EBK EXPLORING CHEMICAL ANALYSIS
EBK EXPLORING CHEMICAL ANALYSIS
5th Edition
ISBN: 8220101443908
Author: Harris
Publisher: MAC HIGHER
Question
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Chapter 21, Problem 21.8P

(a)

Interpretation Introduction

Interpretation:

Number of theoretical plates that can produce a peak that elutes at 12.83 min has to be calculated.

Concept Introduction:

Expression to compute number of theoretical plate is as follows:

  N=5.55 tr2w1/22

Here,

tr denotes analyte’s  retention time.

w1/2 denotes peak width at half-height.

N denotes number of theoretical plate.

(b)

Interpretation Introduction

Interpretation:

Plate height has to be calculated.

Concept Introduction:

Expression to compute plate height is as follows:

  H=LN

Here,

tr denotes analyte’s  retention time.

w1/2 denotes peak width at half-height.

N denotes number of theoretical plate.

L denotes length of chromatographic column.

H denotes plate height.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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