EBK ORGANIC CHEMISTRY
8th Edition
ISBN: 8220102744127
Author: Bruice
Publisher: PEARSON
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Chapter 21.15, Problem 46P
How would a protein that resides in the nonpolar interior of a membrane fold compared with the water-soluble protein just discussed?
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How would a protein that resides in the nonpolar interior of a membrane fold compared with the water-soluble protein just discussed?
Glycolids are nonionic lipids that can orient themselves into bilayers in a manner similar to the phospholipids. Suggest a reason why they can accomplish this feat despite their lack of ionic group similar to that found in phospholipids
The terms nonpolar and polar as well as hydrophilic andhydrophobic can also be used to describe molecules. Howare these terms related to lipid-soluble and non-lipid-soluble?
Chapter 21 Solutions
EBK ORGANIC CHEMISTRY
Ch. 21.1 - a. Explain why, when the imidazole ring of...Ch. 21.2 - a. Which isomer(R)-alanine or (S)-alanineis...Ch. 21.2 - Prob. 4PCh. 21.3 - Prob. 5PCh. 21.3 - Prob. 6PCh. 21.3 - Draw the predominant form for glutamate in a...Ch. 21.3 - a. Why is the pKa of the glutamate side chain...Ch. 21.4 - Calculate the pI of each of the following amino...Ch. 21.4 - a. Which amino acid has the lowest pI value? b....Ch. 21.4 - Prob. 12P
Ch. 21.4 - Prob. 13PCh. 21.4 - Explain why the pI of lysine is the average of the...Ch. 21.5 - What aldehyde is formed when valine is treated...Ch. 21.5 - Prob. 16PCh. 21.5 - Prob. 17PCh. 21.5 - Prob. 18PCh. 21.5 - Prob. 19PCh. 21.6 - Why is excess ammonia used in the preceding...Ch. 21.6 - Prob. 21PCh. 21.6 - What amino acid is formed using the...Ch. 21.6 - Prob. 23PCh. 21.6 - What amino acid is formed when the aldehyde used...Ch. 21.7 - Esterase is an enzyme that catalyzes the...Ch. 21.8 - Draw the tetrapeptide Ala-Thr-Asp-Asn and indicate...Ch. 21.8 - Draw the resonance contributors of the peptide...Ch. 21.8 - Which bonds in the backbone of a peptide can...Ch. 21.9 - An opioid pentapeptide has the following...Ch. 21.9 - What is the configuration about each of the...Ch. 21.9 - Glutathione is a tripeptide whose function is to...Ch. 21.10 - What dipeptides would be formed by heating a...Ch. 21.10 - Suppose you are trying to synthesize the dipeptide...Ch. 21.10 - Show the steps in the synthesis of the...Ch. 21.10 - a. Calculate the overall yield of bradykinin when...Ch. 21.11 - Show the steps in the synthesis of the...Ch. 21.13 - Prob. 37PCh. 21.13 - In determining the primary structure of insulin,...Ch. 21.13 - A decapeptide undergoes partial hydrolysis to give...Ch. 21.13 - Explain why cyanogen bromide does not cleave on...Ch. 21.13 - Indicate the peptides produced from cleavage by...Ch. 21.14 - Prob. 43PCh. 21.14 - Three peptides were obtained from a trypsin...Ch. 21.14 - Prob. 45PCh. 21.15 - How would a protein that resides in the nonpolar...Ch. 21.16 - a. Which would have the greatest percentage of...Ch. 21.17 - When apples that have been cut are exposed to...Ch. 21 - Glycine has pK2 values of 2.34 and 9.60. At what...Ch. 21 - Prob. 50PCh. 21 - A titration curve is a plot of the pH of a...Ch. 21 - Prob. 52PCh. 21 - Aspartame (its structure is on page 1007) has a pl...Ch. 21 - Draw the form of aspartate that predominates at...Ch. 21 - Show how phenylalanine can be prepared by...Ch. 21 - A professor was preparing a manuscript for...Ch. 21 - What aldehydes are formed when the following amino...Ch. 21 - Prob. 58PCh. 21 - Determine the amino acid sequence of a polypeptide...Ch. 21 - Prob. 60PCh. 21 - Prob. 61PCh. 21 - Which is the more effective buffer at...Ch. 21 - Identify the location and type of charge on the...Ch. 21 - Draw the product obtained when a lysine side chain...Ch. 21 - After the polypeptide shown below was treated with...Ch. 21 - Treatment of a polypeptide with 2-mercaptoethanol...Ch. 21 - Show how aspartame can be synthesized using DCCD.Ch. 21 - -Amino acids can be prepared by treating an...Ch. 21 - Reaction of a polypeptide with carboxypeptidase A...Ch. 21 - a. How many different octapeptides can be made...Ch. 21 - Glycine has pKa values of 2.3 and 9.6. Do you...Ch. 21 - A mixture of 15 amino acids gave the fingerprint...Ch. 21 - Write the mechanism for the reaction of an amino...Ch. 21 - Prob. 74PCh. 21 - Show how valine can be prepared by a. a...Ch. 21 - The primary structure of -endorphin, a peptide...Ch. 21 - A chemist wanted to test his hypothesis that the...Ch. 21 - Propose a mechanism for the rearrangement of the...Ch. 21 - A normal polypeptide and a mutant of the...Ch. 21 - Determine the amino acid sequence of a polypeptide...
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- How are phospholipids similar in structure to a soap molecule? What structural difference accounts for the fact that phospholipids form lipid bilayers rather than the micelles that soaps form?arrow_forwardWhat percent of a cells overall mass is accounted for by proteins?arrow_forwardHow does the polarity of the phosphoglycerides contribute to their function of forming cell membranes?arrow_forward
- 76. Space-filling diagrams for the structures of vitamin A, vitamin D, and vitamin C are shown below. Which are fat soluble? Which are water soluble? What is the difference between the structures of water-soluble and fat-soluble vitamins?arrow_forward. How many unique amino acid sequences are possible for a tripeptide containing only the amino acids gly, ala, and cys, with each amino acid occurring only once in each molecule?arrow_forwardStarch contains CC, CH, CO, and OH bonds. Hydrocarbons have only CC and CH bonds. Both starch and hydrocarbons can form colloidal dispersions in water. Which dispersion is classified as hydrophobic? Which is hydrophilic? Explain briefly.arrow_forward
- The salt bridges that hold hair protein (keratin) strands together rely on NH3+ groups. Write an equation for the reaction of this group with OH- ions.arrow_forward21-85 Which of the following statements is (are) consistent with what is known about membranes? (a) A membrane consists of a layer of proteins sandwiched between two layers of lipids. (b) The compositions of the inner and outer lipid layers are the same in any individual membrane. (c) Membranes contain glycolipids and glycoproteins. (d) Lipid bilayers are an important component of membranes. (e) Covalent bonding takes place between lipids and proteins in most membranes.arrow_forwardDraw the structure of a triglyceride that contains one myristic acid, one palmitoleic acid, and one linoleic acid. Identify the ester bonds.arrow_forward
- Which statement about the lipid bilayers around cells is TRUE? They are single layers of molecules that allow only water molecules to pass through freely. They are permeable membranes that allow ions and water molecules to freely pass through. They are semipermeable membranes made of a double layer of molecules. They are double layers of molecules that do not allow any substance to pass through.arrow_forward7.0.00550 g of a highly purified protein was dissolved in 25.0 mL of water. At 50.0 solution exhibited an osmotic pressure of 0.00157 atm. What is the molecular weight of the protein? (Assume the solution volume is 25.0 mL.)arrow_forwardDescribe the orientation of the phospholipid molecules as they spontaneously assemble into a lipid bilayer in an aqueous environment.arrow_forward
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