Co-ordination number of transition metal atom in each of the following complexes has to be given. (a) [ C o ( N O 2 ) 3 ( N H 3 ) 3 ] (b) N a [ F e ( H 2 O ) 2 ( O H ) 4 ] (c) [ C o ( e n ) 2 C l 2 ] I (d) [ N i C O 4 ] Concept introduction: Complex compounds are primarily formed by transition elements which are d-block elements. A co-ordination compound is known as a complex compound is made of metal atom/ion and ligand(s). Ligands are considered as Lewis bases and the central metal atom is Lewis acid. Ligands donate a pair of electron to metal ion and establish bonding with metal ion which is known as co-ordinate bond and hence these compounds are named as co-ordination compounds. The ligands represented inside the square brackets. Co-ordination number of a complex compound refers to the number of ligands bonded to central metal atom.

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of N2 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm ☑ 5 00. 18 Ar

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Question

Chapter 22, Problem 22.42QP

Interpretation Introduction

Interpretation:

Co-ordination number of transition metal atom in each of the following complexes has to be given.

(a) [Co(NO2)3(NH3)3] (b) Na[Fe(H2O)2(OH)4]

(c) [Co(en)2Cl2]I (d) [NiCO4]

Concept introduction:

Complex compounds are primarily formed by transition elements which are d-block elements. A co-ordination compound is known as a complex compound is made of metal atom/ion and ligand(s). Ligands are considered as Lewis bases and the central metal atom is Lewis acid. Ligands donate a pair of electron to metal ion and establish bonding with metal ion which is known as co-ordinate bond and hence these compounds are named as co-ordination compounds. The ligands represented inside the square brackets.

Co-ordination number of a complex compound refers to the number of ligands bonded to central metal atom.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of N2 tend to rise or fall? ☐ x10 fall Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of N2 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of N2 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no ☐ atm ☑ 5 00. 18 Ar

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ar