CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
7th Edition
ISBN: 9781119457282
Author: JESPERSEN
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 21, Problem 69RQ
Interpretation Introduction
Interpretation:
The comparison of the given structure of a complex with respect to the geometrical isomerism is to be explained.
Concept Information:
Isomerism is the phenomenon where the compounds have a different structural arrangement of atoms in space with the same chemical formula.
Ligands are the molecules or ions that are bonded with a coordinate covalent bond to a metal ion.
Geometrical isomerism is the form of stereoisomerism where atoms or group of atoms show different spatial arrangements.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
1. Which of the following statements is correct?a. The transition metals have little variability in their ionization energies and electronegativities due to their similar valence electron shells.b. Transition metals are characterized by the formation of many diamagnetic compounds due to the presence of unpaired d electrons.c. One difference between transition metals and main group metals is the latter’s ability to form coordination complexes.d. Transition metals are characterized by many oxidation states due to the high reactivity of the unpaired d electrons.
2. Which of the following statements about atomic radii accurately describes the data in the photo attached?a. The elements right after the d-block experience an expansion due to the repulsion created by the d electrons such that period 4 nonmetals are substantially larger than period 3 nonmetals.b. The minima of the graph correspond to the halides because they have the greatest effective nuclear charge.c. The transition metals…
What are ligands? Give examples
The molecule CO is a common ligand in transition metal complexes forming a strong
bond with the metal ion.
b) Based on Lewis structure of CO, which end of the CO molecule do you think is
the electron source to form the metal-ligand bond? Why?
Chapter 21 Solutions
CHEMISTRY:MOLECULAR..(LL)-PRINT..W/CODE
Ch. 21 - Prob. 1PECh. 21 - Aluminum chloride crystallizes from aqueous...Ch. 21 - What is the formula of the complex ion that is...Ch. 21 - Prob. 4PECh. 21 - Prob. 5PECh. 21 - Prob. 6PECh. 21 - What is the coordination number of the metal ion...Ch. 21 - What is the coordination number of the metal ion...Ch. 21 - Prob. 9PECh. 21 - Prob. 10PE
Ch. 21 - Prob. 11PECh. 21 - Prob. 12PECh. 21 - The iron metal center in hemoglobin sits in an...Ch. 21 - Prob. 1RQCh. 21 - Prob. 2RQCh. 21 - Prob. 3RQCh. 21 - Prob. 4RQCh. 21 - Complex Ions Use Lewis structures to diagram the...Ch. 21 - Complex Ions
21.6 What must be true about the...Ch. 21 - Prob. 7RQCh. 21 - Complex Ions What is a chelate? Use Lewis...Ch. 21 - Prob. 9RQCh. 21 - Complex Ions Explain how a sale of EDTA4- can...Ch. 21 - Prob. 11RQCh. 21 - Complex Ions
21.12 The cobalt(III) ion, , forms a...Ch. 21 - Prob. 13RQCh. 21 - Complex Ions What is the chelate effect? How does...Ch. 21 - Prob. 15RQCh. 21 - Prob. 16RQCh. 21 - Prob. 17RQCh. 21 - Prob. 18RQCh. 21 - Prob. 19RQCh. 21 - Prob. 20RQCh. 21 - Prob. 21RQCh. 21 - Prob. 22RQCh. 21 - Prob. 23RQCh. 21 - Prob. 24RQCh. 21 - Coordination Number and Structure Draw (a) a...Ch. 21 - Prob. 26RQCh. 21 - Prob. 27RQCh. 21 - Prob. 28RQCh. 21 - Prob. 29RQCh. 21 - Prob. 30RQCh. 21 - Prob. 31RQCh. 21 - Bonding in Metal Complexes
21.32 On appropriate...Ch. 21 - Prob. 33RQCh. 21 - Prob. 34RQCh. 21 - Prob. 35RQCh. 21 - Prob. 36RQCh. 21 - Prob. 37RQCh. 21 - Prob. 38RQCh. 21 - Prob. 39RQCh. 21 - Prob. 40RQCh. 21 - Prob. 41RQCh. 21 - Prob. 42RQCh. 21 - Bonding in Metal Complexes What factors about the...Ch. 21 - Prob. 44RQCh. 21 - Bonding in Metal Complexes The complex [...Ch. 21 - Bonding in Metal Complexes
21.46 Consider the...Ch. 21 - Prob. 47RQCh. 21 - Prob. 48RQCh. 21 - Prob. 49RQCh. 21 - Prob. 50RQCh. 21 - Prob. 51RQCh. 21 - Biological Functions of Metals Ions
21.52 List...Ch. 21 - Prob. 53RQCh. 21 - Prob. 54RQCh. 21 - Prob. 55RQCh. 21 - Write the formula, including its correct charge,...Ch. 21 - Metal Complex Nomenclature How would the following...Ch. 21 - Metal Complex Nomenclature
21.58 How would the...Ch. 21 - Give IUPAC names for each of the following:...Ch. 21 - Prob. 60RQCh. 21 - Prob. 61RQCh. 21 - Prob. 62RQCh. 21 - Coordination Number and Structure
21.63 What is...Ch. 21 - Prob. 64RQCh. 21 - Draw a reasonable structure for (a) [ Zn(NH3)4 ]2+...Ch. 21 - Prob. 66RQCh. 21 - Prob. 67RQCh. 21 - 21.68 The following compound is called...Ch. 21 - Prob. 69RQCh. 21 - Isomers of Metal Complexes
*21.70 Below is a...Ch. 21 - Prob. 71RQCh. 21 - Prob. 72RQCh. 21 - Prob. 73RQCh. 21 - Prob. 74RQCh. 21 - Bonding in Metal Complexes
*21.75 In which complex...Ch. 21 - Prob. 76RQCh. 21 - Prob. 77RQCh. 21 - Prob. 78RQCh. 21 - Prob. 79RQCh. 21 - Prob. 80RQCh. 21 - Referring to the two ligands, A and B, described...Ch. 21 - Referring to the complexes in Problems 21.80 and...Ch. 21 - Prob. 83RQCh. 21 - Prob. 84RQCh. 21 - *21.85 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.86 Sketch the d-orbital energy level diagrams...Ch. 21 - *21.87 ions can be either four coordinate or six...Ch. 21 - Prob. 88RQCh. 21 - Most of the first row transition metals form 2+...Ch. 21 - *21.90 Is the complex chiral? Illustrate your...Ch. 21 - The complex [PtCl2(NH3)2] can be obtained as two...Ch. 21 - Prob. 92RQCh. 21 - Prob. 93RQCh. 21 - The compound Cr2(NH3)3(H2O)3Cl is a neutral salt...Ch. 21 - Prob. 95RQCh. 21 - Prob. 96RQCh. 21 - Prob. 97RQCh. 21 - Prob. 98RQCh. 21 - Prob. 99RQCh. 21 - Platinum(IV) makes compounds with coordination...Ch. 21 - Prob. 101RQCh. 21 - Prob. 102RQ
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- What structural feature is used to determine whether a compound can exist as optical isomers?arrow_forwardFor each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8arrow_forwardDefine the terms complex ion, ligand, and coordination number. Use an example to illustrate the use of these terms.arrow_forward
- An aqueous solution of [Rh(C2O4)3]3− is yellow. Predict the approximate wavelength and predominant color of light absorbed by the complex.arrow_forwardWhat types of isomers are possible for the following compounds or complex ions? (a) K[Co(NH3)2Cl4] (b) Pt(en)Cl2 (square-planar) (c) [Co(NH3)5Cl]2+ (d) [Ru(phen)3]Cl3 (e) Na2[MnCl4] (tetrahedral) (f) [Co(NH3)5NO2)2+arrow_forwardWhich of the following octahedral complexes show geometric isomerism? If geometric isomers are possible, draw their structures. (a) [Co(en)Cl4-] (b) [Ni(C2O4)2ClBr4-] (c) [Cd(NH3)2Cl42-]arrow_forward
- Specify whether the following complexes have isomers.. (a) tetrahedral [Ni(CO)2(Cl)2]. (b) trigonal bipyramidal [Mn(CO)4NO]. (c) [Pt(en)2Cl2]Cl2arrow_forwardDraw the Lewis structure of NH₃. Can this molecule act as a ligand?arrow_forwardIn the structures below, M represents the central metal atom and the colored spheres represent the bonded groups (ligands). Different ligands are labeled with different letter designations. Classify each pair of ions by the type of isomer they represent or as identical ions. a. Coordination isomers b. Geometric isomers c. optical isomers d. identical ionsarrow_forward
- Which of the following statements is not true? A. Coordination Chemistry is the science concerned with the interactions of organic and inorganic ligands with metal centers. B. Coordination compounds are composed of a metal atom or ion and one or more ligands (atoms, ions, or molecules) that donate electrons to the metal. C. Coordination compounds include organometallic compounds. D. The modern theory of coordination chemistry is based largely on the work of Alfred Werner. E. Coordination compounds are examples of Brønsted-Lowry acid-base adducts.arrow_forwardConsider this metal complex: Br Br Cl C1 8 \. Br Complex A Now decide whether each complex in the table below is another example of A, an isomer of A, or an entirely different chemical compound. Complex Br Br Br Br 8 J J J Cl Br 8 8 V C1 Br 8 Cl Br 5 J 2 Br 3- This complex is ... O the same as A ... an isomer of A ... a different compound. ...the same as A O an isomer of A ... a different compound. O ... the same as A ...an isomer of A O a different compound. O ... the same as A O ... an isomer of A ... a different compound. Marrow_forwardWhat is a Chelate ligand? Give one example.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning