Chemistry: Structure and Properties Plus MasteringChemistry with eText -- Access Card Package
1st Edition
ISBN: 9780321729736
Author: Nivaldo J. Tro
Publisher: PEARSON
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Chapter 22, Problem 117E
Interpretation Introduction
Interpretation:
“Free radical fluorination of methane is uncontrollably violent but free radical iodination is a very poor reaction” should be identified.
Concept introduction:
Halogenation of methane is a homolytic reaction in which a bond breaks into equivalent free radical that are responsible for heat generation and this heat further used for to further running the reaction.
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Students have asked these similar questions
5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 22 Solutions
Chemistry: Structure and Properties Plus MasteringChemistry with eText -- Access Card Package
Ch. 22 - Prob. 1SAQCh. 22 - Prob. 2SAQCh. 22 - Prob. 3SAQCh. 22 - Prob. 4SAQCh. 22 - Prob. 5SAQCh. 22 - Prob. 6SAQCh. 22 - Prob. 7SAQCh. 22 - Prob. 8SAQCh. 22 - Prob. 9SAQCh. 22 - Prob. 10SAQ
Ch. 22 - Prob. 1ECh. 22 - Prob. 2ECh. 22 - Prob. 3ECh. 22 - Prob. 4ECh. 22 - Prob. 5ECh. 22 - Prob. 6ECh. 22 - Prob. 7ECh. 22 - What are the main classifications of hydrocarbons?...Ch. 22 - Prob. 9ECh. 22 - What are structural isomers? How do the properties...Ch. 22 - Prob. 11ECh. 22 - Define each term related to optical isomerism:...Ch. 22 - Prob. 13ECh. 22 - Prob. 14ECh. 22 - Explain geometric isomerism in alkenes. How do the...Ch. 22 - Prob. 16ECh. 22 - Prob. 17ECh. 22 - Prob. 18ECh. 22 - Prob. 19ECh. 22 - Prob. 20ECh. 22 - Prob. 21ECh. 22 - Prob. 22ECh. 22 - Prob. 23ECh. 22 - Prob. 24ECh. 22 - Prob. 25ECh. 22 - Prob. 26ECh. 22 - Prob. 27ECh. 22 - Prob. 28ECh. 22 - Prob. 29ECh. 22 - Prob. 30ECh. 22 - Prob. 31ECh. 22 - Prob. 32ECh. 22 - Prob. 33ECh. 22 - How do an addition polymer and a condensation...Ch. 22 - Prob. 35ECh. 22 - Prob. 36ECh. 22 - Prob. 37ECh. 22 - Prob. 38ECh. 22 - Prob. 39ECh. 22 - Prob. 40ECh. 22 - Prob. 41ECh. 22 - Prob. 42ECh. 22 - Name each alkane.Ch. 22 - Prob. 44ECh. 22 - Prob. 45ECh. 22 - Draw a structure for each alkane. a....Ch. 22 - Prob. 47ECh. 22 - Complete and balance each hydrocarbon combustion...Ch. 22 - Prob. 49ECh. 22 - Prob. 50ECh. 22 - Prob. 51ECh. 22 - Prob. 52ECh. 22 - Name each alkene.Ch. 22 - Prob. 54ECh. 22 - Prob. 55ECh. 22 - Name each alkyne.Ch. 22 - Draw the correct structure for each compound. a....Ch. 22 - Prob. 58ECh. 22 - Prob. 59ECh. 22 - Prob. 60ECh. 22 - Prob. 61ECh. 22 - Prob. 62ECh. 22 - Prob. 63ECh. 22 - Prob. 64ECh. 22 - Prob. 65ECh. 22 - Prob. 66ECh. 22 - Prob. 67ECh. 22 - Prob. 68ECh. 22 - Prob. 69ECh. 22 - Prob. 70ECh. 22 - Prob. 71ECh. 22 - Prob. 72ECh. 22 - Prob. 73ECh. 22 - Prob. 74ECh. 22 - Prob. 75ECh. 22 - Prob. 76ECh. 22 - Prob. 77ECh. 22 - Prob. 78ECh. 22 - Prob. 79ECh. 22 - Prob. 80ECh. 22 - Prob. 81ECh. 22 - Prob. 82ECh. 22 - Prob. 83ECh. 22 - Prob. 84ECh. 22 - Prob. 85ECh. 22 - Prob. 86ECh. 22 - Prob. 87ECh. 22 - Prob. 88ECh. 22 - Prob. 89ECh. 22 - Prob. 90ECh. 22 - Prob. 91ECh. 22 - Prob. 92ECh. 22 - Prob. 93ECh. 22 - Prob. 94ECh. 22 - Identify each organic compound as an alkane,...Ch. 22 - Identify each organic compound as an alkane,...Ch. 22 - Prob. 97ECh. 22 - Prob. 98ECh. 22 - Prob. 99ECh. 22 - Determine whether each pair of structures are...Ch. 22 - Prob. 101ECh. 22 - Prob. 102ECh. 22 - Classify each organic reaction as combustion,...Ch. 22 - Prob. 104ECh. 22 - Prob. 105ECh. 22 - Prob. 106ECh. 22 - Prob. 107ECh. 22 - Prob. 108ECh. 22 - Prob. 109ECh. 22 - Prob. 110ECh. 22 - Prob. 111ECh. 22 - Prob. 112ECh. 22 - Prob. 113ECh. 22 - Prob. 114ECh. 22 - Prob. 115ECh. 22 - Prob. 116ECh. 22 - Prob. 117ECh. 22 - Prob. 118ECh. 22 - Prob. 119ECh. 22 - Prob. 120ECh. 22 - Draw the structure and name a compound with the...Ch. 22 - Prob. 122E
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