Organic Chemistry (6th Edition)
Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 21, Problem 43P
Interpretation Introduction

(a)

Interpretation: The given carboxylic acids is to be prepared by using malonic ester synthesis.

Concept introduction: The malonic ester synthesis is a method which is used to convert diethyl malonate into a carboxylic acid. NaOEt is a strong base. It abstracts a proton from the alpha carbon of an ester molecule to forms an enolate.

Interpretation Introduction

(b)

Interpretation: The given carboxylic acids are to be prepared by using malonic ester synthesis.

Concept introduction: The malonic ester synthesis is a method which is used to convert diethyl malonate into a carboxylic acid. NaOEt is a strong base. It abstracts a proton from the alpha carbon of an ester molecule to forms an enolate.

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Calculate the packing factor of CaTiO3. It has a perovskite structure. Data: ionic radii Co²+ = 0.106 nm, Ti4+ = 0.064 nm, O² = 0.132 nm; lattice constant is a = 2(rTi4+ + ro2-). Ca2+ 02- T14+ Consider the ions as rigid spheres. 1. 0.581 or 58.1% 2. -0.581 or -58.1 % 3. 0.254 or 25.4%
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Chapter 21 Solutions

Organic Chemistry (6th Edition)

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