
(a)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(a)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is phenyl formate.
The molecular formula of phenyl formate is
The structure of phenyl formate is given as,
Figure 1
(b)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(b)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is cyclohexyl benzoate.
The molecular formula of cyclohexyl benzoate is
The structure of cyclohexyl benzoate is given as,
Figure 2
(c)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(c)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is cyclopentyl phenylacetate.
The molecular formula of cyclopentyl phenylacetate is
The structure of cyclopentyl phenylacetate is given as,
Figure 3
(d)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(d)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is N-butylacetamide.
The molecular formula of N-butylacetamide is
The structure of N-butylacetamide is given as,
Figure 4
(e)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(e)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is N,N-dimethylformamide.
The molecular formula of N,N-dimethylformamide is
The structure of N,N-dimethylformamide is given as,
Figure 5
(f)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(f)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is benzoic propionic anhydride.
The molecular formula of benzoic propionic anhydride is
The structure of benzoic propionic anhydride is given as,
Figure 6
(g)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(g)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is benzamide.
The molecular formula of benzamide is
The structure of benzamide is given as,
Figure 7
(h)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(h)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is
The molecular formula of
The structure of
Figure 8
(i)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(i)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is
The molecular formula of
The structure of
Figure 9
(j)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(j)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is
The molecular formula of
The structure of
Figure 10
(k)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(k)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is phenyl isocyanate.
The molecular formula of phenyl isocyanate is
The structure of phenyl isocyanate is given as,
Figure 11
(l)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(l)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is cyclobutyl ethyl carbonate.
The molecular formula of cyclobutyl ethyl carbonate is
The structure of cyclobutyl ethyl carbonate is given as,
Figure 12
(m)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(m)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is
The molecular formula of
The structure of
Figure 13
(n)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(n)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is trichloroacetic anhydride.
The molecular formula of trichloroacetic anhydride is
The structure of trichloroacetic anhydride is given as,
Figure 14
(o)
Interpretation:
The structure to correspond with the given common and systematic names is to be drawn.
Concept introduction:
Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.
(o)

Answer to Problem 21.42SP
The structure to correspond with the given common and systematic names is given below.
Explanation of Solution
The given compound is Ethyl-N-methyl carbamate.
The molecular formula of Ethyl-N-methyl carbamate is
The structure of Ethyl-N-methyl carbamate is given as,
Figure 15
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Chapter 21 Solutions
Organic Chemistry, Books a la Carte Edition (9th Edition)
- Calculating the pH of a salt solution Calculate the pH at 25 °C of a 0.29M solution of potassium butanoate (KC3H,CO2). Note that butanoic acid (HC3H,CO2) is a weak acid with a pKa of 4.82. Round your answer to 1 decimal place. pH = -0 Х olo 18 Ararrow_forward: At a certain temperature, the equilibrium constant K for the following reaction is 1.58 × 10-12 N2(g) + O2(g) = 2 NO(g) Use this information to complete the following table. Suppose a 38. L reaction vessel is filled with 0.93 mol of N2 and 0.93 mol of O2. What can you say about the composition of the mixture in the vessel at equilibrium? There will be very little N2 and O2. There will be very little NO. What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 2 NO(g) N2(9)+02(9) What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 3 N2(9)+302(g) 6 NO(g) Neither of the above is true. K = ☐ K = ☐ ☐ X10 Х D ? 000 18 Ar Barrow_forwardwhen performing the reaction that involves 2 equivalents of 3-(diethylamino)-phenol and Phthalic anhydride with sulfuric acid and water react to form rhodamine b where the Phthalic anhydride cleaves in acid and how does Excessive Washing (w/ Base) & Subsequent Resonance Structure get affectedarrow_forward
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- Predicting the qualitative acid-base properties of salts Consider the following data on some weak acids and weak bases: base acid Ка K₁₁ name formula name formula nitrous acid HNO2 4.5×10 4 pyridine CHEN 1.7 × 10 9 4 hydrofluoric acid HF 6.8 × 10 methylamine CH3NH2 | 4.4 × 10¯ Use this data to rank the following solutions in order of increasing pH. In other words, select a '1' next to the solution that will have the lowest pH, a '2' next to the solution that will have the next lowest pH, and so on. solution 0.1 M NaNO2 0.1 M KF pH choose one v choose one v 0.1 M C5H5NHBr 0.1 M CH3NH3CI choose one v ✓ choose one 1 (lowest) 2 ☑ 3 4 (highest) 000 18 Ararrow_forward4. The major product from treatment of 2-propanol with the Jonesreagent is ___.A. acetone; B. none of the other answers is correct C. propene; D.propanoic acid; E carbon dioxide. Please include all steps! Thank you!arrow_forward7. All of the following compounds that are at the same oxidation levelare ___.u. methyl epoxide, v. propyne, w. propanal, x. propene,y. 2,2-dihydroxypropane, z. isopropanol?A. u,v,w,y; B. u,v,w; C. v,w,y,z; D. v, z; E. x,y,z Please include all steps. Thank you!arrow_forward
- 9. Which one of the following substituents is the worst leaving group inan SN2 reaction? A. -NH2; B. -OH; C. –F; D. NH3; E. H2O Please include all steps. Thanks!arrow_forwardUsing the general properties of equilibrium constants At a certain temperature, the equilibrium constant K for the following reaction is 2.5 × 105: CO(g) + H2O(g) CO2(g) + H2(g) Use this information to complete the following table. Suppose a 7.0 L reaction vessel is filled with 1.7 mol of CO and 1.7 mol of H2O. What can you say about the composition of the mixture in the vessel at equilibrium? What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. CO2(9)+H2(g) CO(g)+H₂O(g) What is the equilibrium constant for the following reaction? Be sure your answer has the correct number of significant digits. 3 CO(g)+3H2O(g) = 3 CO2(g)+3H2(g) There will be very little CO and H2O. x10 There will be very little CO2 and H2. 000 Neither of the above is true. K = ☐ K = ☐ 18 Ararrow_forward8. When ethane thiol is treated with hydrogen peroxide the product is___.A. ethane disulfide; B. diethyl sulfide; C. ethane sulfoxide; D. ethanesulfate; E. ethyl mercaptan. Please include all steps. Thanks!arrow_forward
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