For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate . Example:

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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1. Show the steps necessary to make 2-methyl-4-nonene using a Wittig reaction. Start with triphenylphosphine and an alkyl halide. After that you may use any other organic or inorganic reagents. 2. Write in the product of this reaction: CH3 CH₂ (C6H5)₂CuLi H₂O+

3. Name this compound properly, including stereochemistry. H₂C H3C CH3 OH 4. Show the step(s) necessary to transform the compound on the left into the acid on the right. Bri CH2 5. Write in the product of this LiAlH4 Br H₂C OH

What are the major products of the following reaction? Please provide a detailed explanation and a drawing to show how the reaction proceeds.

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Answer 5

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 6

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 7

Chapter 21.1, Problem 4PTS

(a)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 8

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 9

(b)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 10

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 11

(c)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 12

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 13

(d)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 14

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 15

(e)

Interpretation Introduction

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 21.1 - Prob. 1CC Ch. 21.1 - Prob. 2CC Ch. 21.1 - Prob. 3CC Ch. 21.1 - Prob. 1LTS Ch. 21.1 - Prob. 4PTS Ch. 21.1 - APPLY the skill As with aldehydes and ketones, the...Ch. 21.1 - Draw the enolate ion that is formed when each of...Ch. 21.1 - Prob. 7CC Ch. 21.2 - Prob. 8CC Ch. 21.2 - Prob. 9CC

For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate . Example:

Concept explainers

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

Interpretation:

For the given ketone, the resonance structures of the enolate have to be drawn.

Concept Introduction:

Enolates:

When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate.

Example:

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Chapter 21 Solutions

For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate . Example:

Concept explainers

Interpretation: For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate. Example:

Interpretation: For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate. Example:

Interpretation: For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate. Example:

Interpretation: For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate. Example:

Interpretation: For the given ketone, the resonance structures of the enolate have to be drawn. Concept Introduction: Enolates: When ketones are treated with a strong base, the α-position of the ketone will be deprotonated to give a resonance-stabilized intermediate called an enolate. Example:

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Chapter 21 Solutions