Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 22, Problem 19QE
Interpretation Introduction
Interpretation:
Molecular formula of noncyclic
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Identifying electron-donating and
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
NH2
○ donating
NO2
Explanation
Check
withdrawing
no inductive effects
Resonance Effects
Overall Electron-Density
○ donating
O withdrawing
O no resonance effects
O donating
O withdrawing
O donating
withdrawing
O no inductive effects
Ono resonance effects
O electron-rich
electron-deficient
O similar to benzene
O electron-rich
O electron-deficient
O similar to benzene
olo
18
Ar
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
Х
(Choose one)
OH
(Choose one)
OCH3
(Choose one)
OH
(Choose one)
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Assign R or S to all the chiral centers in each compound drawn below
porat
bg
9
Br
Br
Chapter 22 Solutions
Chemistry Principles And Practice
Ch. 22 - Prob. 1QECh. 22 -
Explain what is special about the element carbon...Ch. 22 - Prob. 3QECh. 22 - Prob. 4QECh. 22 - Prob. 5QECh. 22 - Prob. 6QECh. 22 - Prob. 7QECh. 22 - Prob. 8QECh. 22 - Prob. 9QECh. 22 - Prob. 10QE
Ch. 22 - Prob. 11QECh. 22 - Prob. 12QECh. 22 - Prob. 13QECh. 22 - Prob. 14QECh. 22 - Prob. 15QECh. 22 - Prob. 16QECh. 22 - Prob. 17QECh. 22 - Prob. 18QECh. 22 - Prob. 19QECh. 22 - Prob. 20QECh. 22 - Prob. 21QECh. 22 - Prob. 22QECh. 22 - Prob. 23QECh. 22 - Prob. 24QECh. 22 - Prob. 25QECh. 22 - Prob. 26QECh. 22 - Prob. 27QECh. 22 - Prob. 28QECh. 22 - Prob. 29QECh. 22 - Prob. 30QECh. 22 - Prob. 31QECh. 22 - Prob. 32QECh. 22 - Prob. 33QECh. 22 - Prob. 34QECh. 22 - Prob. 35QECh. 22 - Prob. 36QECh. 22 - Prob. 37QECh. 22 - Prob. 38QECh. 22 - Prob. 39QECh. 22 - Prob. 40QECh. 22 - Prob. 41QECh. 22 - Prob. 42QECh. 22 - Prob. 43QECh. 22 - Prob. 44QECh. 22 - Prob. 45QECh. 22 - Prob. 46QECh. 22 - Prob. 47QECh. 22 - Prob. 48QECh. 22 - Prob. 49QECh. 22 - Prob. 50QECh. 22 - Prob. 51QECh. 22 - Prob. 52QECh. 22 - Prob. 53QECh. 22 - Prob. 54QECh. 22 - Name the following compounds. (a) FCH2CH2CH2OH (b)...Ch. 22 - Prob. 56QECh. 22 - Prob. 57QECh. 22 - Prob. 58QECh. 22 - Prob. 59QECh. 22 - Prob. 60QECh. 22 - Prob. 61QECh. 22 - Prob. 62QECh. 22 - Prob. 63QECh. 22 - Prob. 64QECh. 22 - Prob. 65QECh. 22 - Prob. 66QECh. 22 - Prob. 67QECh. 22 - Prob. 68QECh. 22 - Prob. 69QECh. 22 - Prob. 70QECh. 22 - Prob. 71QECh. 22 - Prob. 72QECh. 22 - Prob. 73QECh. 22 - Prob. 74QECh. 22 - Prob. 75QECh. 22 - Prob. 76QECh. 22 - Prob. 77QECh. 22 - Prob. 78QECh. 22 - Prob. 79QECh. 22 - Prob. 80QECh. 22 - Prob. 81QECh. 22 - Prob. 82QECh. 22 - Prob. 83QECh. 22 - Prob. 84QECh. 22 - Prob. 85QECh. 22 - Prob. 86QECh. 22 - Prob. 87QECh. 22 - Prob. 88QE
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- (c) (4pts) Mechanism: heat (E1) CH3OH + 1.5pts each _E1 _ (1pt) Br CH3OH (d) (4pts) Mechanism: SN1 (1pt) (e) (3pts) 1111 I H 10 Ill!! H LDA THF (solvent) Mechanism: E2 (1pt) NC (f) Bri!!!!! CH3 NaCN (3pts) acetone Mechanism: SN2 (1pt) (SN1) -OCH3 OCH3 1.5pts each 2pts for either product 1pt if incorrect stereochemistry H Br (g) “,、 (3pts) H CH3OH +21 Mechanism: SN2 (1pt) H CH3 2pts 1pt if incorrect stereochemistry H 2pts 1pt if incorrect stereochemistryarrow_forwardA mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixturearrow_forwardQ5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forward
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