Concept explainers
a) Li or H
Interpretation:
The more electronegative element among Li and H is to be identified.
Concept introduction:
Electronegativity is the intrinsic ability of an atom to attract the shared pair of electrons in a covalent bond. Metals on the left side of the periodic table attract electron weekly and hence have low electronegativity values. Oxygen, nitrogen and halogens on the right side of the periodic table attract electron strongly and have high electronegativity values. The position in the periodic table determines the relative values of electronegativity of elements. The electronegativity generally decreases from top to bottom and increases from left to right across the periodic table.
To determine:
Which is more electronegative Li or H.
b) B or Be
Interpretation:
The more electronegative element among B and Be is to be identified.
Concept introduction:
Electronegativity is the intrinsic ability of an atom to attract the shared pair of electrons in a covalent bond. Metals on the left side of the periodic table attract electron weekly and hence have low electronegativity values. Oxygen, nitrogen and halogens on the right side of the periodic table attract electron strongly and have high electronegativity values. The position in the periodic table determines the relative values of electronegativity of elements. The electronegativity generally decreases from top to bottom and increases from left to right across the periodic table.
To determine:
Which is more electronegative B or Be.
c) Cl or I
Interpretation:
The more electronegative element among Cl and I is to be identified.
Concept introduction:
Electronegativity is the intrinsic ability of an atom to attract the shared pair of electrons in a covalent bond. Metals on the left side of the periodic table attract electron weekly and hence have low electronegativity values. Oxygen, nitrogen and halogens on the right side of the periodic table attract electron strongly and have high electronegativity values. The position in the periodic table determines the relative values of electronegativity of elements. The electronegativity generally decreases from top to bottom and increases from left to right across the periodic table.
To determine:
Which is more electronegative Cl or I.
d) C or H
Interpretation:
The more electronegative element among C and H is to be identified.
Concept introduction:
Electronegativity is the intrinsic ability of an atom to attract the shared pair of electrons in a covalent bond. Metals on the left side of the periodic table attract electron weekly and hence have low electronegativity values. Oxygen, nitrogen and halogens on the right side of the periodic table attract electron strongly and have high electronegativity values. The position in the periodic table determines the relative values of electronegativity of elements. The electronegativity generally decreases from top to bottom and increases from left to right across the periodic table.
To determine:
Which is more electronegative C or H.
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Chapter 2 Solutions
EP ORGANIC CHEMISTRY,24 MONTH-OWLV2
- 7. For the following structure: ← Draw structure as is - NO BI H H Fisher projections (a) Assign R/S configuration at all chiral centers (show all work). Label the chiral centers with an asterisk (*). (b) Draw an enantiomer and diastereomer of the above structure and assign R/S configuration at all chiral centers (again, show all work). (c) On the basis of the R/S system, justify your designation of the structures as being enantiomeric or diastereomeric to the original structure.arrow_forwardDon't used Ai solutionarrow_forward1. For the following reactions, predict the major product. Show stereochemistry where appropriate. неу b) 7 HBr XV ROOR H₂504 c) N/ H20 H+2 d) ~ Pt c) f. MCPBA -> сна сла (solvent) (1)BH 3-THE (3) Надрон B177 H20 9)arrow_forward
- For the following reactions, predict the major product. Show stereochemistry where approarrow_forwardHow is Talu home quer in Org. Chemistry propose a 3-butanal prepared from ketone? complete reaction for this, (to start from the guignand Meagent. ②what pocubble products could be produced from the reaction of : CA₂ CH₂ CH₂ dil H.504 A CH3 1 OBCH₂OH Naz Cr₂ 07 12504 NazCD 4 CH3CH2 07 AzS04 H3C H3C CH3-C - C - Atz но но + H, CH3 07 > ⑦Colts C614501 + (215) 504 кон 4arrow_forwardRank the following compounds most to least acidic: a) О OH 요애 OH .OH flow flow О F F F F OH F b) Ha EN-Ha CI Ha F F CI Haarrow_forward
- a) b) Provide arrows to show the mechanisms and then predict the products of the following acid base reaction. Use pKas to determine which way the reaction will favor (Hint: the lower pka acid will want to dissociate) Дон OH Ha OH NH2 c) H H-O-Harrow_forwardMATERIALS. Differentiate between interstitial position and reticular position.arrow_forwardFor each of the following, indicate whether the arrow pushes are valid. Do we break any rules via the arrows? If not, indicate what is incorrect. Hint: Draw the product of the arrow and see if you still have a valid structure. a. b. N OH C. H N + H d. e. f. مه N COHarrow_forward
- Decide which is the most acidic proton (H) in the following compounds. Which one can be removed most easily? a) Ha Нь b) Ha Нь c) CI CI Cl Ha Ньarrow_forwardProvide all of the possible resonanse structures for the following compounds. Indicate which is the major contributor when applicable. Show your arrow pushing. a) H+ O: b) c) : N :O : : 0 d) e) Оarrow_forwardDraw e arrows between the following resonance structures: a) b) : 0: :0: c) :0: N t : 0: بار Narrow_forward
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