Concept explainers
(a)
Interpretation:
The time taken to form
Concept Introduction:
An
Galvanic cell consists of two half-cells. The redox reaction occurs in these half-cells. The half-cell in which the reduction reaction occurs is known as the reduction half-cell, whereas the half-cell in which the oxidation reaction occurs is known as the oxidation half-cell.
Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode.
Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode.
Oxidation: The gain of oxygen or the loss of hydrogen or the loss of an electron in a species during a redox reaction is called as oxidation.
Reduction: The loss of oxygen or the gain of hydrogen or the gain of an electron in a species during a redox reaction is called as reduction.
The Standard Gibb’s free energy change and the standard cell potential are related as followed:
n - Number of electrons involved per equivalent of the net redox reaction in the cell
F - Faraday’s Constant (96500 C)
Ideal gas Equation:
Any gas is described by using four terms namely pressure, volume, temperature and the amount of gas. Thus combining three laws namely Boyle’s, Charles’s Law and Avogadro’s Hypothesis the following equation could be obtained. It is referred as ideal gas equation.
Where,
(b)
Interpretation:
The
Concept Introduction:
An electrochemical cell is a device in which a redox reaction is used to convert chemical energy into electrical energy. Such device is also known as the galvanic or voltaic cell.
Galvanic cell consists of two half-cells. The redox reaction occurs in these half-cells. The half-cell in which the reduction reaction occurs is known as the reduction half-cell, whereas the half-cell in which the oxidation reaction occurs is known as the oxidation half-cell.
Anode: The electrode where the oxidation occurs is called as an anode. It is a negatively charged electrode.
Cathode: The electrode where reduction occurs is called as a cathode. It is a positively charged electrode.
Oxidation: The gain of oxygen or the loss of hydrogen or the loss of an electron in a species during a redox reaction is called as oxidation.
Reduction: The loss of oxygen or the gain of hydrogen or the gain of an electron in a species during a redox reaction is called as reduction.
The Standard Gibb’s free energy change and the standard cell potential are related as followed:
n - Number of electrons involved per equivalent of the net redox reaction in the cell
F - Faraday’s Constant (96500 C)
The Nernst equation depicts the relationship between
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Chapter 21 Solutions
CHEMISTRY THE MOLECULAR NATURE OF MATTER
- "Water gas" is an industrial fuel composed of a mixture of carbon monoxide and hydrogen gases. When this fuel is burned, carbon dioxide and water result. From the information given below, write a balanced equation and determine the enthalpy of this reaction: CO(g) + O2(g) → CO₂(g) + 282.8 kJ H2(g) + O2(g) → H₂O(g) + 241.8 kJ MacBook Airarrow_forwardPage of 3 4. Calculate AG for the following reaction at 25°C. Will the reaction occur (be spontaneous)? How do you know? NH3(g) + HCl(g) → NH4Cl(s) AH=-176.0 kJ AS-284.8 J-K-1arrow_forwardtrue or false The equilibrium constant for this reaction is 0.20. N2O4(g) ⇔ 2NO2(g) Based on the above, the equilibrium constant for the following reaction is 5. 4NO2(g) ⇔ 2N2O4(g)arrow_forward
- true or false The equilibrium constant for this reaction is 0.20. N2O4(g) ⇔ 2NO2(g) Based on the above, the equilibrium constant for the following reaction is 0.4. 2N2O4(g) ⇔ 4NO2(g)arrow_forwardtrue or false Using the following equilibrium, if heat is added the equilibrium will shift toward the reactants. N2(g) + 3H2(g) ⇔ 2NH3(g) + heatarrow_forwardTrue or False Using the following equilibrium, if heat is added the equilibrium will shift toward the products. N2O4(g) + heat ⇔ 2NO2(g)arrow_forward
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