OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
5th Edition
ISBN: 9781285460369
Author: STANITSKI
Publisher: Cengage Learning
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Chapter 2.11, Problem 2.16E
Interpretation Introduction
Interpretation:
The number of atoms present in
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 2 Solutions
OWLV2 FOR MOORE/STANITSKI'S CHEMISTRY:
Ch. 2.1 - When you comb your hair on a dry day, your hair...Ch. 2.2 - Prob. 2.1PSPCh. 2.2 - Prob. 2.2PSPCh. 2.2 - Prob. 2.2CECh. 2.2 - Prob. 2.3PSPCh. 2.3 - Prob. 2.4PSPCh. 2.3 - A student in your chemistry class tells you that...Ch. 2.3 - Prob. 2.5PSPCh. 2.3 - Prob. 2.4CECh. 2.3 - Prob. 2.5CE
Ch. 2.4 - Prob. 2.6PSPCh. 2.4 - Prob. 2.6CECh. 2.4 - Prob. 2.7PSPCh. 2.4 - Prob. 2.8PSPCh. 2.5 - Prob. 2.9PSPCh. 2.5 - Prob. 2.10PSPCh. 2.6 - Prob. 2.7CECh. 2.7 - Prob. 2.8CECh. 2.7 - Prob. 2.11PSPCh. 2.7 - Prob. 2.9ECh. 2.8 - Prob. 2.12PSPCh. 2.8 - Prob. 2.10ECh. 2.9 - Prob. 2.11ECh. 2.9 - Prob. 2.12ECh. 2.9 - Prob. 2.13CECh. 2.9 - According to Table 2.10, five constitutional...Ch. 2.11 - Calculate (a) the amount of Ti atoms in 4.00 g...Ch. 2.11 - Prob. 2.15CECh. 2.11 - Prob. 2.16ECh. 2.11 - Prob. 2.17CECh. 2.11 - Prob. 2.18ECh. 2.11 - Prob. 2.19ECh. 2.11 - Prob. 2.14PSPCh. 2.11 - Prob. 2.15PSPCh. 2.11 - Prob. 2.16PSPCh. 2.11 - Prob. 2.20CECh. 2.12 - Prob. 2.17PSPCh. 2.12 - Prob. 2.18PSPCh. 2.12 - Prob. 2.21ECh. 2.12 - Hydrazine is composed of 87.42% nitrogen and...Ch. 2.12 - Prob. 2.20PSPCh. 2.12 - Prob. 2.22ECh. 2 - An isotope of an element contains 63 protons and...Ch. 2 - Prob. IISPCh. 2 - Prob. IIISPCh. 2 - Dioxathion, a pesticide, contains carbon,...Ch. 2 - Prob. 1QRTCh. 2 - Prob. 2QRTCh. 2 - Prob. 3QRTCh. 2 - Prob. 4QRTCh. 2 - Prob. 5QRTCh. 2 - Prob. 6QRTCh. 2 - Prob. 7QRTCh. 2 - Prob. 8QRTCh. 2 - Prob. 9QRTCh. 2 - Prob. 10QRTCh. 2 - Match these by placing the correct notation in the...Ch. 2 - Prob. 12QRTCh. 2 - Prob. 13QRTCh. 2 - Prob. 14QRTCh. 2 - Prob. 15QRTCh. 2 - Prob. 16QRTCh. 2 - Prob. 17QRTCh. 2 - Prob. 18QRTCh. 2 - Prob. 19QRTCh. 2 - Prob. 20QRTCh. 2 - Prob. 21QRTCh. 2 - Prob. 22QRTCh. 2 - Prob. 23QRTCh. 2 - Prob. 24QRTCh. 2 - Prob. 25QRTCh. 2 - Prob. 26QRTCh. 2 - Prob. 27QRTCh. 2 - Prob. 28QRTCh. 2 - Argon has three naturally occurring isotopes:...Ch. 2 - Prob. 30QRTCh. 2 - Prob. 31QRTCh. 2 - Prob. 32QRTCh. 2 - Prob. 33QRTCh. 2 - Prob. 34QRTCh. 2 - Prob. 35QRTCh. 2 - Prob. 36QRTCh. 2 - Prob. 37QRTCh. 2 - Prob. 38QRTCh. 2 - Prob. 39QRTCh. 2 - Prob. 40QRTCh. 2 - Prob. 41QRTCh. 2 - Prob. 42QRTCh. 2 - Prob. 43QRTCh. 2 - Prob. 44QRTCh. 2 - Prob. 45QRTCh. 2 - Prob. 46QRTCh. 2 - Prob. 47QRTCh. 2 - Prob. 48QRTCh. 2 - Prob. 49QRTCh. 2 - Prob. 50QRTCh. 2 - Prob. 51QRTCh. 2 - Prob. 52QRTCh. 2 - Prob. 53QRTCh. 2 - Prob. 54QRTCh. 2 - Prob. 55QRTCh. 2 - Prob. 56QRTCh. 2 - Prob. 57QRTCh. 2 - Prob. 58QRTCh. 2 - Prob. 59QRTCh. 2 - Prob. 60QRTCh. 2 - Prob. 61QRTCh. 2 - Prob. 62QRTCh. 2 - Prob. 63QRTCh. 2 - Prob. 64QRTCh. 2 - Prob. 65QRTCh. 2 - Prob. 66QRTCh. 2 - Prob. 67QRTCh. 2 - Prob. 68QRTCh. 2 - Prob. 69QRTCh. 2 - Prob. 70QRTCh. 2 - Prob. 71QRTCh. 2 - Prob. 72QRTCh. 2 - Prob. 73QRTCh. 2 - Prob. 74QRTCh. 2 - If you have a ring that contains 1.94 g gold,...Ch. 2 - You have a pure sample of the antiseptic...Ch. 2 - You have a pure sample of apholate, C12H24N9P3, a...Ch. 2 - Prob. 78QRTCh. 2 - Prob. 79QRTCh. 2 - Prob. 80QRTCh. 2 - Prob. 81QRTCh. 2 - Prob. 82QRTCh. 2 - Prob. 83QRTCh. 2 - Prob. 84QRTCh. 2 - Prob. 85QRTCh. 2 - Prob. 86QRTCh. 2 - Prob. 87QRTCh. 2 - Prob. 88QRTCh. 2 - Prob. 89QRTCh. 2 - Prob. 90QRTCh. 2 - Quinine (molar mass = 324.41 g/mol) is used as a...Ch. 2 - Prob. 92QRTCh. 2 - The mineral uraninite is a uranium oxide that is...Ch. 2 - Carbonic anhydrase, an important enzyme in...Ch. 2 - Nitrogen fixation in the root nodules of peas and...Ch. 2 - Disilane, Si2Hx, contains 90.28% silicon by mass....Ch. 2 - Chalky, white crystals in mineral collections are...Ch. 2 - A well-known reagent in analytical chemistry,...Ch. 2 - Prob. 99QRTCh. 2 - Prob. 100QRTCh. 2 - The density of a solution of sulfuric acid is...Ch. 2 - Prob. 102QRTCh. 2 - Prob. 103QRTCh. 2 - Prob. 104QRTCh. 2 - Prob. 105QRTCh. 2 - Prob. 106QRTCh. 2 - Prob. 107QRTCh. 2 - The Statue of Liberty in New York harbor is made...Ch. 2 - Prob. 109QRTCh. 2 - Prob. 110QRTCh. 2 - Prob. 111QRTCh. 2 - Prob. 112QRTCh. 2 - Prob. 113QRTCh. 2 - Prob. 114QRTCh. 2 - Prob. 115QRTCh. 2 - Prob. 116QRTCh. 2 - Prob. 117QRTCh. 2 - Prob. 118QRTCh. 2 - Prob. 119QRTCh. 2 - Prob. 120QRTCh. 2 - Prob. 121QRTCh. 2 - Prob. 122QRTCh. 2 - Prob. 123QRTCh. 2 - Prob. 124QRTCh. 2 - Prob. 125QRTCh. 2 - Prob. 126QRTCh. 2 - Prob. 127QRTCh. 2 - Prob. 128QRTCh. 2 - Prob. 129QRTCh. 2 - The element bromine is Br2, so the mass of a Br2...Ch. 2 - Uranium is used as a fuel, primarily in the form...Ch. 2 - Prob. 132QRTCh. 2 - Hemoglobin is an iron-containing protein (molar...Ch. 2 - There are three naturally occurring isotopes of...Ch. 2 - Prob. 135QRTCh. 2 - Prob. 136QRTCh. 2 - Prob. 137QRTCh. 2 - An adult human body contains 6.0 L blood, which...Ch. 2 - Prob. 139QRTCh. 2 - Prob. 140QRTCh. 2 - Prob. 141QRTCh. 2 - The present average concentration (mass percent)...Ch. 2 - Prob. 144QRTCh. 2 - A 4.22-g mixture of calcium chloride and sodium...Ch. 2 - A certain metal, M, forms two oxides, M2O and MO....Ch. 2 - If you heat Al with an element from Group 6A, an...Ch. 2 - Prob. 2.ACPCh. 2 - The age of the universe is unknown, but some...Ch. 2 - Prob. 2.CCPCh. 2 - Prob. 2.DCPCh. 2 - Prob. 2.ECP
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