Concept explainers
A sample of gas with a thermometer immersed in the gas is held over a hot plate. A student is asked to give a step-by-step account of what makes our observation of the temperature of the gas increase. His response includes the following steps, (a) The molecules speed up. (b) Then the molecules collide with one another more often. (c) Internal friction makes the collisions inelastic, (d) Heat is produced in the collisions. (e) The molecules of the gas transfer more energy to the thermometer when they strike it, so we observe that the temperature has gone up. (f) The same process can take place without the use of a hot plate if you quickly push in the piston in an insulated cylinder containing the gas. (i) Which of the parts (a) through
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Chapter 21 Solutions
EBK PHYSICS FOR SCIENTISTS AND ENGINEER
- Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.arrow_forwardA gas is at 200 K. If we wish to double the rms speed of the molecules of the gas, to what value must we raise its temperature? (a) 283 K (b) 400 K (c) 566 K (d) 800 K (e) 1 130 Karrow_forwardTwo cylinders A and B at the same temperature contain the same quantity of the same kind of gas. Cylinder A has three times the volume of cylinder B. What can you conclude about the pressures the gases exert? (a) We can conclude nothing about the pressures. (b) The pressure in A is three times the pressure in B. (c) The pressures must be equal. (d) The pressure in A must be one-third the pressure in B.arrow_forward
- For a temperature increase of 10 at constant volume, what is the heat absorbed by (a) 3.0 mol of a dilute monatomic gas; (b) 0.50 mol of a dilute diatomic gas; and (c) 15 mol of a dilute polyatomic gas?arrow_forwardOne cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.arrow_forwardConsider a gas filling two connected chambers that are separated by a removable barrier (Fig. P20.68). The gas molecules on the left (red) are initially at a higher temperature than the ones on the right (blue). When the barrier between the two chambers is removed, the molecules begin to mix and move from one chamber to the other. a. Describe what happens to the temperature in the left chamber and in the right chamber as time goes on, once the barrier is open. Discuss in terms of the mixing of the molecules from each gas. b. Describe what happens to the most probable speed and average speed in the left chamber and in the right chamber as time goes on, once the barrier is open. Do they increase or decrease by the same factor? Explain. FIGURE P20.68 Problems 68 and 69.arrow_forward
- A cylinder with a piston holds 0.50 m3 of oxygen at an absolute pressure of 4.0 atm. The piston is pulled outward, increasing the volume of the gas until the pressure drops to 1.0 atm. If the temperature stays constant, what new volume does the gas occupy? (a) 1.0 m3 (b) 1.5 m3 (c) 2.0 m3 (d) 0.12 m3 (e) 2.5 m3arrow_forwardThe pressure gauge on a cylinder of gas registers the gauge pressure, which is the difference between the interior pressure and the exterior pressure P0. Lets call the gauge pressure Pg. When the cylinder is full, the mass of the gas in it is mi at a gauge pressure of Pgi. Assuming the temperature of the cylinder remains constant, show that the mass of the gas remaining in the cylinder when the pressure reading is Pgf is given by mf=mi(Pgf+P0Pgi+P0)arrow_forwardIn the text, it was shown that N/V=2.681025m3 for gas at STP. (a) Show that this quantity is equivalent to N/V=2.681019cm3, as stated. (b) About how many atoms are mere in one m3 (a cubic micrometer) at STP? (c) What does your answer to part (b) imply about the separation of Mama and molecules?arrow_forward
- Consider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANSarrow_forwardIn a chemical processing plant, a reaction chamber of fixed volume V0 is connected to a reservoir chamber of fixed volume 4V0 by a passage containing a thermally insulating porous plug. The plug permits the chambers to be at different temperatures. The plug allows gas to pass from either chamber to the other, ensuring that the pressure is the same in both. At one point in the processing, both chambers contain gas at a pressure of 1.00 atm and a temperature of 27.0C. Intake and exhaust valves to the pair of chambers are closed. The reservoir is maintained at 27.0C while the reaction chamber is heated to 400C. What is the pressure in both chambers after that is done?arrow_forwardA fire breaks out and increases the Kelvin temperature of a cylinder of compressed gas by a factor of 1.2. What is the final pressure of the gas relative to its initial pressure?arrow_forward
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