Chemistry (OER)
2nd Edition
ISBN: 9781947172616
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 21, Problem 23E
Why is electron capture accompanied by the emission of an X-ray?
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Briefly state why trifluoroacetic acid is more acidic than acetic acid.
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An analytical chemist is titrating 101.7 mL of a 0.3500M solution of piperidine (C5H10NH) with a 0.05700M solution of HClO4. The pK of piperidine is 2.89.
Calculate the pH of the base solution after the chemist has added 682.9 mL of the HClO solution to it.
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Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HClO solution added.
4
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pH = .11
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Chapter 21 Solutions
Chemistry (OER)
Ch. 21 - Write the following isotopes in hyphenated form...Ch. 21 - Write the following isotopes in nuclide notation...Ch. 21 - For the following isotopes that have missing...Ch. 21 - For each of the isotopes in Exercise 21.1,...Ch. 21 - Write the nuclide notation, including charge if...Ch. 21 - Calculate the density of the M1224g nucleus in...Ch. 21 - What are the two principal differences between...Ch. 21 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 21 - Which of the following nuclei lie within the band...Ch. 21 - Which of the following nuclei lie within the band...
Ch. 21 - Write a brief description or definition of each of...Ch. 21 - Which of the various particles ( particles, ...Ch. 21 - Complete each of the following equations by adding...Ch. 21 - Complete each 0f the following equations: (a)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 21 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 21 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 21 - What are the types of radiation emitted by the...Ch. 21 - That changes occur to the atomic number and mass...Ch. 21 - What is the change in the nucleus that results...Ch. 21 - Many nuclides with atomic numbers greater than 83...Ch. 21 - Why is electron capture accompanied by the...Ch. 21 - Explain, in terms of Figure 21.2, how unstable...Ch. 21 - Which of the following nuclei is most likely to...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - The following nuclei do not lie in the band of...Ch. 21 - Predict by what mode(s) of spontaneous radioactive...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Write a nuclear reaction for each step in the...Ch. 21 - Define the term half-life and illustrate it with...Ch. 21 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 21 - 239Pu is a nuclear waste byproduct with a...Ch. 21 - The isotope 208Tl undergoes decay with a...Ch. 21 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 21 - The isotope S3890r one of the extremely hazardous...Ch. 21 - Technetium-99 is often used for assessing heart,...Ch. 21 - What is the age of mummified primate skin that...Ch. 21 - A sample of rock was found to contain 8.23 mg of...Ch. 21 - A laboratory investigation shows that a sample of...Ch. 21 - Plutonium was detected in trace amounts in natural...Ch. 21 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 21 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 21 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write a balanced equation for each of the...Ch. 21 - Write the balanced nuclear equation for the...Ch. 21 - How does nuclear fission differ from nuclear...Ch. 21 - Both fusion and fission are nuclear reactions. Why...Ch. 21 - Cite the conditions necessary for a nuclear chain...Ch. 21 - Describe the components of a nuclear reactor.Ch. 21 - In usual practice, both a moderator and control...Ch. 21 - Describe how the potential energy of uranium is...Ch. 21 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 21 - How can a radioactive nuclide be used to show that...Ch. 21 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 21 - Iodine that enters the body is stored in the...Ch. 21 - If a hospital were storing radioisotopes, what is...Ch. 21 - Based on what is known about Radon-222’s primary...Ch. 21 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 21 - A scientist is studying a 2.234 g sample of...Ch. 21 - Given specimens neon-24 (t1/2=3.38min) and...
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- The following is a two groups (Regular tomato sauce & Salt Reduced Tomato Sauce) of data recorded by a team analysising salt content in tomato sauce using the MOHR titration method: Regular Tomato Sauce Salt Reduced Tomato Sauce 340.0 262.7 QUESTION: For both groups of data provide answers to the calculations attached in the imagearrow_forward7. Concentration and uncertainty in the estimate of concentration (class data) Class mean for sample (Regular) |[Cl-] (mmol/L) class mean Sn za/2 95% Confidence Interval (mmol/L) [Na+] (mg/100 mL) 95% Confidence Interval (mg/100 mL)arrow_forwardThe following is a two groups (Regular tomato sauce & Salt Reduced Tomato Sauce) of data recorded by a team analysising salt content in tomato sauce using the MOHR titration method: Regular Tomato Sauce Salt Reduced Tomato Sauce 223.4 148.7 353.7 278.2 334.6 268.7 305.6 234.4 340.0 262.7 304.3 283.2 244.7 143.6 QUESTION: For both groups of data calculate the answers attached in the image.arrow_forward
- Give reason(s) for six from the followings [using equations if possible] a. Addition of sodium carbonate to sulfanilic acid in the Methyl Orange preparation. b. What happened if the diazotization reaction gets warmed up by mistake. c. Addition of sodium nitrite in acidified solution in MO preparation through the diazotization d. Using sodium dithionite dihydrate in the second step for Luminol preparation. e. In nitroaniline preparation, addition of the acid mixture (nitric acid and sulfuric acid) to the product of step I. f. What is the main reason of the acylation step in nitroaniline preparation g. Heating under reflux. h. Fusion of an organic compound with sodium. HAND WRITTEN PLEASEarrow_forwardedict the major products of the following organic reaction: u A + ? CN Some important notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. Explanation Check Click and drag to start drawing a structure. Х © 2025 McGraw Hill LLC. All Rights Reserved. Te LMUNDARYarrow_forwardSketch the intermediates for A,B,C & D.arrow_forward
- Can the molecule on the right-hand side of this organic reaction be made in good yield from no more than two reactants, in one step, by moderately heating the reactants? O ? A . If your answer is yes, then draw the reactant or reactants in the drawing area below. You can draw the reactants in any arrangement you like. . If your answer is no, check the box under the drawing area instead. Explanation Check Click and drag to start drawing a structure. ㅇ 80 F5 F6 A 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Cente FIGarrow_forwardIn methyl orange preparation, if the reaction started with 0.5 mole of sulfanilic acid to form the diazonium salt of this compound and then it converted to methyl orange [0.2 mole]. If the efficiency of the second step was 50%, Calculate: A. Equation(s) of Methyl Orange synthesis: Diazotization and coupling reactions. B. How much diazonium salt was formed in this reaction? C. The efficiency percentage of the diazotization reaction D. Efficiency percentage of the whole reaction.arrow_forwardHand written equations pleasearrow_forward
- Hand written equations pleasearrow_forward> each pair of substrates below, choose the one that will react faster in a substitution reaction, assuming that: 1. the rate of substitution doesn't depend on nucleophile concentration and 2. the products are a roughly 50/50 mixture of enantiomers. Substrate A Substrate B Faster Rate X Ś CI (Choose one) (Choose one) CI Br Explanation Check Br (Choose one) © 2025 McGraw Hill LLC. All Rights Farrow_forwardNMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at 4.1 ppm? Select the single best answer. The H O HỌC—C—0—CH, CH, 2 A ethyl acetate H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm Check OA B OC ch B C Save For Later Submit Ass © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center |arrow_forward
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