The name of the given structures of complex ion is to be stated. Concept introduction: Rules followed in the naming of coordination compound: In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element. An ‘o’ is added to the root name of anion. Greek prefix is used to express the number of ligands. Roman numeral is used to denote the oxidation state of metal ion. In case of more than one type of ligand present in a compound, they are named alphabetically. The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals. To determine: The name of the given structure of complex ion.

Question

4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

Answer 1

Question

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

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4. Provide a clear arrow-pushing mechanism for each of the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. 2. 1. LDA 3. H3O+ HO

b. H3C CH3 H3O+ ✓ H OH

2. Provide reagents/conditions to accomplish the following syntheses. More than one step is required in some cases. a. CH3

Answer 2

Question

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

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Answer 3

Question

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

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Answer 4

Question

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

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Answer 5

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

Answer 6

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

Answer 7

Chapter 21, Problem 35E

(a)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

Answer 8

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

Answer 9

(b)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

Answer 10

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

Answer 11

(c)

Interpretation Introduction

Interpretation: The name of the given structures of complex ion is to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

In naming of coordination compound, the name of anion (ligand) comes first. Metal ion is named second, which is the name of element.

An ‘o’ is added to the root name of anion.

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

To determine: The name of the given structure of complex ion.

The name of complex ion [Co(NH3)5Cl]+ is pentaamminechlorocobalt(II).

Answer 12

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Ch. 21 - What two first-row transition metals have...Ch. 21 - Prob. 2RQ Ch. 21 - Prob. 3RQ Ch. 21 - Prob. 4RQ Ch. 21 - Prob. 5RQ Ch. 21 - Prob. 6RQ Ch. 21 - Prob. 7RQ Ch. 21 - Prob. 8RQ Ch. 21 - Prob. 9RQ Ch. 21 - Prob. 10RQ

Solution Summary: The author explains how the name of the given structures of complex ion is to be stated.

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