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Interpretation:
The product formed at electrode of cell in which lead(II)nitrate is electrolyzed has to be identified using the half reactions.
Concept Introduction:
Oxidation: The gain of oxygen or the loss of hydrogen or the loss of an electron in a species during a
Reduction: The loss of oxygen or the gain of hydrogen or the gain of an electron in a species during a redox reaction is called as reduction.
Oxidizing agent: The substance that is oxidized is called as a reducing agent.
Reducing agent: The substance that is reduced is called as an oxidizing agent.
The standard cell potential for voltaic cell is determined by subtracting the electrode potential of cathode and the electrode potential of anode.
The negative cell potential of a redox reaction indicates that the reaction is not spontaneous which shows that the standard free energy should be less than 0. The reverse reaction of this will be definitely a spontaneous reaction with cell potential value greater than 0.
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Chapter 21 Solutions
Connect 2-Year Access Card for Chemistry: The Molecular Nature of Matter and Change
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- 1. Consider a pair of elements with 2p and 4p valence orbitals (e.g., N and Se). Draw their (2p and 4p AO's) radial probability plots, and sketch their angular profiles. Then, consider these orbitals from the two atoms forming a homonuclear л-bond. Which element would have a stronger bond, and why? (4 points)arrow_forwardWrite the reaction and show the mechanism of the reaction. Include the mechanism for formation of the NO2+ 2. Explain, using resonance structures, why the meta isomer is formed. Draw possible resonance structures for ortho, meta and para.arrow_forwardNonearrow_forward
- 3. A molecular form of "dicarbon", C2, can be generated in gas phase. Its bond dissociation energy has been determined at 599 kJ/mol. Use molecular orbital theory to explain why energy of dissociation for C₂+ is 513 kJ/mol, and that for C2² is 818 kJ/mol. (10 points)arrow_forward9.73 g of lead(IV) chloride contains enough Cl- ions to make ____ g of magnesium chloride.arrow_forward6. a) C2's. Phosphorus pentafluoride PF5 belongs to D3h symmetry group. Draw the structure of the molecule, identify principal axis of rotation and perpendicular (4 points) b) assume that the principal axis of rotation is aligned with z axis, assign symmetry labels (such as a1, b2, etc.) to the following atomic orbitals of the P atom. (character table for this group is included in the Supplemental material). 3s 3pz (6 points) 3dz²arrow_forward
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