Organic Chemistry, Books a la Carte Edition (9th Edition)
Organic Chemistry, Books a la Carte Edition (9th Edition)
9th Edition
ISBN: 9780134160382
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
Question
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Chapter 21, Problem 21.42SP

(a)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(a)

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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is phenyl formate.

The molecular formula of phenyl formate is C7O2H6.

The structure of phenyl formate is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  1

Figure 1

(b)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(b)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is cyclohexyl benzoate.

The molecular formula of cyclohexyl benzoate is C13H16O2.

The structure of cyclohexyl benzoate is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  2

Figure 2

(c)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(c)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is cyclopentyl phenylacetate.

The molecular formula of cyclopentyl phenylacetate is C13H16O2.

The structure of cyclopentyl phenylacetate is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  3

Figure 3

(d)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(d)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is N-butylacetamide.

The molecular formula of N-butylacetamide is C6H13ON.

The structure of N-butylacetamide is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  4

Figure 4

(e)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(e)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is N,N-dimethylformamide.

The molecular formula of N,N-dimethylformamide is C3H7ON.

The structure of N,N-dimethylformamide is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  5

Figure 5

(f)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(f)

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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is benzoic propionic anhydride.

The molecular formula of benzoic propionic anhydride is C10H10O3.

The structure of benzoic propionic anhydride is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  6

Figure 6

(g)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(g)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is benzamide.

The molecular formula of benzamide is C7H7NO.

The structure of benzamide is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  7

Figure 7

(h)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(h)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is γhydroxyvaleronitrile.

The molecular formula of γhydroxyvaleronitrile is C4H7NO.

The structure of γhydroxyvaleronitrile is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  8

Figure 8

(i)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(i)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is αbromobutyryl.

The molecular formula of αbromobutyryl is C4H6ClBrO.

The structure of αbromobutyryl is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  9

Figure 9

(j)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(j)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is βbutyrolactone.

The molecular formula of βbutyrolactone is C4H6O2.

The structure of βbutyrolactone is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  10

Figure 10

(k)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(k)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is phenyl isocyanate.

The molecular formula of phenyl isocyanate is C7H5NO.

The structure of phenyl isocyanate is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  11

Figure 11

(l)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(l)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is cyclobutyl ethyl carbonate.

The molecular formula of cyclobutyl ethyl carbonate is C7H12O3.

The structure of cyclobutyl ethyl carbonate is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  12

Figure 12

(m)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(m)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is δcaprolactum

The molecular formula of δcaprolactum is C6H11NO.

The structure of δcaprolactum is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  13

Figure 13

(n)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(n)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is trichloroacetic anhydride.

The molecular formula of trichloroacetic anhydride is C4Cl6O2.

The structure of trichloroacetic anhydride is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  14

Figure 14

(o)

Interpretation Introduction

Interpretation:

The structure to correspond with the given common and systematic names is to be drawn.

Concept introduction:

Structural formulas are used to describe the arrangement of atoms, groups or substituents in a molecule, whereas molecular formula describes the total number and type of atoms present in a molecule. The chemical structures are described by IUPAC name or common names. IUPAC names are totally different from common names because common names do not follow any rule, whereas IUPAC names follow specific rules. The common name does not include any suffix, prefix, and numbers.

(o)

Expert Solution
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Answer to Problem 21.42SP

The structure to correspond with the given common and systematic names is given below.

Explanation of Solution

The given compound is Ethyl-N-methyl carbamate.

The molecular formula of Ethyl-N-methyl carbamate is C4H9NO2.

The structure of Ethyl-N-methyl carbamate is given as,

Organic Chemistry, Books a la Carte Edition (9th Edition), Chapter 21, Problem 21.42SP , additional homework tip  15

Figure 15

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Chapter 21 Solutions

Organic Chemistry, Books a la Carte Edition (9th Edition)

Ch. 21.7C - Prob. 21.20PCh. 21.7C - Prob. 21.21PCh. 21.7D - Prob. 21.22PCh. 21.7D - The mechanism for acidic hydrolysis of a nitrile...Ch. 21.8A - Prob. 21.24PCh. 21.8C - Prob. 21.25PCh. 21.9 - Prob. 21.26PCh. 21.9 - Prob. 21.27PCh. 21.9 - Prob. 21.28PCh. 21.10 - Draw a mechanism for the acylation of anisole by...Ch. 21.10 - Prob. 21.30PCh. 21.11 - Prob. 21.31PCh. 21.11 - Prob. 21.32PCh. 21.12 - Problem 21-33 Propose a mechanism for the...Ch. 21.12 - Suggest the most appropriate reagent for each...Ch. 21.12 - Show how you would synthesize each compound,...Ch. 21.13 - Prob. 21.36PCh. 21.13 - Prob. 21.37PCh. 21.14 - Prob. 21.38PCh. 21.14 - Prob. 21.39PCh. 21.16 - Prob. 21.40PCh. 21.16 - Prob. 21.41PCh. 21 - Prob. 21.42SPCh. 21 - Give appropriate names for the following...Ch. 21 - Predict the major products formed when benzoyl...Ch. 21 - Predict the products of the following reactions....Ch. 21 - Prob. 21.46SPCh. 21 - Prob. 21.47SPCh. 21 - Prob. 21.48SPCh. 21 - Propose mechanisms for the following reactions.Ch. 21 - Prob. 21.51SPCh. 21 - An ether extraction of nutmeg gives large...Ch. 21 - Prob. 21.53SPCh. 21 - Show how you would accomplish the following...Ch. 21 - Prob. 21.55SPCh. 21 - Prob. 21.56SPCh. 21 - Prob. 21.57SPCh. 21 - Prob. 21.58SPCh. 21 - Prob. 21.59SPCh. 21 - Explain this curious result. What does this...Ch. 21 - Prob. 21.61SPCh. 21 - Prob. 21.62SPCh. 21 - Prob. 21.63SPCh. 21 - A chemist was called to an abandoned aspirin...Ch. 21 - Prob. 21.67SPCh. 21 - The IR spectrum, 13ONTVTR spectrum, and 1HNMR...Ch. 21 - Prob. 21.69SPCh. 21 - Prob. 21.70SPCh. 21 - Prob. 21.71SP
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