The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

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Answer 1

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Draw the reaction mechanism to predict the product of the transformation below: N H ? H₂O

Answer 2

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Answer 3

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Answer 4

Question

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

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Answer 5

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 6

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 7

Chapter 21.14, Problem 21.39P

(a)

Interpretation Introduction

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The accomplishment of given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

Grignard reagent is used to generate R− carbanion which attack on electron deficient centre. Carbonyl group that has good leaving group gives substituted product. This reagent is used to convert carbonyl group into alcohol.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21.2F - Name the following carboxylic acid derivatives,...Ch. 21.4A - Prob. 21.2P Ch. 21.4A - Prob. 21.3P Ch. 21.4A - Prob. 21.4P Ch. 21.5C - Prob. 21.7P Ch. 21.6 - When ethyl 4-hydroxybutyrate is heated in the...Ch. 21.6 - Propose a mechanism for the following ring-opening...Ch. 21.6 - Prob. 21.15P Ch. 21.7B - Prob. 21.16P Ch. 21.7C - Prob. 21.19P

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author illustrates the transformation of 1-hexanol by the use of nitrile as an intermediate. Grignard reagent is used to generate R- carbanion which

Concept explainers

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

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Chapter 21 Solutions

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine .

Solution Summary: The author illustrates the transformation of 1-hexanol by the use of nitrile as an intermediate. Grignard reagent is used to generate R- carbanion which

Concept explainers

Interpretation: The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown. Concept introduction: The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.

Want to see the full answer?

Chapter 21 Solutions

Interpretation:

The accomplishment of the given transformation by the use of nitrile as an intermediate is to be shown.

Concept introduction:

The lithium aluminium hydride reduction of nitrile followed by hydrolysis gives primary amine.