For Ethyl diethoxyacetate, the resonance structures have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate . Example:

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ar

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

Highlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OH

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Answer 4

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Answer 5

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 6

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 7

Chapter 21.1, Problem 5ATS

Interpretation Introduction

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 8

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Answer 11

Ch. 21.1 - Prob. 1CC Ch. 21.1 - Prob. 2CC Ch. 21.1 - Prob. 3CC Ch. 21.1 - Prob. 1LTS Ch. 21.1 - Prob. 4PTS Ch. 21.1 - APPLY the skill As with aldehydes and ketones, the...Ch. 21.1 - Draw the enolate ion that is formed when each of...Ch. 21.1 - Prob. 7CC Ch. 21.2 - Prob. 8CC Ch. 21.2 - Prob. 9CC

For Ethyl diethoxyacetate, the resonance structures have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate . Example:

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Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Chapter 21 Solutions

For Ethyl diethoxyacetate, the resonance structures have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate . Example:

Concept explainers

Videos

Interpretation: For Ethyl diethoxyacetate, the resonance structures have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate. Example:

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Chapter 21 Solutions

Interpretation:

For Ethyl diethoxyacetate, the resonance structures have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example: