(a) Interpretation: The ketones formed by the given reaction are to be predicted. Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

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Answer 1

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

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If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.

Answer 2

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

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Answer 3

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

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Answer 4

Question

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Expert Solution & Answer

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Answer 5

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Answer 6

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Answer 7

Chapter 21.10, Problem 26P

Interpretation Introduction

(a)

Interpretation: The ketones formed by the given reaction are to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Answer 8

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Answer 9

Interpretation Introduction

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 21.2 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 21.2 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 21.3 - Prob. 5P Ch. 21.3 - Problem 23.5 Which bonds in the following...Ch. 21.3 - Prob. 7P Ch. 21.3 - Prob. 8P Ch. 21.3 - Prob. 9P Ch. 21.4 - Prob. 10P Ch. 21.5 - Prob. 11P Ch. 21.7 - Problem 23.11 Draw the products of each...

Solution Summary: The author explains that the ketone formed by the given reaction is to be predicted.

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

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Chapter 21 Solutions

Solution Summary: The author explains that the ketone formed by the given reaction is to be predicted.

(b) Interpretation: The ketone formed by reaction is to be predicted. Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.

Want to see the full answer?

Chapter 21 Solutions

(b)

Interpretation: The ketone formed by reaction is to be predicted.

Concept introduction: The α hydrogen attached to the β- ketoester is acidic in nature and the hydrolysis and decarboxylation of the product obtained by substitution reaction of enolate ion with alkyl halide gives ketone.