(a) Interpretation: The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined. Concept introduction: The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory . The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding. The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex. The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Question

Want to see the full answer?

Answer 1

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

PLEASE ANSWER THE QUESTION!!!

3. SYNTHESIS. Propose a sequence of synthetic steps (FGI) that convert the starting material (SM) into the Target molecule. For each FGI in your proposed synthesis, specify the reagents / conditions, and draw the product(s) of that FGI. DO NOT INCLUDE the FGI mxn in the answer you submit. If an FGI requires two reagent sets, specify the order in which the reagent sets are added, e.g., i) Hg(OAc)2 / H₂O; ii) NaBH4/MeOH. Indicate the stereochemistry (if any) of the products of each FGI. FGI 1. Me Starting Material Source of all carbons in the Target molecule (can use multiple copies) Me Me Target molecule + enantiomer

curved arrows are used to illustate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction mechanism steps

Answer 2

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 6

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 7

Chapter 21, Problem 21.20A

Interpretation Introduction

(a)

Interpretation:

The orbital diagram of the free metal ion and its identity is to be discussed. The metal ion that uses hybrid orbital and the number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The orbital diagram of the metal ion and the hybrid orbitals and number of unpaired electrons in the complex is to be determined.

Concept introduction:

The geometry and magnetic properties of the coordination complex can be determined by the valence bond theory.

The hybrid orbitals can be described as the atomic orbitals of the metal that are hybridized to give an equal number of the new orbitals. The hybridized orbital will undergo overlapping with ligands orbitals for bonding.

The complexes that have unpaired electrons are paramagnetic complexes while the complex that has no unpaired electrons are diamagnetic complex.

The inner orbital complex or low spin can be defined as the complex that uses inner orbital in the hybridization while the outer orbital complex or high spin can be defined as the complex that uses outer orbital in the hybridization.

Answer 10

Expert Solution & Answer

Answer 11

Expert Solution & Answer

Answer 12

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 13

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2A Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4A Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6A Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8A Ch. 21 - Which of the following [Pt( H 2O)2Cl3Br]...Ch. 21 - Prob. 21.10A

Solution Summary: The author explains the orbital diagram of the free metal ion and its identity. The number of unpaired electrons in the complex is determined by the valence bond theory.

Concept explainers

Want to see the full answer?

Chapter 21 Solutions