GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
11th Edition
ISBN: 9780134193601
Author: Petrucci
Publisher: PEARSON
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Chapter 21, Problem 13E
Interpretation Introduction
Interpretation:
To determine the conditions under which the given reactants will produce the given products.
Concept introduction:
A chemical equation refers to the symbolic representation of a given
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206 Pb
82
Express your answers as integers. Enter your answers separated by a comma.
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VAΣ
ΜΕ ΑΣΦ
Np, N₁ = 82,126
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?
protons, neutrons
Please draw the inverted chair forms of the products for the two equilibrium reactions
shown below. Circle the equilibrium reaction that would have a AG = 0, i.e., the relative energy of
the reactant (to the left of the equilibrium arrows) equals the relative energy of the product? [No
requirement to show or do calculations.]
CH3
CH3
HH
CH3
1
-CH3
5.
Please consider the Newman projection of tartaric acid drawn below as an eclipsed
conformer (1). Please draw the most stable conformer and two intermediate energy conformers
noting that staggered conformers are lower in energy than eclipsed forms even if the staggered
conformers have gauche relationships between groups. [Draw the substituents H and OH on the front
carbons and H, OH and CO₂H on the back carbons based on staggered forms. -CO₂H is larger than -OH.]
OH
COH
ICOOH
COOH
COOH
1
2
COOH
COOH
3
4
Staggered
Staggered
Staggered (most stable)
Indicate the number of each conformer above (1, 2, 3 and 4) that corresponds to the relative energies
below.
Ref=0
Rotation
6. (60 points)
a. Are compounds 1 and 2 below enantiomers, diastereomers or identical?
OH
OH
HO
HO
LOH
HO
HO
OH
2
OH
OH
b. Please complete the zig-zag conformation of the compound
(3R,4S)-3,4-dichloro-2,5-dimethylhexane by writing the respective atoms in the boxes.
3.
Chapter 21 Solutions
GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
Ch. 21 - Prob. 1ECh. 21 - Use information from the chapter to write chemical...Ch. 21 - Prob. 3ECh. 21 - Describe two methods for determining the identity...Ch. 21 - Arrange the following compounds in the expected...Ch. 21 - Prob. 6ECh. 21 - Prob. 7ECh. 21 - A lithium battery used in a cardiac pacemaker has...Ch. 21 - Prob. 9ECh. 21 - Prob. 10E
Ch. 21 - The standard Gibbs energies of formation, rG , for...Ch. 21 - Prob. 12ECh. 21 - Prob. 13ECh. 21 - Prob. 14ECh. 21 - Prob. 15ECh. 21 - Prob. 16ECh. 21 - Prob. 17ECh. 21 - Write chemical equations for the reactions you...Ch. 21 - Without performing detailed calculations, indicate...Ch. 21 - Prob. 20ECh. 21 - With respect to decomposition to MO(s) and SO2(g)...Ch. 21 - Prob. 22ECh. 21 - Prob. 23ECh. 21 - Prob. 24ECh. 21 - Prob. 25ECh. 21 - Prob. 26ECh. 21 - Prob. 27ECh. 21 - Prob. 28ECh. 21 - Prob. 29ECh. 21 - Prob. 30ECh. 21 - Prob. 31ECh. 21 - Prob. 32ECh. 21 - Prob. 33ECh. 21 - Prob. 34ECh. 21 - Prob. 35ECh. 21 - Prob. 36ECh. 21 - Prob. 37ECh. 21 - Prob. 38ECh. 21 - Prob. 39ECh. 21 - Prob. 40ECh. 21 - Prob. 41ECh. 21 - Prob. 42ECh. 21 - Prob. 43ECh. 21 - Prob. 44ECh. 21 - Methane and sulfur vapor react to form carbon...Ch. 21 - Prob. 46ECh. 21 - Prob. 47ECh. 21 - Prob. 48ECh. 21 - Write plausible chemical equations for the (a)...Ch. 21 - Prob. 50ECh. 21 - Prob. 51ECh. 21 - Aqueous tin(II) ion, Sn2+(aq) , is a good reducing...Ch. 21 - Would you expect the reaction of Sn(s) and Cl2(g)...Ch. 21 - Prob. 54ECh. 21 - Prob. 55IAECh. 21 - The following series of observations is made: (1)...Ch. 21 - Prob. 57IAECh. 21 - Prob. 58IAECh. 21 - Prob. 59IAECh. 21 - Prob. 60IAECh. 21 - Lithium superoxide, LiO2(s) , has never been...Ch. 21 - Prob. 62IAECh. 21 - Prob. 63IAECh. 21 - Prob. 64IAECh. 21 - Use data from Appendix D (Table D-2) to calculate...Ch. 21 - Prob. 66IAECh. 21 - A particular water sample contains 56.9 ppm SO42-...Ch. 21 - An aluminum production cell of the type pictured...Ch. 21 - Prob. 69IAECh. 21 - Prob. 70IAECh. 21 - Prob. 71IAECh. 21 - Prob. 72IAECh. 21 - Prob. 73IAECh. 21 - Prob. 74IAECh. 21 - Prob. 75IAECh. 21 - Would you expect the lattice energy of MgS(s) to...Ch. 21 - Prob. 77IAECh. 21 - Prob. 78FPCh. 21 - Prob. 79FPCh. 21 - Prob. 80SAECh. 21 - Briefly describe each of the following ideas,...Ch. 21 - Explain the important distinction between each...Ch. 21 - Prob. 83SAECh. 21 - Prob. 84SAECh. 21 - Predict the products of the following reactions:...Ch. 21 - A chemist knows that aluminum is more reactive...Ch. 21 - Listed are several pairs of substances. For some...Ch. 21 - Prob. 88SAECh. 21 - Prob. 89SAECh. 21 - Prob. 90SAECh. 21 - Prob. 91SAECh. 21 - Prob. 92SAECh. 21 - Prob. 93SAECh. 21 - Prob. 94SAECh. 21 - Prob. 95SAE
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