Connect for Chemistry
13th Edition
ISBN: 9781260161854
Author: Raymond Chang, Jason Overby
Publisher: Mcgraw-hill Higher Education (us)
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Chapter 21, Problem 21.73QP
After heating, a metal surface (such as that of a cooking pan or skillet) develops a color pattern like an oil slick on water. Explain.
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Please help me find the 1/Time, Log [I^-] Log [S2O8^2-], Log(time) on the data table. With calculation steps. And the average for runs 1a-1b. Please help me thanks in advance. Will up vote!
Q1: Answer the questions for the reaction below:
..!! Br
OH
a) Predict the product(s) of the reaction.
b) Is the substrate optically active? Are the product(s) optically active as a mix?
c) Draw the curved arrow mechanism for the reaction.
d) What happens to the SN1 reaction rate in each of these instances:
1. Change the substrate to
Br
"CI
2. Change the substrate to
3. Change the solvent from 100% CH3CH2OH to 10% CH3CH2OH + 90% DMF
4. Increase the substrate concentration by 3-fold.
Experiment 27 hates & Mechanisms of Reations
Method I visual Clock Reaction
A. Concentration effects on reaction Rates
Iodine
Run [I] mol/L [S₂082] | Time
mo/L
(SCC)
0.04 54.7
Log
1/ Time Temp Log [ ] 13,20] (time)
/ [I] 199
20.06
23.0
30.04 0.04
0.04 80.0
22.8
45
40.02
0.04 79.0
21.6
50.08
0.03 51.0
22.4
60-080-02 95.0
23.4
7 0.08
0-01 1970
23.4
8 0.08 0.04 16.1
22.6
Chapter 21 Solutions
Connect for Chemistry
Ch. 21.3 - Prob. 1RCFCh. 21.3 - Prob. 2RCFCh. 21 - Prob. 21.1QPCh. 21 - Prob. 21.2QPCh. 21 - Prob. 21.3QPCh. 21 - Prob. 21.4QPCh. 21 - Prob. 21.5QPCh. 21 - Prob. 21.6QPCh. 21 - Describe with examples the chemical and...Ch. 21 - Prob. 21.8QP
Ch. 21 - Prob. 21.9QPCh. 21 - Prob. 21.10QPCh. 21 - In the Mond process for the purification of...Ch. 21 - Copper is purified by electrolysis (see Figure...Ch. 21 - Prob. 21.13QPCh. 21 - Prob. 21.14QPCh. 21 - Prob. 21.15QPCh. 21 - Prob. 21.16QPCh. 21 - Which of the following compounds would require...Ch. 21 - Although iron is only about two-thirds as abundant...Ch. 21 - Prob. 21.19QPCh. 21 - Prob. 21.20QPCh. 21 - Prob. 21.21QPCh. 21 - Prob. 21.22QPCh. 21 - Prob. 21.23QPCh. 21 - Why is potassium usually not prepared...Ch. 21 - Prob. 21.25QPCh. 21 - Prob. 21.26QPCh. 21 - Prob. 21.27QPCh. 21 - Prob. 21.28QPCh. 21 - Prob. 21.29QPCh. 21 - Prob. 21.30QPCh. 21 - Prob. 21.31QPCh. 21 - Prob. 21.32QPCh. 21 - Prob. 21.33QPCh. 21 - Prob. 21.34QPCh. 21 - Prob. 21.35QPCh. 21 - Prob. 21.36QPCh. 21 - Prob. 21.37QPCh. 21 - Prob. 21.38QPCh. 21 - Prob. 21.39QPCh. 21 - Prob. 21.40QPCh. 21 - Prob. 21.41QPCh. 21 - Prob. 21.42QPCh. 21 - Prob. 21.43QPCh. 21 - With the Hall process, how many hours will it take...Ch. 21 - Aluminum forms the complex ions AlCl4 and AlF63....Ch. 21 - The overall reaction for the electrolytic...Ch. 21 - Prob. 21.47QPCh. 21 - Write a balanced equation for the thermal...Ch. 21 - Prob. 21.49QPCh. 21 - The pressure of gaseous Al2Cl6 increases more...Ch. 21 - Starting with aluminum, describe with balanced...Ch. 21 - Prob. 21.52QPCh. 21 - Prob. 21.53QPCh. 21 - Prob. 21.54QPCh. 21 - Prob. 21.55QPCh. 21 - Referring to Figure 21.6, would you expect H2O and...Ch. 21 - A 0.450-g sample of steel contains manganese as an...Ch. 21 - Given that Gf (Fe2O3) = 741.0 kJ/mol and that Gf...Ch. 21 - Prob. 21.59QPCh. 21 - Prob. 21.60QPCh. 21 - Prob. 21.61QPCh. 21 - Explain each of the following statements: (a) An...Ch. 21 - Prob. 21.63QPCh. 21 - Write a balanced equation for the reaction between...Ch. 21 - Prob. 21.65QPCh. 21 - Explain why most metals have a flickering...Ch. 21 - Prob. 21.67QPCh. 21 - Prob. 21.68QPCh. 21 - The following are two reaction schemes involving...Ch. 21 - Prob. 21.70QPCh. 21 - Prob. 21.71QPCh. 21 - Prob. 21.72QPCh. 21 - After heating, a metal surface (such as that of a...Ch. 21 - Prob. 21.74QPCh. 21 - Prob. 21.75QPCh. 21 - As stated in the chapter, potassium superoxide...Ch. 21 - A sample of 10.00 g of sodium reacts with oxygen...
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- (15 pts) Consider the molecule B2H6. Generate a molecular orbital diagram but this time using a different approach that draws on your knowledge and ability to put concepts together. First use VSEPR or some other method to make sure you know the ground state structure of the molecule. Next, generate an MO diagram for BH2. Sketch the highest occupied and lowest unoccupied MOs of the BH2 fragment. These are called frontier orbitals. Now use these frontier orbitals as your basis set for producing LGO's for B2H6. Since the BH2 frontier orbitals become the LGOS, you will have to think about what is in the middle of the molecule and treat its basis as well. Do you arrive at the same qualitative MO diagram as is discussed in the book? Sketch the new highest occupied and lowest unoccupied MOs for the molecule (B2H6).arrow_forwardQ8: Propose an efficient synthesis of cyclopentene from cyclopentane.arrow_forwardQ7: Use compound A-D, design two different ways to synthesize E. Which way is preferred? Please explain. CH3I ONa NaOCH 3 A B C D E OCH3arrow_forward
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