one which is attached with four different groups or atoms.

Answer 16

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Answer 27

Ch. 22.1 - Prob. 22.1P Ch. 22.1 - Write a structural formula for the product from...Ch. 22.1 - Prob. 22.3P Ch. 22.2 - Prob. 22.4P Ch. 22.2 - Predict the major produce(s) of each electrophilic...Ch. 22.3 - In SN2 reactions of haloalkanes, the order of...Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Addition of m-xylene to the strongly acidic...Ch. 22 - Addition of tert-butylbenzene to the strongly...

Solution Summary: The author explains how Sulphuric acid is used in acid catalyzed reactions, and the mechanism for conversion to amitriptyline reagents.

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Chapter 22 Solutions

Solution Summary: The author explains how Sulphuric acid is used in acid catalyzed reactions, and the mechanism for conversion to amitriptyline reagents.

Interpretation: For the conversion of compound (B) to compound (C) reagents has to be proposed. Concept Introduction: Grignard addition: It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Interpretation: For the conversion of compound (d) to amitriptyline reagents has to be proposed. Concept Introduction: SN2 reaction: SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.

Chapter 22 Solutions

Interpretation:

For the conversion of compound (B) to compound (C) reagents has to be proposed.

Concept Introduction:

Grignard addition:

It is an addition of organomagnesium halide to an aldehyde or ketone, to form a secondary or tertiary alcohol respectively.

Interpretation:

For the conversion of compound (d) to amitriptyline reagents has to be proposed.

Concept Introduction:

S_N2 reaction:

SN2 stands for bimolecular nucleophilic substitution reaction. In this type of reactions, simultaneous bond breaking and bond making steps are involved.