ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
4th Edition
ISBN: 9781119745105
Author: Klein
Publisher: WILEY
Question
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Chapter 21.3, Problem 14PTS

(a)

Interpretation Introduction

Interpretation:

To predict the major product of when aldehyde is treated with aqueous sodium hydroxide

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of sodium hydroxide.  The name Aldol stands for aldehyde and alcohol ( ald for “aldehyde” and ol for “alcohol”).  The three steps involved in aldol addition reaction is,

  • Deprotonation of α carbon
  • Attach of enolate ion with the aldehyde (nucleophilic attack)
  • Protonation of the alkoxide ion to give aldol product

(b)

Interpretation Introduction

Interpretation:

To predict the major product of when aldehyde is treated with aqueous sodium hydroxide

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of sodium hydroxide.  The name Aldol stands for aldehyde and alcohol ( ald for “aldehyde” and ol for “alcohol”).  The three steps involved in aldol addition reaction is,

  • Deprotonation of α carbon
  • Attach of enolate ion with the aldehyde (nucleophilic attack)
  • Protonation of the alkoxide ion to give aldol product

(c)

Interpretation Introduction

Interpretation:

To predict the major product of when aldehyde is treated with aqueous sodium hydroxide

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of sodium hydroxide.  The name Aldol stands for aldehyde and alcohol ( ald for “aldehyde” and ol for “alcohol”).  The three steps involved in aldol addition reaction is,

  • Deprotonation of α carbon
  • Attach of enolate ion with the aldehyde (nucleophilic attack)
  • Protonation of the alkoxide ion to give aldol product

(d)

Interpretation Introduction

Interpretation:

To predict the major product of when aldehyde is treated with aqueous sodium hydroxide

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of sodium hydroxide.  The name Aldol stands for aldehyde and alcohol ( ald for “aldehyde” and ol for “alcohol”).  The three steps involved in aldol addition reaction is,

  • Deprotonation of α carbon
  • Attach of enolate ion with the aldehyde (nucleophilic attack)
  • Protonation of the alkoxide ion to give aldol product

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Chapter 21 Solutions

ORGANIC CHEMISTRY

Ch. 21.2 - Prob. 10CCCh. 21.2 - Prob. 11CCCh. 21.2 - Prob. 12CCCh. 21.2 - Prob. 13CCCh. 21.3 - Prob. 2LTSCh. 21.3 - Prob. 14PTSCh. 21.3 - Prob. 15PTSCh. 21.3 - Prob. 3LTSCh. 21.3 - Prob. 4LTSCh. 21.3 - Prob. 19PTSCh. 21.3 - Prob. 21CCCh. 21.3 - Prob. 22CCCh. 21.3 - Prob. 23CCCh. 21.4 - Prob. 24CCCh. 21.4 - Prob. 25CCCh. 21.4 - Prob. 26CCCh. 21.4 - Prob. 27CCCh. 21.4 - Prob. 28CCCh. 21.5 - Prob. 29CCCh. 21.5 - Prob. 30CCCh. 21.5 - Prob. 5LTSCh. 21.5 - Prob. 31PTSCh. 21.5 - Prob. 6LTSCh. 21.5 - Prob. 33PTSCh. 21.5 - Prob. 34ATSCh. 21.6 - Prob. 35CCCh. 21.6 - Prob. 36CCCh. 21.6 - Prob. 37CCCh. 21.6 - Prob. 7LTSCh. 21.6 - Prob. 38PTSCh. 21.7 - Prob. 8LTSCh. 21.7 - Prob. 42PTSCh. 21.7 - Prob. 43PTSCh. 21 - Prob. 47PPCh. 21 - Prob. 48PPCh. 21 - Prob. 49PPCh. 21 - Prob. 50PPCh. 21 - Prob. 51PPCh. 21 - Prob. 52PPCh. 21 - Prob. 53PPCh. 21 - Prob. 54PPCh. 21 - Prob. 55PPCh. 21 - Prob. 56PPCh. 21 - Prob. 57PPCh. 21 - Prob. 58PPCh. 21 - Prob. 59PPCh. 21 - Prob. 60PPCh. 21 - Prob. 61PPCh. 21 - Prob. 62PPCh. 21 - Prob. 63PPCh. 21 - Prob. 64PPCh. 21 - Prob. 65PPCh. 21 - Prob. 66PPCh. 21 - Prob. 67PPCh. 21 - Prob. 68PPCh. 21 - Prob. 69PPCh. 21 - Prob. 70PPCh. 21 - Prob. 71PPCh. 21 - Prob. 72PPCh. 21 - Prob. 73PPCh. 21 - Prob. 74PPCh. 21 - Prob. 75PPCh. 21 - Prob. 76PPCh. 21 - Prob. 77PPCh. 21 - Prob. 78PPCh. 21 - Prob. 79PPCh. 21 - Prob. 80PPCh. 21 - Prob. 81PPCh. 21 - Prob. 82PPCh. 21 - Prob. 83PPCh. 21 - Prob. 84PPCh. 21 - Prob. 85PPCh. 21 - Prob. 86PPCh. 21 - Prob. 87PPCh. 21 - Prob. 88PPCh. 21 - Prob. 97IPCh. 21 - Prob. 98IPCh. 21 - Prob. 99IPCh. 21 - Prob. 100IPCh. 21 - Prob. 101IPCh. 21 - Prob. 107IPCh. 21 - Prob. 108IPCh. 21 - Prob. 109IP
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