The given transformation should be explained by using Stork enamine synthesis Concept introduction: The addition of an enamine to α , β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are, Formation of an enamine Michael addition Hydrolysis To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

• Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peak

Could you redraw these and also explain how to solve them for me pleas

None

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 6

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 7

Chapter 21.6, Problem 38PTS

(a)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The given transformation should be explained by using Stork enamine synthesis

Concept introduction:

The addition of an enamine to α,β -unsaturated carbonyl acceptor (Michael acceptor) to form dicarbonyl compound is known as Stork enamine synthesis. The difference between Michael addition and stork enamine is that for Michael addition to take place the enolate formed should be doubly stabilized. The product is then hydrolyzed by an aqueous acid to produce 1,5-dicarbonyl compound. Steps involved in Stork enamine synthesis are,

Formation of an enamine

Michael addition

Hydrolysis

To find : To find the reagents used for the given transformation using Stork enamine synthesis.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 21.1 - Prob. 1CC Ch. 21.1 - Prob. 2CC Ch. 21.1 - Prob. 3CC Ch. 21.1 - Prob. 1LTS Ch. 21.1 - Prob. 4PTS Ch. 21.1 - APPLY the skill As with aldehydes and ketones, the...Ch. 21.1 - Draw the enolate ion that is formed when each of...Ch. 21.1 - Prob. 7CC Ch. 21.2 - Prob. 8CC Ch. 21.2 - Prob. 9CC

Want to see the full answer?

Chapter 21 Solutions