OWLV2 FOR MASTERTON/HURLEY'S CHEMISTRY:
8th Edition
ISBN: 9781305079304
Author: Hurley
Publisher: IACCENGAGE
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Question
Chapter 21, Problem 13QAP
Interpretation Introduction
(a)
Interpretation:
The formula of an anion in which S has an oxidation number of
Concept introduction:
The number of electrons gained or lost by the atom is said to be its oxidation number.
Interpretation Introduction
(b)
Interpretation:
The formula of two anion in which S has an oxidation number of
Concept introduction:
The number of electrons gained or lost by the atom is said to be its oxidation number.
Interpretation Introduction
(c)
Interpretation:
The formula of two different acids of sulfur should be determined.
Concept introduction:
The number of electrons gained or lost by the atom is said to be its oxidation number.
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Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Part IV. C6H5 CH2CH2OH is an aromatic compound which was subjected to Electron Ionization - mass
spectrometry (El-MS) analysis. Prominent m/2 values: m/2 = 104 and m/2 = 9) was obtained.
Draw the structures of these fragments.
For each reaction shown below follow the curved arrows to complete each equationby showing the structure of the products. Identify the acid, the base, the conjugated acid andconjugated base. Consutl the pKa table and choose the direciton theequilibrium goes. However show the curved arrows. Please explain if possible.
Chapter 21 Solutions
OWLV2 FOR MASTERTON/HURLEY'S CHEMISTRY:
Ch. 21 - Prob. 1QAPCh. 21 - Prob. 2QAPCh. 21 - Prob. 3QAPCh. 21 - Prob. 4QAPCh. 21 - Prob. 5QAPCh. 21 - Prob. 6QAPCh. 21 - Give the formula for the acidic oxide of (a) HNO3...Ch. 21 - Prob. 8QAPCh. 21 - Write the formulas of the following compounds. (a)...Ch. 21 - Prob. 10QAP
Ch. 21 - Prob. 11QAPCh. 21 - Prob. 12QAPCh. 21 - Prob. 13QAPCh. 21 - Prob. 14QAPCh. 21 - Prob. 15QAPCh. 21 - Prob. 16QAPCh. 21 - Prob. 17QAPCh. 21 - Write a balanced net ionic equation for the...Ch. 21 - Prob. 19QAPCh. 21 - Prob. 20QAPCh. 21 - Prob. 21QAPCh. 21 - Prob. 22QAPCh. 21 - Prob. 23QAPCh. 21 - Prob. 24QAPCh. 21 - Prob. 25QAPCh. 21 - Prob. 26QAPCh. 21 - Prob. 27QAPCh. 21 - Prob. 28QAPCh. 21 - Prob. 29QAPCh. 21 - Prob. 30QAPCh. 21 - Prob. 31QAPCh. 21 - Prob. 32QAPCh. 21 - Prob. 33QAPCh. 21 - Prob. 34QAPCh. 21 - The average concentration of bromine (as bromide)...Ch. 21 - Prob. 36QAPCh. 21 - Iodine can be prepared by allowing an aqueous...Ch. 21 - Prob. 38QAPCh. 21 - Prob. 39QAPCh. 21 - Prob. 40QAPCh. 21 - Prob. 41QAPCh. 21 - Prob. 42QAPCh. 21 - Prob. 43QAPCh. 21 - Prob. 44QAPCh. 21 - Prob. 45QAPCh. 21 - Given...Ch. 21 - What is the concentration of fluoride ion in a...Ch. 21 - Calculate the solubility in grams per 100 mL of...Ch. 21 - Prob. 49QAPCh. 21 - Follow the directions for Problem 49 for the...Ch. 21 - Consider the equilibrium system HF(aq)H+(aq)+F(aq)...Ch. 21 - Applying the tables in Appendix 1 to...Ch. 21 - Consider the reaction 4NH3(g)+5O2(g)4NO(g)+6H2O(g)...Ch. 21 - Data are given in Appendix 1 for white phosphorus,...Ch. 21 - Prob. 55QAPCh. 21 - Prob. 56QAPCh. 21 - Sodium hypochlorite is produced by the...Ch. 21 - Prob. 58QAPCh. 21 - Prob. 59QAPCh. 21 - Prob. 60QAPCh. 21 - Consider the reduction of nitrate ion in acidic...Ch. 21 - Prob. 62QAPCh. 21 - Choose the strongest acid from each group. (a)...Ch. 21 - Prob. 64QAPCh. 21 - Prob. 65QAPCh. 21 - Prob. 66QAPCh. 21 - Prob. 67QAPCh. 21 - Prob. 68QAPCh. 21 - Prob. 69QAPCh. 21 - Explain why (a) acid strength increases as the...Ch. 21 - Prob. 71QAPCh. 21 - Prob. 72QAPCh. 21 - The amount of sodium hypochlorite in a bleach...Ch. 21 - Prob. 74QAP
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