Chemistry: The Science in Context (Fourth Edition)
Chemistry: The Science in Context (Fourth Edition)
4th Edition
ISBN: 9780393124187
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster, Geoffrey Davies
Publisher: W. W. Norton & Company
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Chapter 22, Problem 22.1VP
Interpretation Introduction

Interpretation: The part of Figure P21.1 that best describes the periodic trend in monatomic cation radii moving up or down a group or across a period in the periodic table is to be stated.

Concept introduction: On moving up to down in a group, the principal quantum number ‘n’ increases. Number of shells of electrons increases down the group. Therefore, the size of cation increases down the group.

To determine: The part of Figure P21.1 that best describes the periodic trend in monatomic cation radii moving up or down a group or across a period in the periodic table.

Expert Solution & Answer
Check Mark

Answer to Problem 22.1VP

Solution

The part of Figure P21.1 that best describes the periodic trend in monatomic cation radii moving up or down a group or across a period in the periodic table is part (d).

Explanation of Solution

Explanation

The periodic trends in monatomic cation radii moving up or down a group or across a period in the periodic table are shown below.

Chemistry: The Science in Context (Fourth Edition), Chapter 22, Problem 22.1VP

Figure 1

A cation is formed when a neutral atom loses an electron. When an electron is lost, the electron-electron repulsion in an atom decreases. Hence, the interaction between nucleus and valence electrons increases. Therefore, the size of cation is less than the corresponding atom

On moving up to down in a group, the principal quantum number ‘n’ increases. Number of shells of electrons increases down the group. Therefore, the size of cation increases down the group. On moving right to left, the principal quantum number remains the same but the effective nuclear charge of electron increases. The atomic number of elements decreases. Therefore, the atomic radii of cation also increase on moving right to left across period.

The part that describes the trend in monatomic cation radii moving up or down a group or across a period in the periodic table is part (d) because in this part, cationic radii is increasing on moving down the group and on moving right to left in a period.

Conclusion

The part of Figure P21.1 that best describes the periodic trend in monatomic cation radii moving up or down a group or across a period in the periodic table is part (d).

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Chapter 22 Solutions

Chemistry: The Science in Context (Fourth Edition)

Ch. 22 - Prob. 22.6VPCh. 22 - Prob. 22.7VPCh. 22 - Prob. 22.8VPCh. 22 - Prob. 22.9VPCh. 22 - Prob. 22.10VPCh. 22 - Prob. 22.11QPCh. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - Prob. 22.14QPCh. 22 - Prob. 22.15QPCh. 22 - Prob. 22.16QPCh. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Prob. 22.26QPCh. 22 - Prob. 22.27QPCh. 22 - Prob. 22.28QPCh. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - Prob. 22.33QPCh. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - Prob. 22.41QPCh. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - Prob. 22.55QPCh. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Prob. 22.62QPCh. 22 - Prob. 22.63QPCh. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Prob. 22.71QPCh. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QPCh. 22 - Prob. 22.81QPCh. 22 - Prob. 22.82QPCh. 22 - Prob. 22.83QPCh. 22 - Prob. 22.84QPCh. 22 - Prob. 22.85QPCh. 22 - Prob. 22.86QPCh. 22 - Prob. 22.87QPCh. 22 - Prob. 22.88QPCh. 22 - Prob. 22.89QPCh. 22 - Prob. 22.90QPCh. 22 - Prob. 22.91QPCh. 22 - Prob. 22.92QPCh. 22 - Prob. 22.93QPCh. 22 - Prob. 22.94QPCh. 22 - Prob. 22.95QPCh. 22 - Prob. 22.96QPCh. 22 - Prob. 22.97QPCh. 22 - Prob. 22.98QPCh. 22 - Prob. 22.99QPCh. 22 - Prob. 22.100QP
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