PRINCIPLES+REACTIONS
PRINCIPLES+REACTIONS
8th Edition
ISBN: 9781337759632
Author: Masterton
Publisher: CENGAGE L
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Chapter 21, Problem 72QAP
Interpretation Introduction

Interpretation:

The cost of HF needed to extract gold from the given reaction needs to be compared with the cost of gold formed.

Concept introduction:

Quartz is used to extract gold with HF. Here, the reaction between HF and quartz forms silicon tetrafluoride and water. The balance chemical reaction can be written as follows:

4 HF(aq)+ SiO2(aq)SiF4(aq)+ 2 H2O(l)

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1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction. 2600 2400 2200 2000 1800 1600 1400 1200 1000 800 Potential Energy (kJ) 600 400 200 0 -200- -400 -600- -800 (i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s) (ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s) Ea = 1550 kJ Ea = 2240 kJ (iii) Cl (g) + CICO (g) → Cl₂CO (g) Ea = 2350 kJ AH=-950 kJ ΔΗ = 575 ΚΙ AH=-825 kJ a. Draw the potential energy diagram for the reaction. Label the data points for clarity. The potential energy of the reactants is 600 kJ Reaction Progress b. What is the overall chemical equation? c. What is the overall change in enthalpy for the above chemical reaction? d. What is the overall amount of activation energy for the above chemical reaction? e. Which reaction intermediate would be considered a catalyst (if any) and why? f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would you be able to make the reaction reverse itself (i.e. have…

Chapter 21 Solutions

PRINCIPLES+REACTIONS

Ch. 21 - Prob. 11QAPCh. 21 - Prob. 12QAPCh. 21 - Prob. 13QAPCh. 21 - Prob. 14QAPCh. 21 - Prob. 15QAPCh. 21 - Prob. 16QAPCh. 21 - Prob. 17QAPCh. 21 - Write a balanced net ionic equation for the...Ch. 21 - Prob. 19QAPCh. 21 - Prob. 20QAPCh. 21 - Prob. 21QAPCh. 21 - Prob. 22QAPCh. 21 - Prob. 23QAPCh. 21 - Prob. 24QAPCh. 21 - Prob. 25QAPCh. 21 - Prob. 26QAPCh. 21 - Prob. 27QAPCh. 21 - Prob. 28QAPCh. 21 - Prob. 29QAPCh. 21 - Prob. 30QAPCh. 21 - Prob. 31QAPCh. 21 - Prob. 32QAPCh. 21 - Prob. 33QAPCh. 21 - Prob. 34QAPCh. 21 - The average concentration of bromine (as bromide)...Ch. 21 - Prob. 36QAPCh. 21 - Iodine can be prepared by allowing an aqueous...Ch. 21 - Prob. 38QAPCh. 21 - Prob. 39QAPCh. 21 - Prob. 40QAPCh. 21 - Prob. 41QAPCh. 21 - Prob. 42QAPCh. 21 - Prob. 43QAPCh. 21 - Prob. 44QAPCh. 21 - Prob. 45QAPCh. 21 - Given...Ch. 21 - What is the concentration of fluoride ion in a...Ch. 21 - Calculate the solubility in grams per 100 mL of...Ch. 21 - Prob. 49QAPCh. 21 - Follow the directions for Problem 49 for the...Ch. 21 - Consider the equilibrium system HF(aq)H+(aq)+F(aq)...Ch. 21 - Applying the tables in Appendix 1 to...Ch. 21 - Consider the reaction 4NH3(g)+5O2(g)4NO(g)+6H2O(g)...Ch. 21 - Data are given in Appendix 1 for white phosphorus,...Ch. 21 - Prob. 55QAPCh. 21 - Prob. 56QAPCh. 21 - Sodium hypochlorite is produced by the...Ch. 21 - Prob. 58QAPCh. 21 - Prob. 59QAPCh. 21 - Prob. 60QAPCh. 21 - Consider the reduction of nitrate ion in acidic...Ch. 21 - Prob. 62QAPCh. 21 - Choose the strongest acid from each group. (a)...Ch. 21 - Prob. 64QAPCh. 21 - Prob. 65QAPCh. 21 - Prob. 66QAPCh. 21 - Prob. 67QAPCh. 21 - Prob. 68QAPCh. 21 - Prob. 69QAPCh. 21 - Explain why (a) acid strength increases as the...Ch. 21 - Prob. 71QAPCh. 21 - Prob. 72QAPCh. 21 - The amount of sodium hypochlorite in a bleach...Ch. 21 - Prob. 74QAP
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